N-AMYL NITRATE

N-AMYL NITRATE Basic information
Product Name:N-AMYL NITRATE
Synonyms:nitrated’amyle;Nitricacid,pentylester;nitricacidpentylester;pentylnitrate;1-Pentyl nitrate;Aspirols;1-Nitrooxypentane;Nitric acid amyl ester
CAS:1002-16-0
MF:C5H11NO3
MW:133.15
EINECS:213-684-2
Product Categories:
Mol File:1002-16-0.mol
N-AMYL NITRATE Structure
N-AMYL NITRATE Chemical Properties
Melting point -123.2°C
Boiling point 157 °C
density 1.00
refractive index 1.4120-1.4160
Fp 52 °C
Water Solubility Insoluble in water
solubility Chloroform (Soluble), Methanol (Sparingly)
form Liquid
color Colorless to Light yellow to Light orange
EPA Substance Registry SystemAmyl nitrate (1002-16-0)
Safety Information
RIDADR 1112
RTECS QV0600000
HazardClass 3.1
PackingGroup III
HS Code 2929900090
Hazardous Substances Data1002-16-0(Hazardous Substances Data)
ToxicityLCLo ihl-rat: 3593 ppm AMIHAB 11,290,55
MSDS Information
N-AMYL NITRATE Usage And Synthesis
Chemical PropertiesAmyl nitrate is a flammable, colorless liquid. Ethereal odor.
Chemical PropertiesColorless liquid; ethereal odor. Flammable.
UsesAdditive to increase cetane number of diesel fuels.
General DescriptionA clear colorless liquid with an ether-like odor. Flash point 118°F. About the same density as water and insoluble in water. Vapors heavier than air. Produces toxic oxides of nitrogen during combustion. Used as an additive for diesel fuels.
Air & Water ReactionsFlammable. Insoluble in water.
Reactivity ProfileN-AMYL NITRATE is an oxidizing reagent. When exposed to heat or flame N-AMYL NITRATE may decompose to form nitrogen oxides. Accelerates the burning of combustible materials. Can produce a violent reaction with reducing materials [Sax, 9th ed., p. 228].
HazardOxidizing agent, moderate fire risk.
Health HazardInhalation or ingestion may cause headache, methemoglobin, and nausea. Liquid and vapor irritate eyes. Contact with skin may cause slight irritation.
Safety ProfileModerately toxic by inhalation. A flammable liquid. An oxidizing agent. When heated to decomposition it emits toxic fumes of NOx.
Potential ExposureHighly flammable, Amyl nitrate is used as an ignition additive in diesel fuels.
ShippingUN1112 Amyl nitrate, Hazard Class: 3; Labels: 3-Flammable liquid.
IncompatibilitiesA strong oxidizer. Violent reaction with many compounds, including reducing agents; chemically active metals; combustible materials, strong acids, alkaline earth sulfides, aluminum carbides, aluminum, amines, calcium sulfide, carbides, chlorine trifluoride, glycerin, hydrides, hydrochloric acid, hydrogen peroxide, hydrogen sulfide, hydroxylamine, magnesium, metal powders, metal sulfides, molybdenum, phenylhydrazine, phosphorous red/ friction, phosphorous trichloride, silicon, sulfides, sulfur, sulfur dioxide, sulfur/friction, sulfuric acid, tungsten, hydrogen trisulfide. Temperature sensitive; may explode as temperature rises.
Waste DisposalIncineration with scrubber to remove nitrogen oxides in effluent gases.
N-AMYL NITRATE Preparation Products And Raw materials
Raw materials1-Methylbutyl nitrate-->pentan-3-yl nitrate-->Sodium pentylate-->2-CYANO-2-PROPYL NITRATE-->1-Iodopentane-->Tetrahydrofuran-->1-Pentanol-->Pentane
Preparation ProductsDecane
KT 1 Pentyl nitrite Isosorbide dinitrate 1,3-DINITROXYADAMANTANE D-ISOSORBIDE DINITRATE 2-Amino-1,4:3,6-dianhydro-2-deoxy-L-iditol 5-nitrate monohydrochloride 5-Amino-5-desoxy-1,4:3,6-dianhydro-D-glucit-2-nitrat-hydrochlorid [Ger man] Mannitol hexanitrate,wetted with not less than 40% water,or mixture of alcohol and water,by mass 2-(Acetylamino)-1,4:3,6-dianhydro-2-deoxy-L-iditol 5-nitrate N-AMYL NITRATE Octylnitrate AKOS BB-9052 isoidide dinitrate 2-((3-(4-Acetaminophenoxy)propyl)amino)-1,4:3,6-dianhydro-2-deoxy-L-id itol 5-nitrate HCl H2O 2-Ethylhexyl nitrate Teopranitol 3,3,4,4,5,5,6,6,6-nonafluorohexyl nitrate 1-METHYL-3-(NITROOXY)ADAMANTANE

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