ChemicalBook Product Catalog Organic Chemistry Phosphines (TRIPHENYLPHOSPHORANYLIDENE)ACETONITRILE

(TRIPHENYLPHOSPHORANYLIDENE)ACETONITRILE

(TRIPHENYLPHOSPHORANYLIDENE)ACETONITRILE Basic information
Product Name:(TRIPHENYLPHOSPHORANYLIDENE)ACETONITRILE
Synonyms:(TRIPHENYLPHOSPHORANYLIDENE)ACETONITRILE;Cyanomethylene triphenylphosphorane, min. 97 %;Triphenyl(cyanomethylene)phosphorane;(Triphenylphosphoranylidene)acetonitrile,96%;(Triphenylphosphoranylidene)acetonitrile,(Cyanomethylene)triphenylphosphorane;Cyanomethyltriphenylphosphonium ylide;NSC 135204;Triphenylphosphoranylidenacetonitrile
CAS:16640-68-9
MF:C20H16NP
MW:301.32
EINECS:240-689-7
Product Categories:Synthetic Organic Chemistry;Wittig & Horner-Emmons Reaction;Wittig Reaction
Mol File:16640-68-9.mol
(TRIPHENYLPHOSPHORANYLIDENE)ACETONITRILE Structure
(TRIPHENYLPHOSPHORANYLIDENE)ACETONITRILE Chemical Properties
Melting point 189-195 °C (lit.)
Boiling point 465.3±28.0 °C(Predicted)
density 1.16±0.1 g/cm3(Predicted)
Fp >110°C
storage temp. Keep in dark place,Sealed in dry,Room Temperature
form powder to crystal
color White to Orange to Green
InChIKeyAPISVOVOJVZIBA-UHFFFAOYSA-N
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36
RIDADR UN 2811 6.1/PG III
WGK Germany 3
Hazard Note Irritant
HazardClass 6.1
PackingGroup III
HS Code 29319090
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
(TRIPHENYLPHOSPHORANYLIDENE)ACETONITRILE Usage And Synthesis
Chemical Propertiesoff-white to light yellow crystalline powder
Uses(Triphenylphosphoran?ylidene)?acetonitrile is a reactant in the synthesis of largazole analogues which displays potent cell growth inhibition and cytotoxicity. As well, is used in the synthesis of monoterpene derivatives against leukemia.
(TRIPHENYLPHOSPHORANYLIDENE)ACETONITRILE Preparation Products And Raw materials
Preparation ProductsTRIPHENYLPHOSPHINE SELENIDE-->1-Pyrenecarboxaldehyde-->TRIPHENYLPHOSPHINE SULFIDE-->Fumaronitrile
SALOR-INT L152099-1EA (TRIPHENYLPHOSPHORANYLIDENE)ACETONITRILE 2-(4-OXO-4,5-DIHYDRO-1,3-THIAZOL-2-YL)-2-(1,1,1-TRIPHENYL-LAMBDA5-PHOSPHANYLIDENE)ACETONITRILE SALOR-INT L152234-1EA (4-OXO-2-(TRICHLOROMETHYL)-3,4-DIHYDRO-2H-1,3,5-THIADIAZIN-6-YL)(TRIPHENYL-LAMBDA5-PHOSPHANYL)ACETONITRILE
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