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Glycinamide hydrochloride

Glycinamide hydrochloride Basic information
Product Name:Glycinamide hydrochloride
Synonyms:Acetamide, 2-amino-, monohydrochloride;GLYCINAMIDEHYDROCHLORIDE,BIOLOGICALBUFFER;GLYCINAMIDE HCI;Aminoacetamide hydrochloride;Glycinamide hydrochloride,98%;GlycinaMide hydrochloride, 98% 25GR;Glycinamide hydrochl;Acetamide, 2-amino-,hydrochloride (1:1)
CAS:1668-10-6
MF:C2H7ClN2O
MW:110.54
EINECS:216-789-1
Product Categories:Glycine [Gly, G];Amino Acids and Derivatives;Amino hydrochloride;Amides;Carbonyl Compounds;Organic Building Blocks;Amino Acid Derivatives;(intermediate of oxiracetam);Amino Acids;A - HOrganic Building Blocks;Amino Acids;Modified Amino Acids;A - H;Modified Amino Acids;Biochemicals and Reagents;Building Blocks;Carbonyl Compounds;Chemical Synthesis;Organic Building Blocks;Pyridines
Mol File:1668-10-6.mol
Glycinamide hydrochloride Structure
Glycinamide hydrochloride Chemical Properties
Melting point 204 °C (dec.)(lit.)
storage temp. Inert atmosphere,Room Temperature
solubility H2O: 0.1 g/mL, clear
form Crystalline Powder
color White to beige
pka8.20(at 20℃)
Water Solubility Soluble in water (1100g/L).
λmaxλ: 260 nm Amax: 0.1
Sensitive Hygroscopic
BRN 3554199
Stability:Hygroscopic
InChIKeyWKNMKGVLOWGGOU-UHFFFAOYSA-N
CAS DataBase Reference1668-10-6(CAS DataBase Reference)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 22-24/25-37/39-26
WGK Germany 3
F 3-10
HazardClass IRRITANT
HS Code 29241900
MSDS Information
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Glycinamide hydrochloride Usage And Synthesis
Chemical PropertiesCrystalline
UsesGlycinamide hydrochloride is a buffer that is useful in the physiological pH range. And it is also used as a pharmaceutical intermediate, in the organic synthesis.
UsesGlycinamide hydrochloride may be used in the synthesis of [M(glycinamidato-N,N′)(ptpy)2] where ptpy = 2-(p-tolyl)pyridinato) and M= Rh or Ir.
It may be used in the synthesis of the following glycinamide-based imidazolidinones:
  • (±)-2-(2-phenylpropyl)imidazolidin-4-one
  • (±)-2-(2,4,4-trimethylpentyl)imidazolidin-4-one
  • (±)-2-[(R)-2,6-dimethyl-5-heptenyl]imidazolidin-4-one
  • (5R,6S,9R)-6-isopropyl-9-methyl-1,4-diazaspiro[4.5]decan-2-one
  • (5S,6S,9R)-6-isopropyl-9-methyl-1,4-diazaspiro[4.5]decan-2-one
  • (±)-2-methyl-2-pentylimidazolidin-4-one
  • (±)-2-ethyl-2-(2-methylbutyl)imidazolidin-4-one
  • (±)-2-(undecan-2-yl)imidazolidin-4-one
  • (±)-2-pentylimidazolidin-4-one
  • 2-(2,4-dimethylcyclohex-3-en-1-yl)imidazolidin-4-one
Purification MethodsCrystallise the salt from EtOH, EtOH/H2O or MeOH. [Karmas & Spoerri J Am Chem Soc 74 1580 1952, Beilstein 4 IV 2358.]
Glycinamide hydrochloride Preparation Products And Raw materials
Raw materialsMethyl chloroacetate-->Glycinamide
Preparation Productsthiazol-3-one-->Z-GLY-NH2-->Z-PRO-GLY-NH2
Glycine methyl ester hydrochloride (R)-(-)-2-Phenylglycine chloride hydrochloride PUROMYCIN DIHYDROCHLORIDE N-Benzoyl-DL-arginine-4-nitroanilide hydrochloride Glycine hydrochloride 3-Bromo-1-chloro-5,5-dimethylhydantoin GIRARD'S REAGENT P 7-CHLORO-3,4-DIHYDRO-1H-BENZO[E][1,4]DIAZEPINE-2,5-DIONE Topotecan hydrochloride Glycinamide hydrochloride Clodacaine N-ALPHA-BENZOYL-L-ARGININAMIDE HYDROCHLORIDE D(-)-Phenylglycinamide (S)-2-Aminobutyramide hydrochloride Glycinamide L-Alanyl-L-Glutamine Transglutaminase Boc-D-Glutamine
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