Basic Green 1

Basic Green 1 Basic information
Product Name:Basic Green 1
Synonyms:brilliantgreencrystalsh;brilliantgreendsc;brilliantgreeng;brilliantgreengx;brilliantgreenlake;brilliantgreenp;brilliantgreenspecial;ANILINE GREEN
CAS:633-03-4
MF:C27H34N2O4S
MW:482.63
EINECS:211-190-1
Product Categories:Analytical Chemistry;Ion Association;Dyes and Pigments;Stains and Dyes;Triphenylmethane;AR
Mol File:633-03-4.mol
Basic Green 1 Structure
Basic Green 1 Chemical Properties
Melting point 210 °C (dec.)(lit.)
Boiling point 100.0
density 1.1016 (rough estimate)
vapor density 16.6 (vs air)
vapor pressure 0Pa at 25℃
refractive index 1.6510 (estimate)
storage temp. room temp
solubility 100g/l
Colour Index 42040
form Powder/Solid
color Metallic green
OdorOdorless
PH2.5 (10g/l, H2O, 25℃)
PH RangeYellow (0.0) to green (2.6)
Water Solubility 100 G/L (25 ºC)
λmax625nm, 428nm
Merck 14,1374
BRN 3901207
Stability:Stable. Incompatible with strong oxidizing agents, reducing agents.
Major ApplicationBlack matrix, color filter, photoresists, sensors, inks, rodenticide, dyes, cosmetics, detecting dental carious tissue, Escherichia coli, antimalarial agent, dressing material, treatment of cancer, medical devices
Biological ApplicationsAntimalarial agent; detecting carious tissue; treating anococcygeal pain syn- drome; wound dressing materials; catheter; mouthwash
InChIKeyUURSSPGMJADCAU-UHFFFAOYSA-N
LogP0.765 at 20℃
CAS DataBase Reference633-03-4(CAS DataBase Reference)
EPA Substance Registry SystemC.I. Basic Green 1 (633-03-4)
Safety Information
Hazard Codes Xn
Risk Statements 22-36-36/37/38-20/21/22
Safety Statements 26-39-36-24/25
RIDADR 2811
WGK Germany 3
RTECS BP6825000
10-21
TSCA Yes
HS Code 3204 13 00
HazardClass 6.1(a)
PackingGroup II
Hazardous Substances Data633-03-4(Hazardous Substances Data)
ToxicityLD100 i.v. in mice: 3 mg/kg (Anderson)
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
ALFA English
Basic Green 1 Usage And Synthesis
Chemical Propertiesmetallic green crystals
Chemical PropertiesC.I. Basic Green 1 is a metallic green, odorless crystal or powder
UsesDyeing silk, wool, leather, jute and cotton yellowish-green; manufacture of green ink; biological stain; indicator.
UsesBrilliant Green a stain used in bacteriological media.
Preparationin the presence of sulfuric acid hydrochloric acid or, Benzaldehyde?and N,N-diethylbenzenamine condensation, and then will product oxidation, and translated into sulfate. The first generation of resin mixture will suddenly for curing crystalline good crystals.
DefinitionChEBI: An organic hydrogensulfate salt having 4-{[4-(diethylamino)phenyl](phenyl)methylidene}-N,N-diethylcyclohexa-2,5-dien-1-iminium as the counterion.
General DescriptionBrilliant green is a triphenylmethane dye, found to be toxic to humans and animals. It is widely used in dying wool, leather, silk, jute, and cotton. It is also used in the manufacturing of green ink, as a staining constituent of bacteriological media.
Flammability and ExplosibilityNonflammable
Biochem/physiol ActionsBrilliant Green is a dye and an antiseptic agent.
Safety ProfilePoison by ingestion, intraperitoneal, and intravenous routes. A rmld human skin irritant. Mutation data reported. See also ALDEHYDES and SULFATES. When heated to decomposition it emits very toxic fumes of NOx, NH3, and SOx.
Potential ExposureC.I. Basic Green 1 is used in dyeing silk, wool, leather, jute, and cotton yellowish-green; manufacturing green ink; as staining constituent of bacteriological media; indicator, an intestinal anthelmintic; a C.I. Basic Green 1 861 wound antiseptic; treatment of mycotic infections; agricultural fungicide (Not registered as a pesticide in the United States).
ShippingUN3143 Dyes, solid, toxic, n.o.s. or Dye intermediates, solid, toxic, n.o.s., Hazard Class: 6.1; Labels: 6.1-Poisonous materials, Technical Name Required. UN2811 Toxic solids, organic, n.o.s., Hazard Class: 6.1; Labels: 6.1-Poisonous materials, Technical Name Required.
Purification MethodsPurify the dye by precipitating the perchlorate from aqueous solution (0.3%) after filtering, heating to 75o and adjusting to pH 1-2. Recrystallise it from EtOH/water (1:4) [Kerr & Gregory Analyst (London) 94 1036 1969]. [Beilstein 13 IV 2281.]
Properties and Applicationsbright green. Green flash golden sand shape. Slightly soluble in cold water, in 98 ℃ of hot water dissolves only 8 g/L, soluble in ethanol to blue. The strong sulfuric acid for yellow green, diluted into blue; For orange in nitric acid. The dye solution for blue purple, add sodium hydroxide have dark purple precipitation; Join the hydrochloric acid become green light yellow. Used for silk, wool, acrylic, tannin mordant dyeing cotton cloth dyeing. Also used in leather, hemp, paper, wood, bamboo or color, also used in the manufacture of paint, medicine used for disinfectant.
Standard Light Fastness Persperation Fastness Ironing Fastness Soaping
Fading Stain Fading Stain Fading Stain
ISO 4 4 4-5 4 4-5
AATCC 2-3
IncompatibilitiesOxidizing agents, reducing agents; anionics, and aqueous solutions of bentonite. Keep away from moisture
Basic Green 1 Preparation Products And Raw materials
Raw materialsLead dioxide-->Benzaldehyde-->N,N-Diethylaniline
LIGHT GREEN SF YELLOWISH Trinexapac-ethyl 4 BASIC GREEN 4 Ethanol 2-Aminocyclohexanol Basic Green 1 Basic Green 4 PHENAZINE ETHOSULFATE ISOXADIFEN-ETHYL Ethyl acetate Ethyl propiolate Cyclamic acid Ethyl acrylate Molasses Fast Green FCF Alkaline Phosphatase Ethyl cyanoacetate Cupric carbonate basic

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