ACETYLACETONATO(1,5-CYCLOOCTADIENE)RHODIUM(I)

ACETYLACETONATO(1,5-CYCLOOCTADIENE)RHODIUM(I) Basic information
Reactions
Product Name:ACETYLACETONATO(1,5-CYCLOOCTADIENE)RHODIUM(I)
Synonyms:(1,5-Cyclooctadiene)rhodium(I) 2,4-pentanedionate;(1,5-cyclooctadiene)(2,4-pentanedionato)rhodium(I);Acetylacetonato(1,5-cyclooctadiene)rhodium(I),97%;Acetylacetonato(1,5-;(Acetylacetonato)(1,5-cyclooctadiene)rhodium(Ⅰ);NSC 240030;RHODIUM (1,5-CYCLOOCTADIENE)-2,4-PENTANEDIONATE;((1,2,5,6-eta)-1,5-cyclooctadiene)(2,4-pentanedionato-o,o’)-rhodiu
CAS:12245-39-5
MF:C13H19O2Rh
MW:310.19
EINECS:
Product Categories:organometallic complex;Rh
Mol File:12245-39-5.mol
ACETYLACETONATO(1,5-CYCLOOCTADIENE)RHODIUM(I) Structure
ACETYLACETONATO(1,5-CYCLOOCTADIENE)RHODIUM(I) Chemical Properties
Melting point 138-140 °C(lit.)
storage temp. Inert atmosphere,2-8°C
form Crystals
color Yellow to orange
Hydrolytic Sensitivity8: reacts rapidly with moisture, water, protic solvents
Sensitive Air Sensitive
Exposure limitsACGIH: TWA 1 mg/m3
NIOSH: IDLH 100 mg/m3; TWA 0.1 mg/m3
InChIKeyWDIAJTWVVLHUJU-SUESZSCISA-N
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-37/39
WGK Germany 3
RTECS VI9292000
TSCA No
HS Code 28439000
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
ACETYLACETONATO(1,5-CYCLOOCTADIENE)RHODIUM(I) Usage And Synthesis
Reactions
  1. Precursor for asymmetric hydrogenation reactions.
  2. Rh-catalyzed carbozincation of ynamides. 
Reactions of 12245-39-5
Chemical PropertiesOrange crystal
UsesUmicore Precatalysts for Asymmetric and Cross-Coupling Catalysis
General DescriptionAtomic number of base material: 45 Rhodium
Safety ProfilePoison by intraperitoneal route. When heated to decomposition it emits toxic fumes of Rh
ACETYLACETONATO(1,5-CYCLOOCTADIENE)RHODIUM(I) Preparation Products And Raw materials
1,5-CYCLOOCTADIENE Acetylacetone ACETYLACETONATO(1,5-CYCLOOCTADIENE)RHODIUM(I) Acetylacetonatobis(ethylene)rhodium(I) 1,5-Cyclooctadiene

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