TETRAKIS(ACETONITRILE)PALLADIUM(II) TETRAFLUOROBORATE

TETRAKIS(ACETONITRILE)PALLADIUM(II) TETRAFLUOROBORATE Basic information
Product Name:TETRAKIS(ACETONITRILE)PALLADIUM(II) TETRAFLUOROBORATE
Synonyms:Tetrakis(acetonitrile)palladium(II)tetrafluoroborate,99%;TETRAKIS(ACETONITRILE)PALLADIUM(II) TETRAFLUOROBORATE;TETRAKIS(ACETONITRILE)PALLADIUM(II) BIS(TETRAFLUOROBORATE);PALLADIUM(II) TETRAFLUOROBORATE-TETRAACETONITRILE COMPLEX;TETRAKIS(ACETONITRILE)PALLADIUM(II) TETRAFLUOROBORATE (30%PD);Tetrakis(acetonitrile)palladium(II) tetrafluoroborate, Pd 23.9%;Tetrakis(acetonitrile)palladiuM(II) tetrafluoroborate, 99% 1GR;NSC 307191
CAS:21797-13-7
MF:C8H12BF4N4Pd+
MW:357.44
EINECS:
Product Categories:Pd;organometallic complex
Mol File:21797-13-7.mol
TETRAKIS(ACETONITRILE)PALLADIUM(II) TETRAFLUOROBORATE Structure
TETRAKIS(ACETONITRILE)PALLADIUM(II) TETRAFLUOROBORATE Chemical Properties
Melting point 230 °C (dec.) (lit.)
storage temp. Inert atmosphere,2-8°C
form Powder
color Yellow
Water Solubility Soluble in water
Sensitive Air Sensitive
Safety Information
Hazard Codes Xn
Risk Statements 20
Safety Statements 22-36/37/39-38
RIDADR UN2811
WGK Germany 3
HazardClass 6.1
PackingGroup III
HS Code 29310099
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
ALFA English
TETRAKIS(ACETONITRILE)PALLADIUM(II) TETRAFLUOROBORATE Usage And Synthesis
Chemical PropertiesYellow powder
UsesTetrakis(acetonitrile)palladium Bis(tetrafluoroborate) is used to prepare an α-Diimine-transition metal complex, which is used as a catalyst for polymerization of olefins. It is also a catalyst used in cross coupling reaction for C-C, C-O, and C-N bond formation.
UsesApplication Guide for Palladium Catalyzed Cross-Coupling Reactions

Reactant involved in:
  • Reactions where it plays a role as the metal source due to weakly coordinated acetonitrile ligands

Precursor for:
  • Synthesis of dendritic SCS-pincer palladium complexes
  • Palladium complexes of click ligands
  • Dipalladium catalysts for use in Heck cross-coupling, Suzuki cross-coupling, and aldehyde olefination
General DescriptionTetrakis(acetonitrile)palladium(II) tetrafluoroborate is a stronger Lewis acid. It participates in the preparation of 2:1 complex [Pd(1,2-bis(2′-pyridylethynyl)benzene)2](BF4]2, by Sonogashira cross-coupling reaction.
TETRAKIS(ACETONITRILE)PALLADIUM(II) TETRAFLUOROBORATE Preparation Products And Raw materials
TETRAKIS(ACETONITRILE)SILVER(I) TETRAFLUOROBORATE tetrakis(acetonitrile)copper(I) trifluoromethanesulfonate hemihydrate Tetrakis(acetonitrile)copper(I) tetrafluoroborate TETRAKIS(ACETONITRILE)PALLADIUM(II) TETRAFLUOROBORATE Acetonitrile Fluoroboric acid

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