BIS(TRICYCLOHEXYLPHOSPHINE)[(PHENYLTHIO)METHYLENE]RUTHENIUM (IV) DICHLORIDE

BIS(TRICYCLOHEXYLPHOSPHINE)[(PHENYLTHIO)METHYLENE]RUTHENIUM (IV) DICHLORIDE Basic information
Reactions
Product Name:BIS(TRICYCLOHEXYLPHOSPHINE)[(PHENYLTHIO)METHYLENE]RUTHENIUM (IV) DICHLORIDE
Synonyms:Bis(tricyclohexylphosphine)[(phenylthio)methylene]ruthenium(II)dichloride,min.97%;Bis(tricyclohexylphosphine)[(phenylthio)Methylene]rutheniuM (II) dichloride,97%;Bis(tricyclohexylphosphine)[(phenylthio)methylene]ruthenium(II) dichloride, min. 97%;Bis(tricyclohexylphosphine)[(phenylthio)methylene]ruthenium(IV) dichloride,97%;Dichloro[(phenylthio)methylene]bis(tricyclohexylphosphine)ruthenium;Bis(tricyclohexylphosphine)[(phenylthio)methylene]ruthenium (II) dichloride;BIS(TRICYCLOHEXYLPHOSPHINE)[(PHENYLTHIO)METHYLENE]RUTHENIUM (IV) DICHLORIDE;Bis(tricyclohexylphosphine)[(phenylthio)methylene]ruthenium(II)
CAS:219770-99-7
MF:C43H72Cl2P2RuS
MW:855.02
EINECS:
Product Categories:metal-phosphine complexes;Ru
Mol File:219770-99-7.mol
BIS(TRICYCLOHEXYLPHOSPHINE)[(PHENYLTHIO)METHYLENE]RUTHENIUM (IV) DICHLORIDE Structure
BIS(TRICYCLOHEXYLPHOSPHINE)[(PHENYLTHIO)METHYLENE]RUTHENIUM (IV) DICHLORIDE Chemical Properties
form Powder
color purple
EPA Substance Registry SystemRuthenium, dichloro[(phenylthio)methylene]bis(tricyclohexylphosphine)- (219770-99-7)
Safety Information
Risk Statements 36/37/38
Safety Statements 26-36/37/39
MSDS Information
BIS(TRICYCLOHEXYLPHOSPHINE)[(PHENYLTHIO)METHYLENE]RUTHENIUM (IV) DICHLORIDE Usage And Synthesis
Reactions
  1. Metathesis catalyst, stable in air and can be used in aqueous media.
  2. Catalyst of choice for the ring-opening metathesis polymerization of cycloolefins.
  3. Catalyst concentration 2-3 times lower than comparable phenyl and vinyl substituted ruthenium carbenes.
  4. Excellent initiator for solvent-free polymerization and control of initiation rates and gelation times.
  5. Highly selective catalyst for the ring opening/cross-metathesis of norbornene derivatives.
Reactions of 219770-99-7
BIS(TRICYCLOHEXYLPHOSPHINE)[(PHENYLTHIO)METHYLENE]RUTHENIUM (IV) DICHLORIDE Preparation Products And Raw materials
BIS(TRICYCLOHEXYLPHOSPHINE)[(PHENYLTHIO)METHYLENE]RUTHENIUM (IV) DICHLORIDE Tricyclohexyl phosphine

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