(S)-(-)-METHYL P-TOLYL SULFOXIDE

(S)-(-)-METHYL P-TOLYL SULFOXIDE Basic information
Product Name:(S)-(-)-METHYL P-TOLYL SULFOXIDE
Synonyms:(S)-(-)-METHYL P-TOLYL SULFOXIDE, 99% (9;(S)-(-)-METHYL P-TOLYL SULFOXIDE;1-Methyl-4-[(S)-methylsulfinyl]benzene;S-(4-Methylphenyl) methyl sulfoxide;(S)-Methyl 4-tolyl sulfoxide;(S)-Methyl p-methylphenyl sulfoxide;(S)-p-Methylphenyl methyl sulfoxide;(S)-p-Tolyl methyl sulfoxide
CAS:5056-07-5
MF:C8H10OS
MW:154.23
EINECS:
Product Categories:Chiral Compound;Chiral Building Blocks;Organic Building Blocks;Sulfoxides
Mol File:5056-07-5.mol
(S)-(-)-METHYL P-TOLYL SULFOXIDE Structure
(S)-(-)-METHYL P-TOLYL SULFOXIDE Chemical Properties
Melting point 75-77 °C(lit.)
Boiling point 282.4±19.0 °C(Predicted)
density 1.15±0.1 g/cm3(Predicted)
optical activity[α]20/D 145°, c = 2 in acetone
BRN 2324696
Safety Information
WGK Germany 3
3-10
MSDS Information
ProviderLanguage
SigmaAldrich English
(S)-(-)-METHYL P-TOLYL SULFOXIDE Usage And Synthesis
Uses(S)-(-)-Methyl p-tolyl sulfoxide can be used as a nucleophilic reagent to synthesize:
  • Optically active β-disulfoxides by reacting with arenesulfinic esters via formation of α-sulfinylcarbanion.
  • α-substituted N-hydroxylamines by treating with nitrones via preparation of (S)-(-)-methyl p-tolyl sulfoxide anion.
  • 2-O-benzyl-3,4-O-isopropylidene-L-erythrose by one-carbon homologation of 2,3-O-isopropylidene-L-glyceraldehyde.

(S)-(-)-METHYL P-TOLYL SULFOXIDE Preparation Products And Raw materials
DIMETHYL DIPHENYL SULFONE 4,4'-DICARBOXYLATE 4'-METHYL-2(P-TOLYL SULFONYL)ACETOPHENONE Methyl o-tolyl sulfoxide PHENYL P-TOLYL SULFONE N-(p-Tolylsulfonylmethyl)formamide 2-(P-TOLUENESULFONYL)ACETOPHENONE 4-METHANESULFONYL-3-NITRO-BENZOIC ACID (R)-(+)-METHYL P-TOLYL SULFOXIDE Tosylmethyl isocyanide 1-Methyl-4-(methylsulfonyl)-benzene METHYL P-TOLYL SULFOXIDE 4,4'-Dimethyldiphenylsulfoxide 2-(ethylsulfonyl)-5-(trifluoromethyl)aniline N,N-BIS(P-TOLYLSULFONYLMETHYL)ETHYLAMINE 4,4'-SULFONYLBIS-BENZOIC ACID Methyl m-tolyl sulfoxide Tosyl cyanide 2-((4-METHYLPHENYL)SULFONYL)ETHANAMIDE

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