tert-Butyl methacrylate

tert-Butyl methacrylate Basic information
Product Name:tert-Butyl methacrylate
Synonyms:TERTIARY-BUTYL METHACRYLATE;TERT-BUTYL METHACRYLATE;TERT-BUTYL METHACRYLATE MONOMER;TBMA;T-BUTYL METHACRYLATE;METHACRYLIC ACID TERT-BUTYL ESTER;METHACRYLIC ACID TERT-BUTYL ESTER MONOMER;(generic)2-propenoicacid,2-methyl-,1,1-dimethylethylester
CAS:585-07-9
MF:C8H14O2
MW:142.2
EINECS:209-548-7
Product Categories:Acrylic Monomers;C8 to C9Monomers;Medical Intermediates;Carbonyl Compounds;Esters;Methacrylate
Mol File:585-07-9.mol
tert-Butyl methacrylate Structure
tert-Butyl methacrylate Chemical Properties
Melting point -60°C
Boiling point 132 °C (lit.)
density 0.875 g/mL at 25 °C (lit.)
vapor pressure 7.13hPa at 25℃
refractive index n20/D 1.415(lit.)
Fp 81°F
storage temp. 2-8°C
solubility Insoluble in water
form clear liquid
color Colorless
Water Solubility 464mg/L at 20℃
LogP2.54 at 25℃
CAS DataBase Reference585-07-9(CAS DataBase Reference)
EPA Substance Registry Systemtert-Butyl methacrylate (585-07-9)
Safety Information
Hazard Codes Xi
Risk Statements 10-38
Safety Statements 16
RIDADR 3272
WGK Germany 1
RTECS OZ3675500
HazardClass 3
PackingGroup III
HS Code 29161400
MSDS Information
ProviderLanguage
tert-Butyl methacrylate English
tert-Butyl methacrylate Usage And Synthesis
Chemical PropertiesColorless liquid
Usestert-Butyl methacrylate (tert-BMA) can be used in the formation of homo and block copolymers by atom transfer radical polymerization (ATRP) for potential usage in coatings, biomaterials and flocculants.
General DescriptionA colorless liquid with an ester like odor. Flash point below 141°F. Less dense than water and insoluble in water.
Air & Water ReactionsHighly flammable. Insoluble in water.
Reactivity ProfileTERT-BUTYL METHACRYLATE is an ester. Esters react with acids to liberate heat along with alcohols and acids. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Heat is also generated by the interaction of esters with caustic solutions. Flammable hydrogen is generated by mixing esters with alkali metals and hydrides.
Health HazardInhalation or contact with material may irritate or burn skin and eyes. Fire may produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control or dilution water may cause pollution.
Flammability and ExplosibilityFlammable
Purification MethodsPurify as for butyl acrylate. [Beilstein 2 IV 1582.]
tert-Butyl methacrylate Preparation Products And Raw materials
Preparation Productsoptical diskbase material modified PMMA copolymer
SPECS AQ-776/42801265 Cyhalofop-butyl 2,2,3,4,4,4-Hexafluorobutyl methacrylate Butyl methacrylate Lercanidipine tert-Butyl methacrylate Buprofezin tert-Butanol Butyl acrylate POLY(N-BUTYL METHACRYLATE) 2-PYRANONE-5-CARBOXYLIC ACID TERT-BUTYL ESTER Dibutyl phthalate BUTYL OLEATE TRITYL METHACRYLATE TERT-BUTYL 2-ACETYL-3-(DIMETHYLAMINO)ACRYLATE Isobutyl acrylate Methyl acrylate tert-Butyl acrylate

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