1-NAPHTHYLMAGNESIUM BROMIDE

1-NAPHTHYLMAGNESIUM BROMIDE Basic information
Product Name:1-NAPHTHYLMAGNESIUM BROMIDE
Synonyms:1-NAPHTHYLMAGNESIUM BROMIDE;1-NAPTHYLMAGNESIUM BROMIDE, 0.25M SOLUTION IN TETRAHYDROFURAN;1-naphthylmagnesium bromide solution;1-NAPHTHYLMAGNESIUM BROMIDE, 0.25M SOLUTION IN THF;(1-Naphthyl)bromomagnesium;1-Naphthylbromomagnesium;Bromo(1-naphthalenyl)magnesium;Bromo(1-naphthyl)magnesium
CAS:703-55-9
MF:C10H7BrMg
MW:231.37
EINECS:
Product Categories:Aryl;Grignard Reagents;Organometallic Reagents
Mol File:703-55-9.mol
1-NAPHTHYLMAGNESIUM BROMIDE Structure
1-NAPHTHYLMAGNESIUM BROMIDE Chemical Properties
Boiling point 65 °C
density 0.908 g/mL at 25 °C
Fp -17 °C
storage temp. water-free area
Sensitive Air & Moisture Sensitive
EPA Substance Registry SystemMagnesium, bromo-1-naphthalenyl- (703-55-9)
Safety Information
Hazard Codes F,C,Xn
Risk Statements 11-14-19-22-34-40-36/37/38
Safety Statements 16-26-33-36/37/39-45-36/37
RIDADR UN 2924 3/PG 2
WGK Germany 1
TSCA Yes
HazardClass 3
HS Code 29319090
MSDS Information
ProviderLanguage
SigmaAldrich English
1-NAPHTHYLMAGNESIUM BROMIDE Usage And Synthesis
Chemical PropertiesLight yellow to yellow slurry or solution
Uses1-Naphthylmagnesium bromide can be used:
  • To prepare unsymmetrical chiral diene ligands, which are applicable in asymmetric transformation reactions.
  • As a starting material in the synthesis of methyl (2Z,4E)-2-methylsulfanyl-5-(1-naphthyl)-4-nitro-2,4-pentadienoate, a naphthylnitrobutadiene based anti-proliferative compound.

2-BUTENYLMAGNESIUM CHLORIDE 1-PROPYNYLMAGNESIUM BROMIDE Hexylmagnesium chloride 2,6-DIMETHYLPHENYLMAGNESIUM BROMIDE 1-PROPENYLMAGNESIUM BROMIDE 2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex 2,5-DIMETHYLPHENYLMAGNESIUM BROMIDE 1-METHYL-1-PROPENYLMAGNESIUM BROMIDE 6-METHOXY-2-NAPHTHYLMAGNESIUM BROMIDE 4-FLUORO-1-NAPHTHYLMAGNESIUM BROMIDE,4-FLUORO-1-NAPHTHYLMAGNESIUM BROMIDE .024M IN TETRAHYDROFURAN 4-METHYL-1-NAPHTHYLMAGNESIUM BROMIDE, 0.25 M SOLUTION IN TETRAHYDROFURAN,4-METHYL-1-NAPHTHYLMAGNESIUM BROMIDE 6-METHOXY-2-NAPHTHYLMAGNESIUM BROMIDE, 0.5 M SOLUTION IN THF,6-methoxy-2-naphthylmagnesium bromide solution 1-NAPHTHYLMAGNESIUM BROMIDE 2-naphthylmagnesium bromide solution,2-NAPHTHYLMAGNESIUM BROMIDE, 0.5M SOLUTION IN TETRAHYDROFURAN,2-NAPHTHYLMAGNESIUM BROMIDE 9-PHENANTHRYLMAGNESIUM BROMIDE 2-METHYL-1-NAPHTHYLMAGNESIUM BROMIDE,2-METHYL-1-NAPHTHYLMAGNESIUM BROMIDE,0.25M SOLUTION IN TETRAHYDROFURAN 5-ACENAPHTHYLMAGNESIUM BROMIDE 2-METHOXY-1-NAPHTHYLMAGNESIUM BROMIDE

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