4-Bromo-1,2-(methylenedioxy)benzene

4-Bromo-1,2-(methylenedioxy)benzene Basic information
Product Name:4-Bromo-1,2-(methylenedioxy)benzene
Synonyms:5-bromobenzo[d][1,3]dioxole;4-BROMO-1,2-(METHYLENEDIOXY)ENZENE;4-Bromo-1,2-methylenedioxybenzene 99%;5-Bromo-1,3-benzodioxole 99%;BROMOBENZODIOXOLE;4-Bromo-1,2-(methylenedioxy)benzene-5;1-Bromo-3,4-(methylenedioxy)benzene 97%;5-Bromo-1,3-benzodioxolane
CAS:2635-13-4
MF:C7H5BrO2
MW:201.02
EINECS:220-123-5
Product Categories:Building Blocks;Chemical Synthesis;Miscellaneous;Organic Building Blocks;Oxygen Compounds;Protected Alcohols/Phenols;Aromatic Hydrocarbons (substituted) & Derivatives;Bromine Compounds;Miscellaneous Compounds;2635-13-4
Mol File:2635-13-4.mol
4-Bromo-1,2-(methylenedioxy)benzene Structure
4-Bromo-1,2-(methylenedioxy)benzene Chemical Properties
Boiling point 85-86 °C1 mm Hg(lit.)
density 1.669 g/mL at 25 °C(lit.)
refractive index n20/D 1.583(lit.)
Fp >230 °F
storage temp. Inert atmosphere,Room Temperature
solubility Chloroform, Methanol (Sparingly)
form Liquid
Specific Gravity1.669
color Clear yellow-orange
BRN 127407
Stability:Light Sensitive
InChIKeyFBOYMIDCHINJKC-UHFFFAOYSA-N
CAS DataBase Reference2635-13-4(CAS DataBase Reference)
NIST Chemistry Reference4-Bromo-1,2-(methylenedioxy)benzene(2635-13-4)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36-37/39
WGK Germany 3
Hazard Note Irritant
HS Code 29329990
MSDS Information
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4-Bromo-1,2-(methylenedioxy)benzene English
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4-Bromo-1,2-(methylenedioxy)benzene Usage And Synthesis
Chemical Propertiesclear yellow-orange liquid
Synthesis Reference(s)Tetrahedron, 64, p. 4999, 2008 DOI: 10.1016/j.tet.2008.03.085
General DescriptionThe coupling of 1-bromo-3,4-(methylenedioxy)benzene with β-methallyl alcohol was catalyzed by Pd(OAc)2 in combination with P(t-Bu)3.
4-Bromo-1,2-(methylenedioxy)benzene Preparation Products And Raw materials
Preparation Products3,4-METHYLENEDIOXYPHENYLBORONIC ACID-->PIPERONALDOXIME-->1-IODO-3,4-METHYLENEDIOXYBENZENE-->5-Bromo-4-iodo-1,3-benzodioxole-->3,4-(METHYLENEDIOXY)THIOPHENOL-->3,4-(Methylenedioxy)aniline
4'-Bromopropiophenone Bromoxynil 1,3-Benzodioxole 3-Bromoanisole Ethylbenzene (3-Methoxyphenyl)acetonitrile Anisole 4-Methoxyphenylacetic acid m-Anisyl alcohol (Trifluoromethoxy)benzene p-Anisic acid 1,2-Dibromobenzene Benzene p-Anisaldehyde Bromine Allylbenzene 3-(Trifluoromethoxy)bromobenzene 1,3-Dibromobenzene

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