ChemicalBook Product Catalog Organic Chemistry Organometallic compounds Organomagnesium ISOPROPYLMAGNESIUM BROMIDE

ISOPROPYLMAGNESIUM BROMIDE

ISOPROPYLMAGNESIUM BROMIDE Basic information
Product Name:ISOPROPYLMAGNESIUM BROMIDE
Synonyms:Isopropylbromomagnesium;Isopropylmagnesium bromide,3M solution in 2-Methyltetrahydrofuran;Isopropylmagnesium bromide [1M solution in THF];Isopropylmagnesium bromide, 3M solution in 2-Methyltetrahydrofuran, AcroSeal§3;Isopropylmagnesium bromide solution 2.9 M in 2-methyltetrahydrofuran;Isopropylmagnesium bromide, 3M solution in 2-Methyltetrahydrofuran, AcroSeal;IsopropylMagnesiuM broMide solution;BroMoisopropylMagnesiuM
CAS:920-39-8
MF:C3H7BrMg
MW:147.3
EINECS:213-056-8
Product Categories:Grignard Reagents;Grignard Reagents & Alkyl Metals;Mg (Magnesium) Compounds;Synthetic Organic Chemistry;Typical Metal Compounds;Grignard Reagent;Classes of Metal Compounds
Mol File:920-39-8.mol
ISOPROPYLMAGNESIUM BROMIDE Structure
ISOPROPYLMAGNESIUM BROMIDE Chemical Properties
Melting point 114-116℃
Boiling point 148-154℃
density 0.982 g/mL at 25 °C
Fp -17°C
storage temp. 2-8°C
solubility Miscible with tetrahydorfuran and diethyl ether. Immiscible with hydrocarbons.
form Solution
color Clear dark brown or dark gray
Sensitive Air & Moisture Sensitive
InChIKeyUCJIVFREPMUZDC-UHFFFAOYSA-M
EPA Substance Registry SystemMagnesium, bromo(1-methylethyl)- (920-39-8)
Safety Information
Hazard Codes F,C
Risk Statements 11-19-34-14/15-40-37-17-14
Safety Statements 16-26-27-36/37/39-45-43-39-37-36
RIDADR 3399
WGK Germany 2
TSCA Yes
HazardClass 4.3
PackingGroup I
HS Code 29319090
MSDS Information
ISOPROPYLMAGNESIUM BROMIDE Usage And Synthesis
Chemical PropertiesClear dark brown or dark gray solution
UsesIsopropylmagnesium bromide is a Grignard reagent used in organic synthesis, especially for the introduction of iso-propyl group to carbonyl compounds. It is also used as a strong base in aprotic solvent.
UsesGrignard reagent in greener solvent, 2-methyltetrahydrofuran (2-MeTHF)

2-Methyltetrahydrofuran (2-MeTHF): A Biomass-Derived Solvent with Broad Application in Organic Chemistry
General DescriptionThis product, 2.9 M in 2-methyltetrahydrofuran aligns with Safer Solvents and Auxiliaries, Use of Renewable Feedstocks and Inherently Safer Chemistry for Accident Prevention.
ISOPROPYLMAGNESIUM BROMIDE Preparation Products And Raw materials
Preparation Products4-Isopropylaniline-->2,2-DIMETHYL-1-BUTANOL-->4-isobutylaniline-->Isopropylboronic acid-->ISOBUTYLCYCLOBUTANE-->2-Adamantanol-->ISOBUTYRALDEHYDE DIETHYL ACETAL-->4-CHLORO-2,6-DIMETHYLPHENOL-->2-Isopropyl-2-phenylacetic acid-->2-Methyl-1[4-(trifluoromethoxy)phenyl] propan-1-one-->4-bromo-2,6-dimethylbenzoic acid-->3-Methyl-1-butanethiol-->TRIISOPROPYLPHOSPHINE-->DIISOPROPYLCHLOROSILANE-->2-Bromo-2-phenylacetic acid-->ISOPROPYLDIPHENYLPHOSPHINE
1-PROPENYLMAGNESIUM BROMIDE ETHYNYLMAGNESIUM BROMIDE Methylmagnesium Bromide N-PROPYLMAGNESIUM BROMIDE Vinylmagnesium bromide ISOPROPYLMAGNESIUM BROMIDE IN THF CYCLOHEXYLMAGNESIUM BROMIDE BISMUTH TRIBROMOPHENATE ISOPROPYLMAGNESIUM BROMIDE SEC-BUTYLMAGNESIUM BROMIDE 2-ETHYLHEXYLMAGENSIUM BROMIDE (1-Ethylpentyl)magnesium bromide (1-Ethylbutyl)magnesium bromide CYCLOPENTYLMAGNESIUM BROMIDE Cyclopropylmagnesium bromide Diethyl ether 3-PENTYLMAGNESIUM BROMIDE, 2M IN ETHER% Magnesium
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