4-Methoxybiphenyl

4-Methoxybiphenyl Basic information

Product Name:	4-Methoxybiphenyl
Synonyms:	4-METHOXYBIPHENYL;4-METHOXY-1,1'-BIPHENYL;4-methoxy-1’-biphenyl;Anisole, p-phenyl-;biphenyl,4-methoxy;p-phenyl-anisol;p-phenylanisole;PARA-PHENYLANISOLE
CAS:	613-37-6
MF:	C13H12O
MW:	184.23
EINECS:	210-339-8
Product Categories:	Biphenyl derivatives
Mol File:	613-37-6.mol

4-Methoxybiphenyl Chemical Properties

Melting point	86-90 °C(lit.)
Boiling point	157 °C (10 mmHg)
density	1.0278
refractive index	1.5744 (estimate)
Fp	157°C/10mm
storage temp.	Sealed in dry,Room Temperature
color	Leaves or plates from alc
BRN	2043157
CAS DataBase Reference	613-37-6(CAS DataBase Reference)
NIST Chemistry Reference	P-phenylanisole(613-37-6)
EPA Substance Registry System	1,1'-Biphenyl, 4-methoxy- (613-37-6)

Safety Information

Safety Statements	24/25
WGK Germany	3
RTECS	BZ8850000
TSCA	Yes
HS Code	2909.30.6000
HazardClass	IRRITANT
Hazardous Substances Data	613-37-6(Hazardous Substances Data)

MSDS Information

Provider	Language
ACROS	English
SigmaAldrich	English
ALFA	English

4-Methoxybiphenyl Usage And Synthesis

Chemical Properties	white powder
Uses	4-Methoxybiphenyl is a useful intermediate in the preparation of biphenyl derivatives which are potential downregulators of VEGF protein secretion and telomerase-related gene expressions.
Synthesis Reference(s)	The Journal of Organic Chemistry, 60, p. 1060, 1995 DOI: 10.1021/jo00109a044
Safety Profile	Questionable carcinogen with experimental tumorigenic data. When heated to decomposition it emits acrid smoke and irritating fumes

4-Methoxybiphenyl Preparation Products And Raw materials

Raw materials	4-METHOXYPHENYL 4-METHYLBENZENESULFONATE-->4-METHOXYPHENYLTRIMETHOXYSILANE-->Triphenylbismuth-->TRIBUTYL(4-METHOXYPHENYL)STANNANE-->4-Methoxyphenylmagnesium bromide-->(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)BENZENE-->Phenylboronic acid-->4-Methoxyphenol-->Aniline-->Iodobenzene-->4-Chloroanisole-->TRIBUTYLPHENYLTIN
Preparation Products	5-PHENYL-O-ANISIDINE-->METHYL 4'-HYDROXY[1,1'-BIPHENYL]-4-CARBOXYLATE

4,4'-DI-N-AMYLOXYBIPHENYL 4-FLUORO-3'-METHOXYBIPHENYL 4,4'-DI-N-BUTOXYBIPHENYL 3-AMINO-4-METHOXYBIPHENYL 97+% 4,4'-Dimethoxybiphenyl 4,4'-DIMETHOXYOCTAFLUOROBIPHENYL Methoxybiphenyl,3-METHOXYBIPHENYL 95+% 2-ACETOXY-7-NITROFLUORENE 9,10-BIS(4-METHOXYPHENYL)ANTHRACENE (2-METHOXY-5-PHENYL)PHENYL ISOTHIOCYANATE 4'-METHOXY-BIPHENYL-4-YLAMINE 4'-METHOXYBIPHENYL-3-YLAMINE 3-(METHOXYMETHOXY)BENZALDEHYDE 9,10-Bis(4-methoxyphenyl)-2-chloroanthracene 4-Phenyltoluene 4,4'-DIETHOXYBIPHENYL 4,4'-Bis(4-aminophenoxy)biphenyl 2-(4-BIPHENYLYLOXY)ETHANOL

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