ChemicalBook Product Catalog Organic Chemistry Phosphines TRI-M-TOLYLPHOSPHINE

TRI-M-TOLYLPHOSPHINE

TRI-M-TOLYLPHOSPHINE Basic information
Product Name:TRI-M-TOLYLPHOSPHINE
Synonyms:Tri-m-tolyphosphine;Tris(m-tolyl)phosphine, 98+%;Tri(m-tolyl)phosphine,98+%;TRIS(M-TOLYL)PHOSPHINE (TMTP);Tri-M-tolyl;Tris(m-methylphenyl)phosphine;tris(3-Methylphenyl)phosphane;Phosphine,tris(3-Methylphenyl)-
CAS:6224-63-1
MF:C21H21P
MW:304.37
EINECS:228-312-4
Product Categories:Phosphorus Compounds;Achiral Phosphine;Ligand;Phosphine Ligands;organophosphorus ligand;Aryl Phosphine;Synthetic Organic Chemistry;Basic Phosphine LigandsCatalysis and Inorganic Chemistry;Catalysis and Inorganic Chemistry;Cross-Coupling;Phosphine Ligands
Mol File:6224-63-1.mol
TRI-M-TOLYLPHOSPHINE Structure
TRI-M-TOLYLPHOSPHINE Chemical Properties
Melting point 97-99 °C(lit.)
Boiling point 423.1±44.0 °C(Predicted)
storage temp. Inert atmosphere,Room Temperature
form crystal
color white
Water Solubility Insoluble in water.
Sensitive Air Sensitive
BRN 658863
InChIInChI=1S/C21H21P/c1-16-7-4-10-19(13-16)22(20-11-5-8-17(2)14-20)21-12-6-9-18(3)15-21/h4-15H,1-3H3
InChIKeyLFNXCUNDYSYVJY-UHFFFAOYSA-N
SMILESP(C1=CC=CC(C)=C1)(C1=CC=CC(C)=C1)C1=CC=CC(C)=C1
CAS DataBase Reference6224-63-1(CAS DataBase Reference)
EPA Substance Registry SystemPhosphine, tris(3-methylphenyl)- (6224-63-1)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38-38-37-36
Safety Statements 26-36
WGK Germany 3
F 10-23
TSCA Yes
HS Code 29319090
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
ALFA English
TRI-M-TOLYLPHOSPHINE Usage And Synthesis
Chemical Propertieswhite to light yellow crystal powde
Usessuzuki reaction
UsesTri-m-tolylphosphine acts as a reagent for the preparation, crystal structure, multinuclear NMR, antitumor activity, photolysis of silver methylxanthate complexes against human adrenocarcinoma breast cancer cells.
TRI-M-TOLYLPHOSPHINE Preparation Products And Raw materials
Raw materialsEthanol-->Hydrochloric acid-->Ethyl acetate-->Tetrahydrofuran-->Dichloromethane-->PETROLEUM ETHER-->Magnesium-->Phosphorus trichloride-->3-Bromotoluene-->5-Bromo-m-xylene
DICHLORO[(R)-(-)-4,12-BIS(DI(3,5-XYLYL)PHOSPHINO)-[2,2]-PARACYCLOPHANE][(1S,2S)-(-)-1,2-DIPHENYLETHYLENEDIAMINE]RUTHENIUM (R)-(-)-4,12-BIS(DI-3,5-XYLYLPHOSPHINO)[2.2]PARACYCLOPHANE(1,5-CYCLOOCTADIENE)RHODIUM(I) TETRAFLUOROBORATE DICHLORO[(S)-(+)-4,12-BIS(DI(3,5-XYLYL)PHOSPHINO)-[2.2]-PARACYCLOPHANE][(1R,2R)-(+)-1,2-DIPHENYLETHYLENEDIAMINE]RUTHENIUM (II) (S)-(-)-7,7'-BIS[DI(3,5-DIMETHYLPHENYL)PHOSPHINO]-2,2',3,3'-TETRAHYDRO-1,1'-SPIROBIINDANE (S)-(+)-4,12-BIS(DI(3,5-XYLYL)PHOSPHINO)-[2.2]-PARACYCLOPHANE ,CTH-(S)-3,5-XYLYL-PHANEPHOS BIS(TRIS(3-(H4-PERFLUORODECYL)PHENYL)PH& ([3,5-BIS(TRIFLUOROMETHYL)PHENYL]IMINO)[TRIS(3-METHYLPHENYL)]PHOSPHORANE (R)-(+)-2,2'-BIS[BIS(3,5-DITRIFLUOROMETHYLPHENYL)PHOSPHINO]-5,5',6,6',7,7',8,8'-OCTAHYDROBINAPHTHYL TRIS-(3-(HEPTADECAFLUOROOCTYL)PHENYL) TRI-P-TOLYLPHOSPHINE, TECH TRIS[3,5-BIS(TRIFLUOROMETHYL)PHENYL]PHOSPHINE TRI-M-TOLYLPHOSPHINE BIS(TRIS(3-(HEPTADECAFLUOROOCTYL)PHE)PHO (S)-(-)-2,2'-BIS[BIS(3,5-DIMETHYLPHENYL)PHOSPHINO]-5,5',6,6',7,7',8,8'-OCTAHYDRO-1,1'-BINAPHTHYL TRIS(4-METHOXY-3,5-DIMETHYLPHENYL)PHOSPHINE TRIS(3,5-DIMETHYLPHENYL)PHOSPHINE DICHLOROBIS(TRI-O-TOLYLPHOSPHINE)PALLADIUM(II) TRI(2,5-XYLYL)PHOSPHINE
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