Diethyl isopropylidenemalonate

Diethyl isopropylidenemalonate Basic information
Product Name:Diethyl isopropylidenemalonate
Synonyms:DIETHYL ISOPROPYLIDENEMALONATE;Diethyl 2-isopropylidenepropandioate;1-Methylethylidenepropanedioic acid diethyl ester;Diethyl isopropylide;ISOPROPYLIDENEMALONIC ACID DIETHYL ESTER;DIETHYL 2-(1-METHYLETHYLIDENE)MALONATE;Propanedioic acid, 2-(1-Methylethylidene)-, 1,3-diethyl ester;DIETHYL ISOPROPYLIDENEMALONATE FOR SYNTH
CAS:6802-75-1
MF:C10H16O4
MW:200.23
EINECS:229-876-4
Product Categories:TheMalonateRamificationProducts;Aliphatics;Esters;C10 to C11;Carbonyl Compounds
Mol File:6802-75-1.mol
Diethyl isopropylidenemalonate Structure
Diethyl isopropylidenemalonate Chemical Properties
Melting point 93-94 °C
Boiling point 175-178 °C/120 mmHg (lit.)
density 1.021 g/mL at 25 °C (lit.)
refractive index n20/D 1.451(lit.)
Fp 229 °F
storage temp. Sealed in dry,2-8°C
form clear liquid
color Colorless to Almost colorless
Specific Gravity1.021
λmax214nm(EtOH)(lit.)
BRN 1776122
InChIKeyWEISAZNMMVPNTH-UHFFFAOYSA-N
CAS DataBase Reference6802-75-1(CAS DataBase Reference)
NIST Chemistry ReferenceDiethyl isopropylidenemalonate(6802-75-1)
Safety Information
Safety Statements 23-24/25
WGK Germany 3
HS Code 29171900
MSDS Information
ProviderLanguage
SigmaAldrich English
ALFA English
Diethyl isopropylidenemalonate Usage And Synthesis
Chemical PropertiesClear colorless liquid
UsesDiethyl isopropylidenemalonate has been used in the synthesis of retinoids having functional groups at the side-chain terminus.
General DescriptionReduction of diethyl isopropylidenemalonate with sodium borohydride has been reported.
dimethyl isopropylidenemalonate Diethyl Isonitrosomalonate 2-Hydroxyethyl α-bromoisobutyrate Diisopropyl malonate Diethyl dipropylmalonate DIETHYL 2-[2-TRIFLUOROMETHYL-4H-CHROMENE-4-YLIDENE]MALONATE PROPYLMALONIC ACID Diethyl phenylmalonate DIETHYL ISOPROPYLIDENEMALONATE, (ISOPROPYLIDENEMALONIC ACID DIETHYL ESTER) AKOS BC-1761 PROPYLMALONIC ACID Diethyl isopropylidenemalonate DIETHYL ISOPROPYLIDENEMALONATE (IPEM) Diethyl methylmalonate Ethyl hydrogen malonate AKOS BC-0585 Diethyl allylmalonate TETRAETHYL ETHYLENETETRACARBOXYLATE

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