ETHYL PHENYLCYANOACETATE

ETHYL PHENYLCYANOACETATE Basic information
Product Name:ETHYL PHENYLCYANOACETATE
Synonyms:RARECHEM AK ML 0109;PHENYLCYANOACETIC ACID ETHYL ESTER;ETHYL 2-CYANO-2-PHENYLACETATE;ETHYL PHENYLCYANOACETATE;Acetic acid, cyanophenyl-, ethyl ester;Ethyl alpha-cyano-alpha-phenylacetate;Ethyl alpha-cyanophenylacetate;Ethyl cyanophenylacetate
CAS:4553-07-5
MF:C11H11NO2
MW:189.21
EINECS:224-921-4
Product Categories:Building Blocks;C10 to C11;Carbonyl Compounds;Chemical Synthesis;Organic Building Blocks;Aliphatics;Esters;C10 to C11;Carbonyl Compounds
Mol File:4553-07-5.mol
ETHYL PHENYLCYANOACETATE Structure
ETHYL PHENYLCYANOACETATE Chemical Properties
Melting point 115-116 °C
Boiling point 275 °C (lit.)
density 1.09 g/mL at 25 °C (lit.)
refractive index 1.5033-1.5053
Fp >110°C
storage temp. Inert atmosphere,Room Temperature
solubility Chloroform, DMSO, Methanol (Slightly)
form Liquid
color Clear colorless to light yellow
BRN 611232
CAS DataBase Reference4553-07-5(CAS DataBase Reference)
Safety Information
Hazard Codes Xn
Risk Statements 20/21-36/37/38-20/21/22
Safety Statements 23-37/39-26
RIDADR UN3276
WGK Germany 3
HazardClass 6.1
PackingGroup III
HS Code 29269095
MSDS Information
ProviderLanguage
ACROS English
ALFA English
ETHYL PHENYLCYANOACETATE Usage And Synthesis
Chemical Propertiesclear colorless to light yellow liquid
UsesEthyl phenylcyanoacetate?is a reagent used for the asymmetric synthesis of?(-)-manzacidin A.?It is also a useful reagent for C-C bond formation by conjugate additions with vinyl sulfones.
DefinitionChEBI: An alpha-substituted cyanoacetate ester that consists of ethyl cyanoacetate bearing an alpha-phenyl substituent.
Synthesis Reference(s)Journal of the American Chemical Society, 64, p. 576, 1942 DOI: 10.1021/ja01255a033
Organic Syntheses, Coll. Vol. 4, p. 461, 1963
Synthesis, p. 67, 1983
ETHYL PHENYLCYANOACETATE Preparation Products And Raw materials
ETHYL 2-CYANO-2-(4-NITROPHENYL)ACETATE RARECHEM AK ML 0154 ETHYL 2-CYANO-2-(2-NITROPHENYL)ACETATE RARECHEM AK ML 0162 RARECHEM AK ML 0163 RARECHEM AK ML 0151 RARECHEM AK ML 0106 ETHYL 2-CYANO-2-[2-NITRO-5-(TRIFLUOROMETHYL)PHENYL]ACETATE RARECHEM AK ML 0165 RARECHEM AK ML 0164 RARECHEM AK ML 0112 RARECHEM AK ML 0150 RARECHEM AK ML 0169 RARECHEM AK ML 0160 ETHYL ALPHA-CYANO-2-NITRO-4-(TRIFLUOROMETHYL)PHENYLACETATE RARECHEM AK ML 0156 Ethylphenylcyano-acetic acid ethyl ester RARECHEM AK ML 0122

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