METHYL (PHENYLSULFINYL)ACETATE

METHYL (PHENYLSULFINYL)ACETATE Basic information
Product Name:METHYL (PHENYLSULFINYL)ACETATE
Synonyms:METHYL 2-(PHENYLSULFINYL)ACETATE;METHYL (PHENYLSULFINYL)ACETATE;methyl (phenylsulphinyl)acetate;methyl 2-(phenylsulphinyl)acetate;METHYL (+/-)-(PHENYLSULFINYL)ACETATE, 98 %;Acetic acid, (phenylsulfinyl)-, methyl ester;Methyl 2-phenylsulfinylacetate 98%;(Phenylsulfinyl)acetic acid methyl ester
CAS:14090-83-6
MF:C9H10O3S
MW:198.24
EINECS:237-936-6
Product Categories:Organic Building Blocks;Sulfoxides;Sulfur Compounds;Building Blocks;Chemical Synthesis;Organic Building Blocks;Sulfur Compounds
Mol File:14090-83-6.mol
METHYL (PHENYLSULFINYL)ACETATE Structure
METHYL (PHENYLSULFINYL)ACETATE Chemical Properties
Melting point 52-54 °C(lit.)
Boiling point 130-131 °C0.5 mm Hg(lit.)
density 1.3339 (rough estimate)
refractive index 1.5250 (estimate)
Fp >230 °F
BRN 1953383
Safety Information
Safety Statements 22-24/25
WGK Germany 3
MSDS Information
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SigmaAldrich English
METHYL (PHENYLSULFINYL)ACETATE Usage And Synthesis
UsesUndergoes condensation reactions with aldehydes to form vinylic sulfoxides.1
UsesAnion of methyl 2-phenylsulfinylacetate has been employed in the synthesis of α,β-unsaturated esters.
General DescriptionAnion of methyl 2-phenylsulfinylacetate undergoes facile alkylative elimination under solid-liquid phase-transfer conditions to afford ring-substituted cinnamates. Methyl 2-phenylsulfinylacetate undergoes condensation reactions with aldehydes to form vinylic sulfoxides.
METHYL (PHENYLSULFINYL)ACETATE Preparation Products And Raw materials
ETHYL 3-((4-ETHOXYPHENYL)AMINO)-2-((4-METHYLPHENYL)SULFONYL)PROP-2-ENOATE 3-((4-CHLOROPHENYL)SULFONYL)-6,8-DIIODO-2H-CHROMEN-2-ONE 3-(P-TOLYL SULFONYL)ACETYLCOUMARIN (4-HYDROXY-BENZENESULFONYL)-ACETIC ACID ETHYL ESTER ETHYL 1-BENZYL-4-[(4-METHOXYPHENYL)SULFONYL]-4-PIPERIDINECARBOXYLATE BUTTPARK 52\04-50 BUTTPARK 52\04-47 BUTTPARK 52\04-48 ETHYL 2-[(4-METHYLPHENYL)SULFONYL]ACETATE ETHYL 2-[(4-CHLOROPHENYL)SULPHONYL]ACETATE METHYL (PHENYLSULFINYL)ACETATE ETHYL-A-(4-ACETAMIDOPHENYLSULFONYL)ACETATE ETHYL 1-(4-METHYLBENZYL)-4-(PHENYLSULFONYL)-4-PIPERIDINECARBOXYLATE ETHYL 4-[(4-METHOXYPHENYL)SULFONYL]-1-(4-METHYLBENZYL)-4-PIPERIDINECARBOXYLATE ETHYL 1-(4-METHOXYBENZYL)-4-[(4-METHOXYPHENYL)SULFONYL]-4-PIPERIDINECARBOXYLATE 1-ETHOXYCARBONYL-1-TOSYLMETHYL ISOCYANIDE 6,8-DIIODO-3-((4-(TRIFLUOROMETHOXY)PHENYL)SULFONYL)-2H-CHROMEN-2-ONE ETHYL 1-BENZYL-4-[(4-CHLOROPHENYL)SULFONYL]-4-PIPERIDINECARBOXYLATE

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