2-CHLOROETHYL PHENYL SULFIDE

2-CHLOROETHYL PHENYL SULFIDE Basic information

Product Name:	2-CHLOROETHYL PHENYL SULFIDE
Synonyms:	2-(PHENYLTHIO)ETHYL CHLORIDE;[(2-CHLOROETHYL)THIO]BENZENE;2-CHLOROETHYL PHENYL SULFIDE;2-CHLOROETHYL PHENYL SULPHIDE;2-Chloroethyl phenyl sulfide 98%;2-chloroethylephenyl sulfide;2-Chlorethyl-phenylsulfid;2-CHLOROETHYL PHENYL
CAS:	5535-49-9
MF:	C8H9ClS
MW:	172.68
EINECS:	226-891-8
Product Categories:
Mol File:	5535-49-9.mol

2-CHLOROETHYL PHENYL SULFIDE Chemical Properties

Boiling point	90-91 °C/1 mmHg (lit.)
density	1.174 g/mL at 25 °C (lit.)
refractive index	n20/D 1.583(lit.)
Fp	104 °C
storage temp.	Inert atmosphere,Room Temperature
form	Liquid
Specific Gravity	1.174
color	Clear colorless
BRN	1907116
CAS DataBase Reference	5535-49-9(CAS DataBase Reference)

Safety Information

Hazard Codes	C,T,Xi,Xn
Risk Statements	34-36/37/38-20/21/22-23/24-45
Safety Statements	26-28-36/37/39-45-53
RIDADR	UN 2810 6.1/PG 2
WGK Germany	3
HazardClass	8
PackingGroup	III
HS Code	2930909899

MSDS Information

Provider	Language
ACROS	English
SigmaAldrich	English
ALFA	English

2-CHLOROETHYL PHENYL SULFIDE Usage And Synthesis

Chemical Properties	CLEAR COLORLESS LIQUID
Uses	2-Chloroethyl phenyl sulfide, a sulfur mustard agent stimulant, may be used as target analyte in a bioassay for the detection of mustard agent.
Synthesis Reference(s)	The Journal of Organic Chemistry, 58, p. 4506, 1993 DOI: 10.1021/jo00068a063 Synthesis, p. 577, 1978
General Description	2-Chloroethyl phenyl sulfide has been reported as sulfur mustard simulant. It is a chemical-warfare agent (CWA) simulant and its oxidation using hydrothane films has been reported. It is also reported as a simulant for the chemical warfare agent mustard [bis(2-chloroethyl) sulfide]. Its reaction with vesicular functionalized double-chain surfactant (potassium O, O′-didodecylphosphorodithioate) at pH 9.0 borate buffer affords [S-[(2-phenylthio)ethyl]O,O′-didodecylphosphorodithioate]. Its oxidation with H₂O₂ catalyzed by [MnL](ClO₄)₂ (L = N,N′,N″-tris(2-hydroxypropyl)-1,4,7-triazacyclononane) afforded 2-chloroethyl phenyl sulfone and phenyl vinyl sulfone.

2-CHLOROETHYL PHENYL SULFIDE Preparation Products And Raw materials

Raw materials	2-CHLOROETHYL PHENYL SULPHOXIDE-->(PHENYLTHIO)ACETIC ACID-->2-(Phenylthio)ethanol-->1-Bromo-2-chloroethane-->Thiophenol-->SODIUM THIOPHENOXIDE-->1,2-Dichloroethane
Preparation Products	PHENYL N-PROPYL SULPHIDE-->2-BROMOETHYL PHENYL SULFIDE-->Thioanisole-->1,2-BIS(PHENYLTHIO)ETHANE

3-CHLORO-4-[(4-CHLOROPHENYL)THIO]TETRAHYDRO-1H-1LAMBDA6-THIOPHENE-1,1-DIONE (PHENYLTHIO)ACETYL CHLORIDE 2-CHLOROETHYL 4-CHLOROPHENYL SULFONE 2,2-DICHLOROCYCLOPROPYL PHENYL SULFONE 2-CHLOROETHYL-(3-(TRIFLUOROMETHYL)PHENYL)SULFONE 1-[(2-CHLORO-2-PHENYLETHYL)SULFONYL]-2,4-DIFLUOROBENZENE 2-[(2-chloro-1,1,2-trifluoroethyl)thio]aniline 2,4-DICHLORO-1-[(2-CHLOROETHYL)SULFONYL]BENZENE 1-[(2-CHLOROETHYL)THIO]-4-METHYLBENZENE 2-CHLOROETHYL PHENYL SULPHOXIDE 2-CHLOROETHYL PHENYL SULFIDE 3-CHLORO-4-(PHENYLTHIO)TETRAHYDRO-1H-1LAMBDA6-THIOPHENE-1,1-DIONE 2-CHLOROETHYL P-TOLYL SULFONE S-CHLOROACETYL-P-MERCAPTOTOLUENE 1-CHLORO-4-[(2-CHLOROETHYL)THIO]BENZENE DIFLUORO(PHENYLSULFANYL)ACETYL CHLORIDE 4-CHLOROPHENYL 2-CHLORO-1,1,2-TRIFLUOROETHYL SULFONE 3-CHLORO-4-(PHENYLSULFONYL)TETRAHYDRO-1H-1LAMBDA6-THIOPHENE-1,1-DIONE

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