ChemicalBook Product Catalog Biochemical Engineering Amino Acids and Derivatives Histidine derivatives N-Cbz-L-histidine

N-Cbz-L-histidine

N-Cbz-L-histidine Basic information
Product Name:N-Cbz-L-histidine
Synonyms:(S)-2-BENZYLOXYCARBONYLAMINO-3-(3H-IMIDAZOL-4-YL)-PROPIONIC ACID;N2-CARBOBENZYLOXY-L-HISTIDINE;N-ALPHA-Z-L-HISTIDINE;NALPHA-CARBOBENZOXY-L-HISTIDINE;N(ALPHA)-CBZ-L-HISTIDINE;N-ALPHA-CARBOBENZYLOXY-L-HISTIDINE;N-CARBOBENZOXY-L-HISTIDINE;N-ALPHA-BENZYLOXYCARBONYL-L-HISTIDINE
CAS:14997-58-1
MF:C14H15N3O4
MW:289.29
EINECS:239-084-0
Product Categories:Amino Acid Derivatives;Histidine [His, H];Z-Amino Acids and Derivatives;Cbz-Amino Acids;Amino Acids;Amino Acids (N-Protected);Biochemistry;Z-Amino acid series
Mol File:14997-58-1.mol
N-Cbz-L-histidine Structure
N-Cbz-L-histidine Chemical Properties
Melting point 168 °C (dec.)(lit.)
alpha -24 º (c=1 in 6 M HCl)
Boiling point 616.7±55.0 °C(Predicted)
density 1.368±0.06 g/cm3(Predicted)
refractive index -23.5 ° (C=6, 6mol/L HCl)
storage temp. Sealed in dry,2-8°C
solubility Soluble in Chloroform,Dichloromethane,Ethyl Acetate,DMSO,Acetone,etc.
pka3.35±0.10(Predicted)
form powder to crystal
color White to Almost white
optical activity[α]20/D 24°, c = 1% in 6 M HCl
Water Solubility almost transparency
BRN 3561682
InChIKeyWCOJOHPAKJFUDF-LBPRGKRZSA-N
CAS DataBase Reference14997-58-1(CAS DataBase Reference)
Safety Information
Hazard Codes Xn
Risk Statements 20/21/22-36/37/38
Safety Statements 22-24/25-36-26
WGK Germany 3
HS Code 29332900
MSDS Information
ProviderLanguage
SigmaAldrich English
ALFA English
N-Cbz-L-histidine Usage And Synthesis
Chemical PropertiesWhite powder
UsesNα-Cbz-L-histidine is an N-Cbz-protected form of L-Histidine (H456010). L-Histidine is an essential amino acid that plays an important role in mitochondrial glutamine transport and has potential of abolishing oxidative stress caused by brain edema.L-Histidine promotes zinc uptake in human erythrocyes and also has potential as an antioxidant therapy for acute mammary inflammation in cattle.
N-Cbz-L-histidine Preparation Products And Raw materials
Raw materialsN,1-Bis-Cbz-L-histidine-->L-Histidine-->Benzyl chloroformate
N-ALPHA-CBZ-L-HISTIDINE METHYL ESTER Z-HIS(BZL)-OH NA-CBZ-N-IM-BENZYL-L-HISTIDINE Z-HIS(Z)-ONP Nequinate Z-HIS(Z)-OH ETOH Ethyl 2-(Chlorosulfonyl)acetate LABOTEST-BB LT00847689 Trimethoprim Ascoric Acid Propionic acid N-Cbz-L-histidine Folic acid Imidazole L-Histidine Benzyl chloroformate N-ALPHA-N-IM-DI-CBZ-L-HISTIDINE Citric acid
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