ChemicalBook Product Catalog Organic Chemistry Organometallic compounds Organomagnesium P-TOLYLMAGNESIUM BROMIDE

P-TOLYLMAGNESIUM BROMIDE

P-TOLYLMAGNESIUM BROMIDE Basic information
Product Name:P-TOLYLMAGNESIUM BROMIDE
Synonyms:4-METHYLPHENYLMAGNESIUM BROMIDE;P-TOLYLMAGNESIUM BROMIDE;bromo(4-methylphenyl)-magnesiu;p-TolylMagnesiuM broMide, 0.5 M solution in diethyl ether, J&KSeal;p-TolylMagnesiuM broMide solution 1.0 M in THF;p-TolylMagnesiuM broMide, 1.0 M solution in THF, SpcSeal;p-TolylMagnesiuM broMide solut;(p-Methylphenyl)magnesium bromide
CAS:4294-57-9
MF:C7H7BrMg
MW:195.34
EINECS:
Product Categories:Classes of Metal Compounds;Grignard Reagents;Grignard Reagents & Alkyl Metals;Mg (Magnesium) Compounds;Synthetic Organic Chemistry;Typical Metal Compounds
Mol File:4294-57-9.mol
P-TOLYLMAGNESIUM BROMIDE Structure
P-TOLYLMAGNESIUM BROMIDE Chemical Properties
Melting point >300℃ (acetonitrile ethyl ether )
Boiling point 65-67 °C
density 1.002 g/mL at 25 °C
Fp −1 °F
storage temp. 2-8°C
BRN 636491
EPA Substance Registry SystemMagnesium, bromo(4-methylphenyl)- (4294-57-9)
Safety Information
Hazard Codes F+,C,F
Risk Statements 12-14-19-22-34-66-67-20/21/22-11-37-40
Safety Statements 16-26-33-36/37/39-43-45-27
RIDADR UN 2924 3/PG 1
WGK Germany 1
F 10
HazardClass 3/8
PackingGroup II
HS Code 29319090
MSDS Information
ProviderLanguage
SigmaAldrich English
P-TOLYLMAGNESIUM BROMIDE Usage And Synthesis
Chemical PropertiesClear yellow solution
Usesp-Tolylmagnesium bromide is a common Grignard reagent. It can also be used in a variety of cross-coupling reactions.
P-TOLYLMAGNESIUM BROMIDE Preparation Products And Raw materials
Preparation Products4,4'-Dimethylbiphenyl-->tert-butyl 4-methylphenyl ether-->4,N-DIMETHYL-N-METHOXYBENZAMIDE-->DI-P-TOLYLMETHANE-->2,4,6-trip-tolyl-1,3,5-triazine-->2-chloro-4,6-di-p-tolyl-1,3,5-triazine-->4-(TRIFLUOROACETYL)TOLUENE-->3-(4-Methylbenzoyl)propionic acid
4-TERT-BUTYLPHENYLMAGNESIUM BROMIDE O-TOLYLMAGNESIUM BROMIDE 4-N-PROPYLPHENYLMAGNESIUM BROMIDE 3-FLUORO-2-METHYLPHENYLMAGNESIUM BROMID& 4-METHYL-1-NAPHTHYLMAGNESIUM BROMIDE 2-BIPHENYLMAGNESIUM BROMIDE Toluene P-TOLYLMAGNESIUM BROMIDE 2,4-DIMETHYLPHENYLMAGNESIUM BROMIDE 3,4-DIMETHYLPHENYLMAGNESIUM BROMIDE M-TOLYLMAGNESIUM BROMIDE: 19% IN TETRAHYDROFURAN, 1M),m-Tolylmagnesium Bromide (19% in Tetrahydrofuran, ca. 1mol/L),M-TOLYLMAGNESIUM BROMIDE Benzene 2,4,6-TRIMETHYLPHENYLMAGNESIUM BROMIDE 4-ISO-PROPYLPHENYLMAGNESIUM BROMIDE 4-N-BUTYLPHENYLMAGNESIUM BROMIDE 2,3,4,5,6-PENTAMETHYLPHENYLMAGNESIUM BROMIDE P-TOLYLMAGNESIUM BROMIDE, 1.0M SOLUTION IN DIETHYL ETHER 4-ETHYLPHENYLMAGNESIUM BROMIDE
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