[1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II)

[1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II) Basic information
Product Name:[1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II)
Synonyms:Chemical Name:1,2-Bis(diphenylphosphino)ethane palladium(II) chloride,98%;Dichloro(1,2-bis(diphenylphosphino)ethane)palladiuM(II),98% (DPPE)PdCl2;[1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II) Dichloro[1,2-bis(diphenylphosphino)ethane]palladium(II);1,2-Bis(diphenylphosphino)ethane palladium (II) dichloride, 98+%;[1,2-Bis(diphenylphosphiNA)ethane]dichloropalladiuM(II);Dichloro(1,2-bis(diphenylphosphino)ethane)palladiuM(II),(DPPE)PdCl2;[1,2-Bis(diphenylphosphino)ethane]dichloropalladiuM(Ⅱ), 19% Pd, Product of UMicore;Dichloro[1,2-bis(diphenylphosphino)ethane]palladiuM(II), Pd 18.5%
CAS:19978-61-1
MF:C26H24Cl2P2Pd
MW:575.74
EINECS:625-508-5
Product Categories:chemical reaction,pharm,electronic,materials;metal-phosphine complexes;Metal Compounds;API intermediates;Catalysts-Ligands;Pd;Catalysts for Organic Synthesis;Classes of Metal Compounds;Homogeneous Catalysts;Metal Complexes;Pd (Palladium) Compounds;Synthetic Organic Chemistry;Transition Metal Compounds;Catalysis and Inorganic Chemistry;Homogeneous Pd Catalysts;Palladium
Mol File:19978-61-1.mol
[1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II) Structure
[1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II) Chemical Properties
Melting point 360 °C
storage temp. Inert atmosphere,Room Temperature
form Powder
color off-white
Water Solubility insoluble
Sensitive Moisture sensitive
InChIInChI=1S/C26H24P2.2ClH.Pd/c1-5-13-23(14-6-1)27(24-15-7-2-8-16-24)21-22-28(25-17-9-3-10-18-25)26-19-11-4-12-20-26;;;/h1-20H,21-22H2;2*1H;/q;;;+2/p-2
InChIKeyLDJXFZUGZASGIW-UHFFFAOYSA-L
SMILESC(P(C1=CC=CC=C1)C1=CC=CC=C1)CP(C1=CC=CC=C1)C1=CC=CC=C1.[Pd](Cl)Cl
CAS DataBase Reference19978-61-1(CAS DataBase Reference)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-37/39
WGK Germany 3
HS Code 28439000
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
ALFA English
[1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II) Usage And Synthesis
Chemical Propertiesorange powder
Uses[1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II) is a precatalyst used in the production of acrylic acid sodium salt via coupling of CO2 with ethene.
suzuki reaction.
reaction suitabilityreaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
core: palladium
PrecautionsThis palladium catalyst, also known as [1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II), presents as a very pale yellow to yellow crystalline powder. Store under inert gas, at ambient temperatures and protected from moisture. This substance is moisture sensitive. [1,2-Bis(diphenylphosphino)ethane]palladium(II) Dichloride is incompatible with oxidizing agents. This chemical is harmful if swallowed, in contact with skin or if inhaled. It causes skin irritation as well as serious eye irritation.
[1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II) Preparation Products And Raw materials
Raw materialsToluene-->Acetonitrile-->Triphenylphosphine-->Lithium-->Palladium chloride
Dichloro(2-pyridinecarboxylato)gold [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) Tetrakis(triphenylphosphine)platinum DICHLORO[1,3-BIS(DIPHENYLPHOSPHINO)PROPANE]PALLADIUM(II) Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) Dichloro(1,5-cyclooctadien)ruthenium(II) polymer Diphenylphosphine ETHANE-D ETHANE Hexafluoroethane [1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II) Diphenylsilane Palladium Chlorodiphenylphosphine 1,2-Bis(diphenylphosphino)ethane Palladium chloride [1,2-BIS(DIPHENYLPHOSPHINO)ETHANE]DICHLOROPALLADIUM(II) 1,5-Diphenylcarbazide

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