|
| | Vat Blue 4 Basic information |
| Product Name: | Vat Blue 4 | | Synonyms: | 14,18-anthrazinetetrone,6,15-dihydro-9;6,15-dihydroanthrazine-5,9,14,18-tetrone;anthraquinonedeepblue;aticvatbluexrn;benzadonebluers;bleusolanthrene;blueanthraquinonepigment;6,15-Dihydro-5,9,14,18-anthrazinetetrone, Pigment Blue 60 | | CAS: | 81-77-6 | | MF: | C28H14N2O4 | | MW: | 442.42 | | EINECS: | 201-375-5 | | Product Categories: | | | Mol File: | 81-77-6.mol |  |
| | Vat Blue 4 Chemical Properties |
| Melting point | 470-500°C | | Boiling point | 553.06°C (rough estimate) | | density | 1.3228 (rough estimate) | | refractive index | 1.5800 (estimate) | | storage temp. | Sealed in dry,Room Temperature | | Colour Index | 69800 | | pka | -1.40±0.20(Predicted) | | form | powder to crystal | | color | Dark red to Dark purple to Dark blue | | Water Solubility | <0.1 g/100 mL at 21 ºC | | Merck | 14,4934 | | Stability: | Incompatible with strong oxidizing agents. | | LogP | 1.78 at 20℃ | | EPA Substance Registry System | C.I. Pigment Blue 60 (81-77-6) |
| | Vat Blue 4 Usage And Synthesis |
| Chemical Properties | blue needles with a metallic lustre | | Uses | Mainly to dye cotton. | | Uses | Indanthrone (Pigment Blue 60) functions as a blue pigment or as a dye. | | Uses | Dinaphtho[2,3-a:2'',3''-h]phenazine-5,9,14,18(6H,15H)-tetraone is a pigment; used in preparation of Polyethylene composite material for outdoor building materials. | | Preparation | (a) in potassium nitrate, LvSuanJia, glucose or organic acid salt (such as formic acid potassium or acetic acid potassium or the mixture of both) under the existence of, with potassium hydroxide treatment 2-Aminoanthracene-9,10-dione; | | Definition | A blue vat dye or pigment. The molecule consists of
two anthraquinone nuclei linked through two –NH
groups. | | Reactions | As a pigment, indanthrone is a particulate, insoluble solid dispersed directly into a vehicle, whereas as a dye it is reduced to a base-soluble hydroquinone derivative and then reoxidized onto a solid substrate. | | General Description | Blue needles with a metallic luster or fine fluffy deep blue powder. | | Air & Water Reactions | Insoluble in water. | | Fire Hazard | Flash point data for Vat Blue 4 are not available. Vat Blue 4 is probably combustible. | | Flammability and Explosibility | Notclassified | | Properties and Applications | red light blue. Slightly soluble in chloroform (heat), o-chlorophenol,Quinoline, insoluble in acetic acid, acetone, ethanol, pyridine, toluene, xylene. The strong sulfuric acid for brown, after diluted blue precipitation; In alkaline insurance powder solution for blue, acidic solutions for the red light in blue. And C.I. Vat ?Blue 4, C.I. Pigment Blue 60 the same chemical structure. | | Purification Methods | Crystallise indanthrene repeatedly from 1,2,4-trichlorobenzene to give a blue powder. It is soluble in alkali and conc H2SO4. [Weinstein & Merritt J Am Chem Soc 81 3759 1959, Beilstein 24 II 317, 24 III/IV 2193.] |
| | Vat Blue 4 Preparation Products And Raw materials |
| Raw materials | Sodium nitrite-->Potassium hydroxide-->Sodium acetate-->Sodium dithionite-->Sodium acetate trihydrate-->Oleic acid-->Sodium nitrate-->2-AMINOANTHRAQUINONE-->Mixed alkalis-->5,9,14,18-Anthrazinetetrone-->2-amino-1-chloroanthraquinone-->2-Imidazolidinone,1,3,4-trimethyl--->1-Aminoanthraquinone-->Naphthalene-->2-AMINOANTHRAQUINONE-->9,10-dihydro-8-nitro-9,10-dioxoanthracene-1-sulphonic acid-->1-amino-2-bromoanthracene-9,10-dione | | Preparation Products | Vat Dark Blue VB-->Vat Blue 14-->Alizarin-->5,9,14,18-Anthrazinetetrol, 6,15-dihydro-, tetrakis(hydrogen sulfate) (ester), tetrasodium salt-->C.I.Vat Blue 10 |
|
