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Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II)

Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) Basic information
Reaction
Product Name:Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II)
Synonyms:Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II);(R)-Ru(OAc)2(BINAP),Diacetato[(R)-(+)-2,2′-bis(diphenylphosphino)-1,1′binaphthyl]ruthenium(II);Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) Ru(OAc)2[(R)-binap];Ru-BINAP;RU(OAC)2[(R)-BINAP];Ru(OAc)2[(R)-binap];-binaphthyl]ruthenium(II),Ru(OAc)2[(R)-binap].;(OC-6-22)-Bis(acetato-κO,κO')[(1R)-[1,1'-binaphthalene]-2,2'-diylbis[diphenylphosphine-κP]]ruthenium
CAS:325146-81-4
MF:C48H40O4P2Ru
MW:843.86
EINECS:
Product Categories:Ru
Mol File:325146-81-4.mol
Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) Structure
Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) Chemical Properties
Melting point >100°C
storage temp. 2-8°C
form Powder
color ocher to green
Sensitive air sensitive
Safety Information
WGK Germany 3
HS Code 28439000
MSDS Information
Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) Usage And Synthesis
Reaction
  1. Catalyst system that exhibits very high catalytic activity and enantioselectivity in the hydrogenation of a wide range of substrates.
  2. Catalyst used in the synthesis of β-amino acids by hydrogenation.
Reactions of 325146-81-4
Chemical PropertiesLight yellow powder
Uses(R)-Ru(OAc)2(BINAP) is a catalyst.
Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) Preparation Products And Raw materials
Benzilic acid Dichloro(2-pyridinecarboxylato)gold DICHLORO[1,3-BIS(DIPHENYLPHOSPHINO)PROPANE]PALLADIUM(II) Diacetato[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]ruthenium(II) Dichloro(cycloocta-1,5-diene)ruthenium(II) [1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II) Diacetato[(R)-(+)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]ruthenium(II) Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II) Diacetato[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) Diacetato[(R)-(+)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole] ruthenium(II) Ru(OAc)2[(R)-segphos]　
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