DI-P-TOLYL SULFONE

DI-P-TOLYL SULFONE Basic information
Product Name:DI-P-TOLYL SULFONE
Synonyms:DI-P-TOLYL SULFONE;P-TOLYL SULFONE;1,1’-sulfonylbis[4-methyl-benzen;1-Methyl-4-[(4-methylphenyl)sulfonyl]benzene;4,4’-Dimethyldiphenylsulfone;4,4’-Ditolylsulfone;4,4'-Dimethyldiphenylsulfone;4,4'-Ditolyl sulfone
CAS:599-66-6
MF:C14H14O2S
MW:246.32
EINECS:209-969-6
Product Categories:Sulfones;Sulfur Compounds;Organic Building Blocks
Mol File:599-66-6.mol
DI-P-TOLYL SULFONE Structure
DI-P-TOLYL SULFONE Chemical Properties
Melting point 158-160 °C(lit.)
Boiling point 359.33°C (rough estimate)
density 1.2052 (rough estimate)
refractive index 1.5200 (estimate)
storage temp. Sealed in dry,Room Temperature
solubility chloroform: soluble25mg/mL, clear, colorless to yellow
EPA Substance Registry SystemBenzene, 1,1'-sulfonylbis[4-methyl- (599-66-6)
Safety Information
Safety Statements 22-24/25
WGK Germany 3
TSCA Yes
MSDS Information
ProviderLanguage
SigmaAldrich English
ALFA English
DI-P-TOLYL SULFONE Usage And Synthesis
Uses4,4''-Ditolyl Sulfone is used in preparation method of OLED material for improving luminous efficiency.
UsesDi-p-tolyl sulfone may be used in the synthesis of isomeric p-tolylpyridines (α , β and γ ) by photochemical decomposition.
General DescriptionDi-p-tolyl sulfone is a di-p-substituted diaryl sulfone. Its synthesis by the sulfonylation of toluene with p-toluenesulfonic acid (TsOH) in the presence of polystyrene supported aluminium triflate (Ps-Al(OTf)3) catalyst has been reported along with its NMR and IR spectra. The gas-phase heats of formation of di-p-tolyl sulfone has been studied. The kinetics and thermodynamics of sulphuric acid assisted cleavage of di-p-tolyl sulfone has been invesitigated.
Purification MethodsCrystallise the sulfone repeatedly from Et2O or EtOH. It has been purified by zone melting. [Beilstein 6 H 419, 6 II 395, 6 III 1405, 6 IV 2174.]
DI-P-TOLYL SULFONE Preparation Products And Raw materials
Preparation Products4,4'-SULFONYLBIS-BENZOIC ACID-->DIMETHYL DIPHENYL SULFONE 4,4'-DICARBOXYLATE
DIMETHYL DIPHENYL SULFONE 4,4'-DICARBOXYLATE Di-o-tolyl sulfone DI-P-TOLYL SULFONE 100MG [R] 1,1'-Sulfonylbis(3,4-dimethylbenzene) 1-(bromomethyl)-4-[(4-methylphenyl)sulfonyl]benzene HEXAMETHYLENE DIAMMONIUM-P,P'-SULFONYL-DIBENZOATE 2-[(4-METHYLPHENYL)SULFONYL]-5-(TRIFLUOROMETHYL)ANILINE 1,2-DIMETHYL-4-TOSYLBENZENE METHYL 3-[(CYCLOPROPYLCARBONYL)AMINO]-4-[(4-METHYLPHENYL)SULFONYL]BENZENECARBOXYLATE O-TOLIDINE SULFONE METHYL 4-[(4-METHYLPHENYL)SULFONYL]-3-NITROBENZENECARBOXYLATE (4-METHYLPHENYL)[2-NITRO-4-(TRIFLUOROMETHYL)PHENYL]DIOXO-LAMBDA6-SULFANE DI-N-BUTYL-4,4'-SULFONYLDIBENZOATE 4,4'-SULFONYLBIS-BENZOIC ACID METHYL 4-[(4-METHYLPHENYL)SULFONYL]-3-[(2-THIENYLCARBONYL)AMINO]BENZENECARBOXYLATE 4-[(4-METHYLPHENYL)SULFONYL]-3-NITROBENZOIC ACID 4,4'-DICYANODIPHENYLSULPHONE METHYL 3-AMINO-4-[(4-METHYLPHENYL)SULFONYL]BENZENECARBOXYLATE

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