Chlorophyll b

Chlorophyll b Basic information
Product Name:Chlorophyll b
Synonyms:Magnesium, [3,7,11,15-tetramethyl-2-hexadecenyl 9-ethenyl-14-ethyl-13-formyl- 21-(methoxycarbonyl)-4,8,18-trimethyl-20-oxo-3 -phorbinepropanoato(2-)-N23,N24,N25,N26 ]-, [SP-4-2-[3S-[3α(2E, 7S,11S),4,21]]]-;(SP-4-2)-((2E,7R,11R)-3,7,11,15-Tetramethyl-2-hexadecenyl (3S,4S,21R)-9-ethenyl-14-ethyl-13-formyl-21-(methoxycarbonyl)-4,8,18-trimethyl-20-oxo-3-phorbinepropanoato(2-)-N23,N24,N25,N26]-magnesium;b-Chlorophyll;Magnesium, [(2E,7R,11R)-3,7,11,15-tetramethyl-2-hexadecenyl (3S,4S,21R)-9-ethenyl-14-ethyl-13-formyl-21-(methoxycarbonyl)-4,8,18-trimethyl-20-oxo-3-phorbinepropanoato(2-)-kN23,kN24,kN25,kN26]-, (SP-4-2)-;Phorbine, magnesium deriv.;C05307;CHLOROPHYLL B(SH);BETA-CHLOROPHYLL
CAS:519-62-0
MF:C55H70MgN4O6
MW:907.49
EINECS:208-272-4
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Mol File:519-62-0.mol
Chlorophyll b Structure
Chlorophyll b Chemical Properties
Melting point 183-185 °C(lit.)
alpha D20 -267° (acetone-methanol)
storage temp. -20°C
solubility Do you have solubility information on this product that you would like to share
form Solid
color Dark Green to Very Dark Green Semi-Solid
Merck 13,2174
BRN 4122778
Stability:Light Sensitive
InChIKeyNSMUHPMZFPKNMZ-VBYMZDBQSA-M
EPA Substance Registry SystemChlorophyll b (519-62-0)
Safety Information
Safety Statements 22-24/25
WGK Germany 3
8-10-23
HS Code 29339900
Chlorophyll b Usage And Synthesis
Chemical PropertiesChlorophyll b is Light, silvery, metallic element.
UsesDo you have application information on this product that you would like to share
UsesChlorophyll b is a photosynthetic pigment used in the absorption of light energy. Chlorophyl b is involved in photosynthesis and absorbs primarily blue light.
UsesExtends the absorption spectrum of light-harvesting complexes LHC-I and LHC-II above 700 nm
DefinitionChlorophyll b is a species that is generally characteristic of higher plants and is an accessory chlorophyll that occurs in green algae. Its salts are essential in nutrition, being required for the activity of many enzymes, especially those concerned with oxidative phosphorylation. It is a component of both intra- and extracellular fluids and is excreted in the urine and feces.
General DescriptionChlorophyll b is one of the chlorophyll pigments that impart leaves their green color. Chlorophyll is a Greek name with?chlorós?meaning green and?phyllon?meaning leaf. It is present in peripheral antenna complexes along with chlorophyll a. The amount of chlorophyll b in spinach is found to be lesser than chlorophyll a.
Biochem/physiol ActionsChlorophyll b undergoes breakdown to form pheophytin b by the enzyme chlorophyllase. This causes a change in its color from green to olive-brown. It is involved in the harvesting of light energy during the process of photosynthesis and its subsequent conversion to chemical energy. Along with chlorophyll a, it plays a key role in the ability of a plant to adapt to different light intensities.
Purification MethodsIt forms red-black hexagonal bipyramids or four-sided plates from dilute EtOH and has been recrystallised from CHCl3/MeOH. It is soluble in MeOH, EtOH, EtOAc and insoluble in pet ether. [Dougherty et al. J Am Chem Soc 88 5037 1966, Beilstein 26 III/IV 3787.]
Chlorophyll b Preparation Products And Raw materials
Raw materialsSucrose-->Potassium phosphate tribasic-->PHYTANTRIOL-->Sodium copper chlorophyllin
Chlorophyll A TRANS-2-HEXENYL VALERATE 2-DODECENYLACETATE TRANS-2-HEXENYL HEXANOATE 3,7,11,15-TETRAMETHYL-2-HEXADECEN-1-OL ACETIC ACID TRANS-2-DECEN-1-YL ESTER Magnesium diamide Chlorophyll b TRANS-2-TRIDECENYL ACETATE 7-Octenoic acid ethyl ester 2-UNDECENYLACETATE 2,4-DIMETHYL-3-PYRROLEPROPIONIC ACID 3,7,11,15-TETRAMETHYL-2-HEXADECENYL ACETATE 2,4-DIMETHYL PYRROL-3-CARBALDEHYDE TRANS-2-HEXENYL BUTYRATE 3-Acetyl-2,4-dimethylpyrrole 1-(2-METHYL-1H-PYRROL-3-YL)-ETHANONE 2-Methyl-1-pyrroline

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