2-Amino-p-cresol

2-Amino-p-cresol Basic information

Product Name:	2-Amino-p-cresol
Synonyms:	2-AMINO-PARA-CRESOL, 97%;2-amino-4-methyl-pheno;Phenol, 2-amino-4-methyl-;2-AMINO-4-METHYLPHENOL / 2-AMINO-P-CRESOL / 3-AMINO-4-HYDROXYTOLUENE;2-Amino-p-cresol (OH=1);2-Amino-p-cresol, 2-Hydroxy-5-methylaniline, 3-Amino-4-hydroxytoluene;(2-Hydroxy-5-methylphenyl)amine;1-Amino-2-hydroxy-5-methylbenzene
CAS:	95-84-1
MF:	C7H9NO
MW:	123.15
EINECS:	202-457-3
Product Categories:	Amines;Aromatic Hydrocarbons (substituted) & Derivatives;Intermediates of Dyes and Pigments
Mol File:	95-84-1.mol

2-Amino-p-cresol Chemical Properties

Melting point	133-136 °C(lit.)
Boiling point	229.26°C (rough estimate)
density	1.0877 (rough estimate)
refractive index	1.5706 (estimate)
storage temp.	Keep in dark place,Inert atmosphere,Room temperature
solubility	slightly soluble
pka	10.06±0.18(Predicted)
form	Flakes or Crystalline Powder
color	Beige to gray-brown
Water Solubility	slightly soluble
BRN	606494
CAS DataBase Reference	95-84-1(CAS DataBase Reference)
EPA Substance Registry System	2-Amino-p-cresol (95-84-1)

Safety Information

Hazard Codes	Xi
Risk Statements	36/37/38
Safety Statements	26-36-37/39
WGK Germany	2
RTECS	SJ6078000
TSCA	Yes
HS Code	29222900

MSDS Information

Provider	Language
2-Amino-4-methylphenol	English
SigmaAldrich	English
ACROS	English
ALFA	English

2-Amino-p-cresol Usage And Synthesis

Chemical Properties	White crystal powder
Uses	2-Amino-4-methylphenol was used in the synthesis of novel functionalized spiropyran derivatives of 2H-1,3-benzoxazinone series.
General Description	Brown powder.
Air & Water Reactions	2-Amino-p-cresol may be sensitive to prolonged exposure to air. Insoluble in water.
Reactivity Profile	2-Amino-p-cresol reacts with strong oxidizing agents.
Fire Hazard	Flash point data for 2-Amino-p-cresol are not available, however 2-Amino-p-cresol is probably combustible.
Purification Methods	Recrystallise the cresol from H2O, Et2O or toluene. It sublimes in vacuo as plates or needles. The hydrochloride has m 222-224o (dec, from aqueous EtOH). [Beilstein 13 H 601, 13 I 227, 13 II 338, 13 III 1576.]

2-Amino-p-cresol Preparation Products And Raw materials

Raw materials

Sodium sulfide-->2-Nitro-p-cresol-->tert-butyl 2-hydroxy-5-methylphenylcarbamate-->4-DIMETHYLAMINOAZOBENZENE-4'-ARSENIC ACID-->2-PHENYLAZO-4-METHYLPHENOL

Preparation Products

Fluorescent Brightener 135-->Fluorescent Brightener Pf-->N-(2-hydroxy-5-methylphenyl)-N'-phenylthiourea-->2-Mercapto-5-methylbenzoxazole-->2,6-Dimethyl-2H-benzo[b][1,4]oxazin-3(4H)-one-->2,5-Dimethylbenzoxazole-->Reactive blue 40-->Mordant Green 10-->SOLOCHROME GREEN V-->2-[[4-[[4-[bis(2-hydroxyethyl)amino]-6-chloro-1,3,5-triazin-2-yl]amino]phenyl]azo]-p-cresol-->2H-1,4-Benzoxazine, 3-(4-chlorophenyl)-6-methyl-

4-AMINO-O-CRESOL 5-amino-m-cresol ALTRENOGEST 2-AMINO-P-CRESOL HYDROCHLORIDE toluidine Bis(5-amino-o-cresol) sulfuric acid [bis(2-hydroxyethyl)amino]-o-cresol P-AMINO-O-CRESOL, 2-Amino-4-methyl-phenol/2-amino-p-Cresol 6-AMINO-M-CRESOL (OH=1) 4-AMINO-2-CRESOL,4-AMINO-O-CRESOL 6-amino-meta-cresol,6-Amino-m-cresol;2-Amino-5-methylphenol 2-amino-o-cresol ,3-AMINO-O-CRESOL AMINO ACIDS [bis(2-hydroxypropyl)amino]-o-cresol CHLOROPHOSPHONAZO III 4-AMINO-M-CRESOL (OH=1) 5-[[2-(2-methoxyethoxy)ethyl]amino]-o-cresol

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