ADOGEN(R) 464

ADOGEN(R) 464 Basic information
Product Name:ADOGEN(R) 464
Synonyms:TOM-ACL;Tricaprylylmethylammonium chloride[Phase-transfer Catalyst];TrioctylMethylaMMoniuM Chloride (R=C8-C10) [Phase-transfer Catalyst];(R=C8-C10) [Phase-transfer Catalyst];TrioctylMethylaMMoniuM Chloride ;Aliquat 336, average MW 442 1LT;Methyltrioctylammonium Chloride Tricaprylmethylammonium Chloride;MethyltrioctylaMMoniuM chloride (R=C8-C10)
CAS:63393-96-4
MF:C25H54ClN
MW:404.15596
EINECS:264-120-7
Product Categories:
Mol File:63393-96-4.mol
ADOGEN(R) 464 Structure
ADOGEN(R) 464 Chemical Properties
Boiling point >240℃
density 0.898 g/mL at 25 °C(lit.)
vapor density >1 (vs air)
vapor pressure 33 mm Hg ( 20 °C)
refractive index n20/D 1.4665(lit.)
Fp >230 °F
storage temp. Store below +30°C.
solubility Miscible with benzene and chloroform.
form Viscous Liquid
color Amber
Water Solubility 1.023g/L at 20℃
Sensitive Hygroscopic
LogP2.93 at 25℃
EPA Substance Registry SystemQuaternary ammonium compounds, tri-C8-10-alkylmethyl, chlorides (63393-96-4)
Safety Information
Hazard Codes C,N,Xn
Risk Statements 10-22-34-50/53-41-38-67
Safety Statements 16-26-27-36/37/39-45-61-60-39
RIDADR UN 2924 3/PG 3
WGK Germany 3
RTECS UZ2997500
TSCA Yes
HS Code 3824 99 92
HazardClass 8
PackingGroup III
ToxicityLD50 orally in Rabbit: 220 mg/kg
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
ALFA English
ADOGEN(R) 464 Usage And Synthesis
Chemical Propertiesamber viscous liquid at room temperature
UsesQuat suitable for nearly all PTC applications without aqueous work-up
UsesAliquat 336 is widely utilized as a phase transfer catalyst for the catalytic oxidation of cyclohexene to 1,6-hexanedioic acid. It is involved in the total synthesis of Manzamine A. It serves as an anti-static agent for textile fabrics and carpeting. It finds application in waste water treatment to control foaming. It has a major application as a metal extraction reagent for cadmium, zinc, iron and rare earth metals. It is used as an effective catalyst for the preparation of methylphenyl ether from sodium phenolate with for methyl bromide.
DefinitionChEBI: Methyltrioctylammonium chloride is an organic chloride salt having methyltrioctylammonium as the cation. It has a role as a phase-transfer catalyst. It is a quaternary ammonium salt and an organic chloride salt. It contains a methyltrioctylammonium.
Flammability and ExplosibilityNotclassified
Purification MethodsA 30% (v/v) of Aliquat 336 solution in *benzene is washed twice with an equal volume of 1.5M HBr. [Petrow & Allen, Anal Chem 33 1303 1961.] It is purified by dissolving 50g in CHCl3 (100mL) and shaking with 20% NaOH solution (200mL) for 10minutes, and followed by 20% NaCl (200mL) for 10minutes. It is then washed with a small volume of H2O and filtered through a dry filter paper [Adam & Pribil Talanta 18 733 1971]. n-Alkylammonium chloride n=2,4,6. Recrystallise them from EtOH or an EtOH/Et2O mixture. [Hashimoto & Thomas J Am Chem Soc 107 4655 1985, Chu & Thomas J Am Chem Soc 108 6270 1986.] n-Alkyltrimethylammonium bromide n=10,12,16. Recrystallise them from an EtOH/Et2O mixture. [Hashimoto & Thomas J Am Chem Soc 107 4655 1985.]
ADOGEN(R) 464 Preparation Products And Raw materials
Preparation Products3,5-DIMETHYL-4-ISOXAZOLECARBALDEHYDE
Aluminum acetylacetonate METHYL ISOCYANOACETATE TRIS(2,2,6,6-TETRAMETHYL-3,5-HEPTANEDIONATO)EUROPIUM(III) N-BUTYLISOCYANIDE PHENYLSELENOL Tris(2,4-pentanedionato)chroMiuM(III) DICHLORO(ETHYLENEDIAMINE)PLATINUM(II) SALCOMINE ADOGEN 464 2,4-PENTANEDIONE, SILVER DERIVATIVE Tosylmethyl isocyanide COBALT(II) ACETYLACETONATE Cupric acetylacetonate Ethyl isocyanoacetate TERT-BUTYL ISOCYANIDE Ferric acetylacetonate COBALT ETHYLENE DIAMINE CHLORIDE TRIS(2,2,6,6-TETRAMETHYL-3,5-HEPTANEDIONATO)DYSPROSIUM(III)

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