TRI-N-BUTYLGERMANE

TRI-N-BUTYLGERMANE Basic information
Product Name:TRI-N-BUTYLGERMANE
Synonyms:TRIBUTYLGERMANIUM HYDRIDE;TRIBUTYLGERMANE;TRI-N-BUTYLGERMANIUM HYDRIDE;TRI-N-BUTYLGERMANE;Tri-n-butylgermaniumhydride,97+%;Tributylgermane,99%;Germane, tributyl-;TRI-N-BUTYLGERMANE ISO 9001:2015 REACH
CAS:998-39-0
MF:C12H28Ge
MW:244.99
EINECS:
Product Categories:Metal HydridesOrganometallic Reagents;Organogermanium;Others;Precursors by Metal;Reduction;Vapor Deposition Precursors;CVD and ALD Precursors by Metal;Germanium;Materials Science;Metal Hydrides;Micro/NanoElectronics;Organometallic Reagents;Synthetic Reagents;Vapor Deposition Precursors;Chemical Synthesis;GermaniumSynthetic Reagents
Mol File:998-39-0.mol
TRI-N-BUTYLGERMANE Structure
TRI-N-BUTYLGERMANE Chemical Properties
Melting point <0°C
Boiling point 123 °C/20 mmHg (lit.)
density 0.949 g/mL at 25 °C (lit.)
refractive index n20/D 1.45(lit.)
Fp >230 °F
solubility Not miscible.
form Liquid
Specific Gravity0.92
Sensitive Air & Moisture Sensitive
CAS DataBase Reference998-39-0(CAS DataBase Reference)
Safety Information
Hazard Codes Xn
Risk Statements 20/21/22-41
Safety Statements 26-36
WGK Germany 3
TSCA No
MSDS Information
ProviderLanguage
SigmaAldrich English
ALFA English
TRI-N-BUTYLGERMANE Usage And Synthesis
Chemical Propertiesclear colorless liquid
Chemical PropertiesReduces acid chlorides to aldehydes in presence of Pd(0). Effects free-radical reductive addition of alkyl halides to olefins. Reduces benzylic chlorides 70x faster than silyl hydrides.
UsesTri-n-butylgermanium hydride is used in the reduction of benzylic chlorides. It is also used as pharmaceutical intermediate.
UsesEfficient reducing agent for benzylic chlorides.1
General DescriptionTributylgermanium hydride is a radical generating reagent. Reductive alkylation of active olefins with alkyl halides with tributylgermanium hydride was investigated in detail.
TRI-N-BUTYLGERMANE Preparation Products And Raw materials
TETRA-N-BUTYLGERMANE TRI-N-BUTYLGERMANIUM CHLORIDE DIGERMOXANE, HEXABUTYL- TRI-N-BUTYLGERMANE N-BUTYLGERMANE acetic acid, tributylgermanium Germanium TRI-N-BUTYLBROMOGERMANE 3-AMINOPROPYLTRIBUTYLGERMANE TETRAPENTYLGERMANE GERMANIUM TETRAHEXYL

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