Tri-O-acetyl-D-glucal

Tri-O-acetyl-D-glucal Basic information
Product Name:Tri-O-acetyl-D-glucal
Synonyms:1,2-DIDEOXY-3,4,6-TRI-O-ACETYL-D-ARABINO-1-HEXENOPYRANOSE;1,2-DIDEOXY-3,4,6-TRI-O-ACETYL-D-ARABINO-1-HEXENOPYRANOSIDE;1,5-ANHYDRO-2-DEOXY-D-ARABINO-HEX-1-ENITOL 3,4,6-TRI-O-ACETYL ETHER;3,4,6-TRI-O-ACETYL-1,5-ANHYDRO-D-ARABINO-HEX-1-ENITOL;3,4,6-TRI-O-ACETYL-1,5-ANHYDRO-2-DEOXY-D-ARABINO-HEX-1-ENITOL;3,4,6-TRI-O-ACETYL-D-GLUCAL;(-)-TRI-O-ACETYL-D-GLUCAL;TRI-O-ACETYL-D-GLUCAL
CAS:2873-29-2
MF:C12H16O7
MW:272.25
EINECS:220-709-0
Product Categories:Sugars, Carbohydrates & Glucosides;Biochemistry;Glucose;Glycals;O-Substituted Sugars;Sugars;chiral;Carbohydrates & Derivatives
Mol File:2873-29-2.mol
Tri-O-acetyl-D-glucal Structure
Tri-O-acetyl-D-glucal Chemical Properties
Melting point 53-55 °C(lit.)
Boiling point 335.31°C (rough estimate)
density 1.2602 (rough estimate)
refractive index 1.4455 (estimate)
Fp >230 °F
storage temp. Keep in dark place,Sealed in dry,Room Temperature
solubility Chloroform (Slightly), Ethanol (Slightly), Methanol (Slightly)
form Crystalline Powder
color White to off-white
optical activity[α]25/D 12°, c = 2 in ethanol
Water Solubility Soluble in chloroform and ethanol. Insoluble in water.
BRN 90781
CAS DataBase Reference2873-29-2(CAS DataBase Reference)
Safety Information
Safety Statements 24/25
WGK Germany 3
HS Code 29329995
MSDS Information
ProviderLanguage
1,5-Anhydro-2-deoxy-D-arabino-hex-1-enitol triacetate English
SigmaAldrich English
ACROS English
ALFA English
Tri-O-acetyl-D-glucal Usage And Synthesis
Chemical Propertieswhite to off-white crystalline powder
UsesA D-glucal derivative.
Uses3,4,6-Tri-O-acetyl-D-glucal acts as a building block for the synthesis of oligosaccharides in both solution and solid-phase. Further, it is used in the preparation of D-arabino-1,5-anhydro-2-deoxy-hex-1-enitol.
Tri-O-acetyl-D-glucal Preparation Products And Raw materials
Preparation ProductsD-Glucopyranose, 2-azido-2-deoxy-3,4-bis-O-(phenylMethyl)-, 1,6-diacetate-->D-Galactal-->2-Azido-2-deoxy-D-glucopyranose 1,3,4,6-Tetraacetate-->6-O-BENZYL-D-GLUCAL,-->D-arabino-Hex-1-enitol, 1,5-anhydro-4,6-O-[bis(1,1-dimethylethyl)silylene]-2-deoxy--->6-O-(TERT-BUTYLDIPHENYLSILYL)-D-GLUCAL
HEXA-O-ACETYL-CELLOBIAL 3,4-6TRI-O-ACETYL-L-GLUCAL,TRI-O-ACETYL-L-GLUCAL Calcium gluconate N-ACETYL-L-TYROSINE ETHYL ESTER Acetylacetone Gluconic acid 3,4,6-TRI-O-(4-METHYLBENZOYL)-D-GLUCAL TRI-O-ACETYL-D-[2-13C]GLUCAL Acetylferrocene tributyl acetocitrate Tri-O-acetyl-D-glucal Acetyl chloride TRI-O-ACETYL-D-[6-13C]GLUCAL 3,4,6-TRI-O-ACETYL-D-GLUCAL - REFERENCE SPECTRUM D-Glucal 4,5,7-TRI-O-ACETYL-2,6-ANHYDRO-3-DEOXY-D-LYXO-HEPT-2-ENONONITRILE, TRI-O-ACETYL-D-[1-13C]GLUCAL 2,3,4,5-TETRA-O-ACETYL-1-DEOXY-D-ARABINO-HEX-1-ENOPYRANOSE,

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