Acid Blue 9

Acid Blue 9 Basic information
Product Name:Acid Blue 9
Synonyms:CI NO 42090;ERIOGLAUCIN A;ERIOGLAUCINE;ERIOGLAUCINE A;ERIOGLAUCINE SODIUM SALT;E133;INTRACID PURE BLUE L;LAKE BRILLIANT BLUE FCF
CAS:2650-18-2
MF:C37H39N3O9S3
MW:765.91
EINECS:220-168-0
Product Categories:Organics
Mol File:2650-18-2.mol
Acid Blue 9 Structure
Acid Blue 9 Chemical Properties
Melting point 283 °C (dec.)(lit.)
density 1.1666 (rough estimate)
vapor pressure 0Pa at 25℃
refractive index 1.6000 (estimate)
storage temp. Amber Vial, Refrigerator
solubility DMSO (Slightly), Ethyl Acetate (Slightly), Methanol (Slightly)
form Solid
color Dark Blue to Very Dark Purple
Water Solubility 1000g/L at 24.3℃
Stability:Light Sensitive
LogP-3 at 23℃
CAS DataBase Reference2650-18-2(CAS DataBase Reference)
EPA Substance Registry SystemC.I. Acid Blue 9, diammonium salt (2650-18-2)
Safety Information
WGK Germany 3
RTECS BQ4725000
Hazardous Substances Data2650-18-2(Hazardous Substances Data)
ToxicityLDLo intravenous in human: 33ug/kg
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
Acid Blue 9 Usage And Synthesis
DescriptionFD & C Blue No. 1 is principally the disodium salt of ethyl[4-[p- [ethyl(m-sulfobenzyl)amino]-α-(ο-sulfophenyl)benzylidene]2,5-cyclohexadien-l-ylidene](m-sulfobenzyl) ammonium hydroxide inner salt.
The colorant is a dark purple to bronze powder that dissolves in water to give a solution green-blue at neutrality, green in weak acid, and yellow in stronger acid. Addition of base to its neutral solution produces a violet color only on boiling. When dissolvedin concentrated sulfuric acid, it yields a yellow solution that turns green when diluted with water. It is soluble in 95% ethanol. FD & C Blue No. 1 is used in beverages and beverage powders, dairy products, bakery products, dessert powders, confectionery products, condiments, icings, syrups, jams, jellies, marmalades, liqueurs, and extracts. It is also used for coloring ingested drugs.
Chemical PropertiesBlue powder
UsesAcid Blue 9 (CAS# 2650-18-2) is an organic azo dye. It has been used in the preparation of solar-sensitive liposomes capable of capturing and releasing food dyes for the measurement of sunlight exposure over extended periods of time. Being water soluble, acid blue 9 is often considered a pollutant, and is used as an analyte in the development of azo-dye removal processes.
Preparation2-Formylbenzenesulfonic acid ?and 3-(Ethyl(phenyl)amino)methyl)benzenesulfonic acid condensation, oxidation, and then the product into the ammonium salt or sodium salt.
DefinitionChEBI: Erioglaucine A is an aromatic amine.
Flammability and ExplosibilityNotclassified
Safety ProfileHuman poison by intravenous route. Human systemic effects by intravenous route: muscle contractions or spasticity and dpspnea. Questionable carcinogen with experimental neoplastigenic and tumorigenic data. Mutation data reported. When heated to decomposition it emits very toxic fumes of NH3, NOx, and SOx.
Properties and Applicationscolourful green light blue. Violet powder, soluble in water, in 90 ℃ water solubility of 50 g/L, soluble in ethanol. The strong sulfuric acid in orange, dilute yellowish later. The water solution is green light blue dye, add sodium hydroxide after it shows colorless, and you have a deep purple precipitation. Good levelness, white sex is better, for copper, iron ion sensitive, dyeing should pay attention, or influence colored light. This product used for wool, silk,nylon?with wool blended fabric dyeing and printing. Can also be used as a food dyes and organic pigments, also used for paper shading and anti-epidemic field, can also be used in leather color.
Standard Light Fastness Soaping Persperation Fastness Oxygen bleaching Fastness to seawater
Fading Stain Fading Stain Fading Stain
ISO 3 2-3 3 3 3 3
AATCC 1 4 4 2 2 3-4
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