ChemicalBook Product Catalog Chemical Reagents Organic reagents Phosphine ligand (R)-(-)-1-[(S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-T-BUTYLPHOSPHINE

(R)-(-)-1-[(S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-T-BUTYLPHOSPHINE

(R)-(-)-1-[(S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-T-BUTYLPHOSPHINE Basic information
Reaction
Product Name:(R)-(-)-1-[(S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-T-BUTYLPHOSPHINE
Synonyms:(R)-1-[(S)-2-(Dicyclohexylphosphino)ferrocenyl]ethyli-tert-butylphosphine;(R)-(S)-cy2PF-PtBu2;(R)-1-[(SP)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldi-tert-butylphosphine;Ferrocene,1-[(1R)-1-[bis(1,1-dimethylethyl)phosphino]ethyl]-2-(dicyclohexylphosphino)-,(2R)-;(R)-1-[(SP)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldi-tert-butylphosphine >=97%;(Dicyclohexylphosphino)ferrocenyl]ethyldi-t-butylphosphine;Josiphos SL-J009-1 / (R)-1-[(S)-2-(Dicyclohexylphosphino)ferrocenyl]ethyli-tert-butylphosphine;(R)-(-)-1-[(S)-2-(Dicyclohexylphosphino)ferrocenyl] ethyldi-t-butylphosphine, min. 97%
CAS:158923-11-6
MF:C32H52FeP2 10*
MW:554.55
EINECS:238-086-9
Product Categories:organophosphine ligand;Chiral Phosphine;Ferrocene Series;Josiphos Series
Mol File:158923-11-6.mol
(R)-(-)-1-[(S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-T-BUTYLPHOSPHINE Structure
(R)-(-)-1-[(S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-T-BUTYLPHOSPHINE Chemical Properties
Melting point 118-120oC
alpha -185° ±10° (c 0.5, CHCl3)
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
solubility Chloroform (Slightly), Methanol (Very Slightly)
form Powder
color orange
Safety Information
Safety Statements 22-24/25
WGK Germany 3
HS Code 29319090
MSDS Information
(R)-(-)-1-[(S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-T-BUTYLPHOSPHINE Usage And Synthesis
Reaction
  1. Ligand for Palladium-catalyzed C-N cross-coupling.
  2. Ligand for Palladium-catalyzed C-S cross-coupling.
  3. Ligand for Palladium-catalyzed Kumada couplings of aryl and vinyl tosylates.
  4. Ligand for Rhodium-catalyzed hydroacylation of cyclopropenes, an enatioselective desymmetrization method.
  5. Ligand for Palladium-catalyzed C-O cross-coupling.
  6. Ligand for Rhodium-catalyzed coupling of imidazole derivatives with terminal allenes.
  7. Ligand for Ruthenium-catalyzed C-C coupling of alkynes and alcohols to form branched products of carbonyl allylation
Reactions of 158923-11-6_1
Reactions of 158923-11-6_2
Reactions of 158923-11-6_3

Chemical PropertiesOrange powder
UsesIt may be used as a ligand in the palladium catalyzed hetero cross-coupling between aryl bromides/aryl triflates with potassium thioacetate to form S-aryl thioacetates.
General Descriptionsold in collaboration with Solvias AG
(R)-(-)-1-[(S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-T-BUTYLPHOSPHINE Preparation Products And Raw materials
(R)-1-[(1S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDICYCLOHEXYLPHOSPHINE (R)-1-[(R)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-FERROCENYL]ETHYLDICYCLOHEXYLPHOSPHINE (R)-(S)-JOSIPHOS (R)-(-)-1,2,3,4-TETRAHYDRO-1-NAPHTHOL (R)-1-nonen-3-ol (R)-1-[3,5-Bis(trifluoromethyl)phenyl]ethanol (R)-(-)-1-[(S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDI(3,5-DIMETHYLPHENYL)PHOSPHINE (R)-1-[(1S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDI-TERT-BUTYLPHOSPHINE CYCLOHEXYLPHOSPHINE (S)-1-[(R)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-TERT-BUTYLPHOSPHINE Ferrocene DICYCLOHEXYLPHOSPHINE 1,3-BIS(DI-I-PROPYLPHOSPHINO)PROPANE Di-tert-butylphosphine T-BUTYLPHOSPHINE (R)-(-)-1-[(S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-T-BUTYLPHOSPHINE 1,3-BIS(DIETHYLPHOSPHINO)PROPANE (R)-(-)-[(S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-T-BUTYLPHOSPHINE
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