ChemicalBook Product Catalog Organic Chemistry Organometallic compounds Organomagnesium CYCLOHEXYLMAGNESIUM CHLORIDE

CYCLOHEXYLMAGNESIUM CHLORIDE

CYCLOHEXYLMAGNESIUM CHLORIDE Basic information
Product Name:CYCLOHEXYLMAGNESIUM CHLORIDE
Synonyms:CYCLOHEXYLMAGNESIUM CHLORIDE;chlorocyclohexyl-magnesiu;Cyclohexylmagnesium chloride, 1M in THF;chlorocyclohexylmagnesium;cyclohexylmagnesium chloride sol.;Cyclohexylmagnesium chloride solution;CYCLOHEXYLMAGNESIUM CHLORIDE SOL., ~1.6 M IN DIETHYL ETHER;CYCLOHEXYLMAGNESIUM CHLORIDE, 2.0M SOLUT ION IN DIETHYL ETHER
CAS:931-51-1
MF:C6H11ClMg
MW:142.91
EINECS:213-237-1
Product Categories:Alkyl;Grignard Reagents;Organometallic Reagents
Mol File:931-51-1.mol
CYCLOHEXYLMAGNESIUM CHLORIDE Structure
CYCLOHEXYLMAGNESIUM CHLORIDE Chemical Properties
density 0.871 g/mL at 25 °C
Fp −40 °F
storage temp. 2-8°C
form Solution
color Clear very dark brown
Water Solubility It reacts violently with water.
Sensitive Air & Moisture Sensitive
BRN 3535440
InChIKeyWMJMABVHDMRMJA-UHFFFAOYSA-M
EPA Substance Registry SystemMagnesium, chlorocyclohexyl- (931-51-1)
Safety Information
Hazard Codes F+,C,F
Risk Statements 12-14/15-19-22-34-67-66-14-65-48/20-40-37-11-63
Safety Statements 7-9-16-26-29-33-36/37/39-43-45-62
RIDADR UN 3399 4.3/PG 1
WGK Germany 1
F 1-3-10
TSCA Yes
HazardClass 4.2
PackingGroup I
HS Code 29319090
Hazardous Substances Data931-51-1(Hazardous Substances Data)
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
CYCLOHEXYLMAGNESIUM CHLORIDE Usage And Synthesis
Chemical Propertiesclear very dark brown solution
UsesCyclohexylmagnesium chloride is used as a Grignard reagent in greener solvent, 2-methyltetrahydrofuran (2-MeTHF). It is used as a reagent for the introduction of the cyclohexyl group; metalation of CH-acidic compounds.
UsesNucleophilic reagent is commonly used in substitution and addition reactions.
CYCLOHEXYLMAGNESIUM CHLORIDE Preparation Products And Raw materials
Preparation ProductsDicyclohexylphosphine oxide-->Ethyl 2-cyclohexyl-2-oxoacetate-->Potassium cyclohexyltrifluoroborate-->CYCLOHEXALALLENE-->Cyclohexylmethyl bromide-->1-Cyclohexyl-1-propanone oxime-->Dicyclohexylchlorophosphine-->3-CHLOROPHENYL CYCLOHEXYL KETONE-->4-CYCLOHEXYL-4-OXO-BUTYRIC ACID
3-FLUOROPHENYLMAGNESIUM BROMIDE O-TOLYLMAGNESIUM BROMIDE Butylmagnesium chloride 4-METHYLBENZYLMAGNESIUM CHLORIDE ISOBUTYLMAGNESIUM BROMIDE 4-FLUOROPHENYLMAGNESIUM BROMIDE OCTYLMAGNESIUM CHLORIDE 3 5-DIMETHYOXYPHENYLMAGNESIUM CHLORIDE OCTADECYLMAGNESIUM CHLORIDE Magnesium monochloride Hexylmagnesium chloride PENTYLMAGNESIUM CHLORIDE CYCLOHEXYLMAGNESIUM CHLORIDE Ethylmagnesium chloride PROPYLMAGNESIUM CHLORIDE ISOPROPYLMAGNESIUM CHLORIDE SEC-BUTYLMAGNESIUM CHLORIDE Methylmagnesium chloride
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