TRIETHYLGERMANIUM HYDRIDE

TRIETHYLGERMANIUM HYDRIDE Basic information
Product Name:TRIETHYLGERMANIUM HYDRIDE
Synonyms:TRIETHYLGERMANE;TRIETHYLGERMANIUM HYDRIDE;Triethylgermanium hydride,98%;TRIETHYLGERMANIUM HYDRIDE ISO 9001:2015 REACH;Germane, triethyl-
CAS:1188-14-3
MF:C6H16Ge
MW:160.83
EINECS:
Product Categories:GermaniumSynthetic Reagents;Metal HydridesOrganometallic Reagents;Organogermanium;Others;Precursors by Metal;Reduction;Vapor Deposition Precursors
Mol File:1188-14-3.mol
TRIETHYLGERMANIUM HYDRIDE Structure
TRIETHYLGERMANIUM HYDRIDE Chemical Properties
Boiling point 121-122 °C/20 mmHg (lit.)
density 0.994 g/mL at 25 °C (lit.)
refractive index n20/D 1.433(lit.)
Fp 47 °F
storage temp. Flammables area
form liquid
Specific Gravity1.004
Water Solubility Soluble in water( 46 g/100 mL (26°C).
Hydrolytic Sensitivity7: reacts slowly with moisture/water
InChIKeyLTLGQZPDSQYFSB-UHFFFAOYSA-N
Safety Information
Hazard Codes F,Xn
Risk Statements 11-20/21/22
Safety Statements 16-36
RIDADR UN 1993 3/PG 2
WGK Germany 3
TSCA No
HazardClass 4.3
PackingGroup II
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
ALFA English
TRIETHYLGERMANIUM HYDRIDE Usage And Synthesis
Chemical Propertiesclear colorless liquid
UsesCo-reactant for the preparation of germanium acrylates. They are the Synthetic Reagents.
General DescriptionTriethylgermanium hydride (Ge(C2H5)3H) may be prepared by a three step process:
  • Ge(C2H5)3Br reacted with Na to yield Ge2(C2H5)6
  • Ge2(C2H5)6 treated with Li to form Ge(C2H5)3Li
  • ammonolysis of Ge(C2H5)3Li to give the end product, Ge(C2H5)3H. 1
TRIETHYLGERMANIUM HYDRIDE Preparation Products And Raw materials
Preparation ProductsChlorofluoromethane-->TRIETHYLGERMANIUMACETATE
TETRA-N-BUTYLGERMANE TRIALLYLFLUOROGERMANE VINYLTRIETHYLGERMANE HEXAALLYLDIGERMOXANE TRI-N-BUTYLGERMANIUM CHLORIDE DIGERMOXANE, HEXABUTYL- BROMOTRIETHYLGERMANE TRI-N-BUTYLGERMANE TETRAETHYLGERMANE TRIETHYLGERMANIUM HYDRIDE HEXAETHYLDIGERMOXANE acetic acid, tributylgermanium METHACRYLOXYTRIETHYLGERMANE HEXAETHYLDIGERMANE 3-AMINOPROPYLTRIBUTYLGERMANE TETRAPENTYLGERMANE TETRA-N-PROPYLGERMANE GERMANIUM TETRAHEXYL

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