TETRAPROPYLAMMONIUM PERRUTHENATE

TETRAPROPYLAMMONIUM PERRUTHENATE Basic information
Uses
Product Name:TETRAPROPYLAMMONIUM PERRUTHENATE
Synonyms:TETRAPROPYLAMMONIUM PERRUTHENATE;TETRA-N-PROPYLAMMONIUM PERRUTHENATE (VII);TerapropylaMMoniuMperruthenate;TetrapropylaMMoniuM perruthenate,97% TPAP, (n-C3H7)4NRuO4;TetrapropylaMMoniuM perruthenate,TPAP,(n-C3H7)NRuO4;TetrapropylaMMoniuM perruthenate 97%;Tetrapropylammonium perruthenate, min. 97%;Tetrapropylammoniumperruthenate,min.97%TPAP
CAS:114615-82-6
MF:C12H28NO4Ru
MW:351.43
EINECS:628-415-8
Product Categories:Boron, Nitrile, Thio,& TM-Cpds;Ammonium Polyhalides, etc. (Quaternary);Catalysts for Organic Synthesis;Classes of Metal Compounds;Environmentally-friendly Oxidation;Homogeneous Catalysts;Metal Complexes;Oxidation;Quaternary Ammonium Compounds;Ru (Ruthenium) Compounds;Synthetic Organic Chemistry;Transition Metal Complexes (Environmentally-friendly Oxidation);Transition Metal Compounds;Ru;Alkylammonium salt
Mol File:114615-82-6.mol
TETRAPROPYLAMMONIUM PERRUTHENATE Structure
TETRAPROPYLAMMONIUM PERRUTHENATE Chemical Properties
Melting point ~160 °C (dec.) (lit.)
storage temp. Inert atmosphere,2-8°C
solubility Methanol (Slightly)
form crystal
color green
Water Solubility Insoluble in water.
Sensitive Hygroscopic
Stability:store cold
InChIKeyNQSIKKSFBQCBSI-UHFFFAOYSA-N
Safety Information
Hazard Codes O,Xi
Risk Statements 5-8-36/37/38
Safety Statements 17-26-36
RIDADR UN 1479 5.1/PG 2
WGK Germany 3
3-10
HazardClass 5.1
PackingGroup III
HS Code 28439000
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
ALFA English
TETRAPROPYLAMMONIUM PERRUTHENATE Usage And Synthesis
UsesA mild oxidant for the selective transformation of primary alcohols to aldehydes and secondary alcohols to ketones.
Chemical Propertiesdark green solid
UsesTetrapropylammonium Perruthenate is used in sustainable oxidation reactions and has potential for chemical recycling.
DefinitionChEBI: A quaternary ammonium salt having tetrapropylammonium as the cation and perruthenate as the anion.
General DescriptionTetrapropylammonium perruthenate is a mild oxidizing agent used for the oxidation of alcohols to corresponding carbonyl compounds. It is a non-volatile, air-stable, and readily soluble reagent, which can be used either stoichiometrically or catalytically with a suitable co-oxidant.
Purification MethodsIt is a strong oxidant and may explode on heating. It can be washed with aqueous n-propanol, then H2O and dried over KOH in a vacuum. It is stable at room temperature but best stored in a refrigerator. It is soluble in CH2Cl2 and MeCN. [Dengel et al. Transition Met Chem 10 98 1985, Griffith et al. J Chem Soc, Chem Commun 1625 1987.] § Polymer supported reagent is available commercially.
Tetrakis-(u-acetato-O,O'')-diruthenium Tetrapropylammonium bromide Tetrapropylammonium hydroxide 1 4-BIS(DIPHENYLAMINO)BENZENE Oxalyl chloride Dodecyltrimethylammonium Bromide Zinc peroxide TETRAPROPYLAMMONIUM PERRUTHENATE Ruthenium dioxide Ruthenium

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