ChemicalBook Product Catalog Organic Chemistry Organometallic compounds Organic palladium Bis(2,4-pentanedionato-O,O')palladium(II)

Bis(2,4-pentanedionato-O,O')palladium(II)

Bis(2,4-pentanedionato-O,O')palladium(II) Basic information
Product Name:Bis(2,4-pentanedionato-O,O')palladium(II)
Synonyms:ACETYLACETONE, PALLADIUM(II) DERIVATIVE;ACETYLACETONE PALLADIUM(II) SALT;Palladium acetylacetonate or Palladium(II)2,4-pentanedionate;Bis(acetylacetonato)palladium(II) dec. 205 halide free source of Pd;bis(2,4-pentanedionato-o,o')palladium(ii);BIS(2,4-PENTANEDIONATO)PALLADIUM(II);BIS(ACETYLACETONATO)PALLADIUM(II);Bis(2,4-pentanedionato-O,O')palladium(II),99%
CAS:14024-61-4
MF:C10H14O4Pd
MW:304.64
EINECS:237-859-8
Product Categories:metal beta-diketonate complexes;Catalysts for Organic Synthesis;Classes of Metal Compounds;Homogeneous Catalysts;Metal Complexes;Pd (Palladium) Compounds;Synthetic Organic Chemistry;Transition Metal Compounds;chemical reaction,pharm,electronic,materials;Pd
Mol File:14024-61-4.mol
Bis(2,4-pentanedionato-O,O')palladium(II) Structure
Bis(2,4-pentanedionato-O,O')palladium(II) Chemical Properties
Melting point 190 °C
vapor pressure 0Pa at 25℃
storage temp. Store below +30°C.
solubility Soluble in benzene and chloroform.
form Solution
color Yellow to orange
Specific Gravity1.862
Water Solubility INSOLUBLE
Hydrolytic Sensitivity4: no reaction with water under neutral conditions
BRN 4136188
InChIKeyRJJXYEQOOACRKP-LNKPDPKZSA-M
LogP2.6 at 25℃
NIST Chemistry ReferenceBis(acetylacetonato)palladium(14024-61-4)
EPA Substance Registry SystemPalladium, bis(2,4-pentanedionato-.kappa.O,.kappa.O')-, (SP-4-1)- (14024-61-4)
Safety Information
Hazard Codes Xi,Xn
Risk Statements 36-36/37/38-22
Safety Statements 26-37/39
RIDADR 3181
WGK Germany 2
TSCA Yes
HS Code 28439090
MSDS Information
ProviderLanguage
Bis(2,4-pentanedionato-O,O')palladium(II) English
SigmaAldrich English
ACROS English
ALFA English
Bis(2,4-pentanedionato-O,O')palladium(II) Usage And Synthesis
Chemical Propertiesyellow orange needles
UsesPalladium(II) Acetylacetonate is an active anticancer agent. Exhibits growth inhibitory effect more than cisplatin in several cancer cells and treatment with Palladium(II) Acetylacetonate inhibits H460 cells. Palladium(II) Acetylacetonate is a catalyst for various organic transformations.
UsesPalladium(II) acetylacetonate (Pd(acac)2) was used in the following studies:
  • Typical high-temperature organic solution phase protocol for the preparation of monodisperse CuPd alloy nanoparticles (NPs).
  • Preparation of [(NHC)Pd(acac)L] (where L=Me, NHC = N-heterocyclic carbene) complexes. These complexes efficiently catalyze the Heck reaction of activated aryl bromides.
  • As catalyst in the decarboxylative cross-coupling of arylcarboxylic acids with aryl halides.
General DescriptionPalladium(II) acetylacetonate (Pd(acac)2) is a metal-organic complex. Sublimation of Pd(acac)2 has been investigated by thermogravimetry and XRD. The temperature range for the sublimation of Pd(acac)2, without undergoing thermal decomposition, was determined to be 100-160°C in the presence of inert gas helium.
Flammability and ExplosibilityHighlyflammable
Purification MethodsIt can be recrystallised from *C6H6/pet ether and sublimes in vacuo. It is soluble in heptane, *C6H6 (1.2% at 20o, 2.2 at 40o), toluene (0.56% at 20o, 1.4% at 40o) and acetylacetone (1.2% at 20o, 0.05% at 40o). [West & Riley J Inorg Nucl Chem 5 295 1957/8, Fernelius & Bryant Inorg Synth V 105 1957, Beilstein 1 IV 3676.]
Bis(2,4-pentanedionato-O,O')palladium(II) Preparation Products And Raw materials
Raw materialsToluene-->Acetonitrile-->Acetylacetone-->Palladium chloride-->1,3-Dichloropropane
1-BUTENE TRANS-2-PENTENE Acrolein Propane Ethanol Palladium hydroxide Crotonaldehyde PROPYLENE Bis(2,4-pentanedionato-O,O')palladium(II) Formaldehyde vinyl alcohol Palladium Water METHANOL WITH FORMALDEHYDE Methanol Methyl vinyl ketone Acetaldehyde PALLADIUM(II) HEXAFLUOROACETYLACETONATE
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