Titanium ethoxide

Titanium ethoxide Basic information
Product Name:Titanium ethoxide
Synonyms:ETHYL TITANATE;ETHYL TITANATE(IV);ETHYL ORTHOTITANATE;TETRAETHYL TITANATE;TETRAETHYL ORTHOTITANATE;Tetraethoxy titanium;ORTHOTITANIC ACID TETRAETHYL ESTER;VERTEC(TM) ET
CAS:3087-36-3
MF:C8H20O4Ti
MW:228.11
EINECS:221-410-8
Product Categories:Pyrazoles;metal alkoxide;Catalysts for Organic Synthesis;Classes of Metal Compounds;Homogeneous Catalysts;Synthetic Organic Chemistry;Organic-metal salt;Ti (Titanium) Compounds;Titanium Alkoxides, etc. (Homogeneous Catalysts);Transition Metal Compounds;bc0001
Mol File:3087-36-3.mol
Titanium ethoxide Structure
Titanium ethoxide Chemical Properties
Melting point 54°C
Boiling point 150-152 °C10 mm Hg(lit.)
density 1.088 g/mL at 25 °C(lit.)
vapor pressure 57.26hPa at 19.6℃
refractive index n20/D 1.505(lit.)
Fp 84 °F
storage temp. 2-8°C
solubility Soluble in organic solvents.
form Liquid
Specific Gravity1.107 (20℃)
color Pale yellow
Water Solubility reacts
Sensitive Moisture Sensitive
BRN 3678992
Exposure limitsACGIH: TWA 200 ppm; STEL 400 ppm
OSHA: TWA 400 ppm(980 mg/m3)
NIOSH: IDLH 2000 ppm; TWA 400 ppm(980 mg/m3); STEL 500 ppm(1225 mg/m3)
Stability:Stability Incompatible with strong oxidizing agents, strong acids. May decompose upon exposure to air or moisture.
InChIKeyJMXKSZRRTHPKDL-UHFFFAOYSA-N
LogP-0.3 at 25℃
CAS DataBase Reference3087-36-3(CAS DataBase Reference)
NIST Chemistry ReferenceTi(OEt)4(3087-36-3)
EPA Substance Registry SystemEthanol, titanium(4+) salt (3087-36-3)
Safety Information
Hazard Codes Xi
Risk Statements 10-36/37/38-67
Safety Statements 26-37/39-16
RIDADR UN 1993 3/PG 3
WGK Germany 3
3-10-21
TSCA Yes
HazardClass 4.1
PackingGroup III
HS Code 29051900
MSDS Information
ProviderLanguage
Ethyl titanate English
ACROS English
SigmaAldrich English
ALFA English
Titanium ethoxide Usage And Synthesis
Chemical Propertiescolourless liquid
UsesTitanium(IV) ethoxide is used in organic synthesis and material science. It is involved in the synthesis of anti-perspirants and antifungal agents. Furthermore, it is used to prepare carbon films in association with silicon dioxide. It is also used as a precursor for the synthesis of Ti4+ ions titanium nanoparticles by various methods.
UsesTitanium ethoxide is used widely as a precursor for the synthesis of Ti4+ ions titania nanoparticles by various techniques such as :
  • in the sol-gel synthesis of free-standing ferroelectric lead zirconate titanate nanoparticles
  • spherical titania cores, produced either by hydrolysis of Ti(IV) ethoxide droplets in contact with water vapor or
  • by preadsorption of the titanium alkoxides into/onto the clay mineral platelets and their subsequent hydrolysis and calcination.
UsesTitanium(IV) ethoxide can be used:
  • As an activator and dehydrating agent for by condensation of (S)-(+)-p-toluenesulfinamide with aldehydes and ketones to form sulfinimines.
  • As a Ti4+ ion source to form complexes of titanium (IV) acrylate with methacrylic acid.
  • As a catalyst to synthesize esters of sterically hindered alcohols via transesterification reactions.

ApplicationTitanium(IV) ethoxide can be used:
As an activator and dehydrating agent for by condensation of (S)-(+)-p-toluenesulfinamide with aldehydes and ketones to form sulfinimines.
As a Ti4+ ion source to form complexes of titanium (IV) acrylate with methacrylic acid.
As a catalyst to synthesize esters of sterically hindered alcohols via transesterification reactions.
Flammability and ExplosibilityFlammable
Materials UsesTitanium ethoxide is used widely as a precursor for the synthesis of Ti4+ ions titania nanoparticles by various techniques such as :
in the sol-gel synthesis of free-standing ferroelectric lead zirconate titanate nanoparticles
spherical titania cores, produced either by hydrolysis of Ti(IV) ethoxide droplets in contact with water vapor or
by preadsorption of the titanium alkoxides into/onto the clay mineral platelets and their subsequent hydrolysis and calcination.
Barium titanate Phenetidine Titanium TEPP TITANIUM Ethanol Ethyl pyruvate Tetraethyl orthosilicate Titanate coupler Lithium titanate, nanopowder Ethylparaben Titanium ethoxide Ethoxyquin ISOXADIFEN-ETHYL Ethyl oleate Ethyl acrylate Diethoxymethyl acetate Ethyl cyanoacetate

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