ChemicalBook Product Catalog Chemical Reagents Organic reagents Boric acid 6-METHOXY-2-NAPHTHALENEBORONIC ACID

6-METHOXY-2-NAPHTHALENEBORONIC ACID

6-METHOXY-2-NAPHTHALENEBORONIC ACID Basic information
Product Name:6-METHOXY-2-NAPHTHALENEBORONIC ACID
Synonyms:6-Methoxy-2-naphthaleneboronic acid >=95%;6-METHOXYNAPHTHALENE-2-BORONIC ACID;6-METHOXYNAPHTHYL-2-BORONIC ACID;(6-METHOXY-2-NAPHTHYL)BORONIC ACID;6-METHOXY-2-NAPHTHALENEBORONIC ACID;(6-METHOXY-2-NAPHTHALENYL)BORONIC ACID;AKOS BRN-0219;6-METHOXY-2-PHTHALENEBORONIC ACID
CAS:156641-98-4
MF:C11H11BO3
MW:202.01
EINECS:627-194-5
Product Categories:Boronic acid;Aryl;Boronic Acids;Boronic Acids and Derivatives;blocks;BoronicAcids
Mol File:156641-98-4.mol
6-METHOXY-2-NAPHTHALENEBORONIC ACID Structure
6-METHOXY-2-NAPHTHALENEBORONIC ACID Chemical Properties
Melting point >295 °C(lit.)
Boiling point 416.2±37.0 °C(Predicted)
density 1.23±0.1 g/cm3(Predicted)
storage temp. Inert atmosphere,Room Temperature
solubility DMSO (Slightly), Methanol (Slightly, Heated)
form powder to crystal
pka8.72±0.30(Predicted)
color White to Orange to Green
BRN 7636998
CAS DataBase Reference156641-98-4(CAS DataBase Reference)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36
WGK Germany 3
HazardClass IRRITANT
HS Code 29163990
MSDS Information
ProviderLanguage
SigmaAldrich English
ALFA English
6-METHOXY-2-NAPHTHALENEBORONIC ACID Usage And Synthesis
Chemical PropertiesWhite to off-white crystalline powder
UsesReactant for:
  • Suzuki-Miyaura coupling
  • Enantioselective a-arylation of carbonyls via copper-bisoxazoline catalysis
  • Enantioselective synthesis of aryl ketones
  • Copper-catalyzed trifluoromethylation
  • Rhodium-catalyzed oxidative coupling with alkynes
Usessuzuki reaction
General DescriptionContains varying amounts of anhydride.
6-METHOXY-2-NAPHTHALENEBORONIC ACID Preparation Products And Raw materials
Raw materialsTetrahydrofuran-->Nitrogen-->Dimethyl sulfate-->Triisopropyl borate-->6-Bromo-2-naphthol-->SEC-BUTYLLITHIUM
Preparation Products6-Methoxy-2-vinylnaphthalene-->6-ETHYL-2-METHOXYLNAPHTHALINE-->3-(6-Methoxynaphthalen-2-yl)benzaldehyde
2-METHOXY-1-NAPHTHALENEBORONIC ACID 2-Naphthaleneboronic acid 6-Ethoxy-2-naphthaleneboronic acid 6-METHOXY-2-NAPHTHALENEBORONIC ACID 2-(6-METHOXY-2-NAPHTHYL)-5,5-DIMETHYL-1,3,2-DIOXABORINANE 6-(TETRAHYDRO-2H-PYRAN-2-YLOXY)-2-NAPHTHYLBORONIC ACID 2-(6-Methoxynaphthalen-2-yl)-4,4,6-trimethyl-1,3,2-dioxaborinane 4-METHOXY-1-NAPHTHALENEBORONIC ACID 2-(6-Benzyloxynaphthalen-2-yl)-5,5-dimethyl-1,3,2-dioxaborinane 6-(BENZYLOXY)-2-NAPHTHYLBORONIC ACID 2-(6-Benzyloxynaphthalen-2-yl)-4,4,6-trimethyl-1,3,2-dioxaborinane 6-PENTYLOXYNAPHTHALENE-2-BORONIC ACID
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