2,3,5-TRIMETHACARB

2,3,5-TRIMETHACARB Basic information
Product Name:2,3,5-TRIMETHACARB
Synonyms:2,3,5(or3,4,5)-trimethyl-phenomethylcarbamate;broot;carbamicacid,methyl-,2,3,5(or3,4,5)-trimethylphenylester;trimethacarb;trimethylphenylmethylcarbamate;uc27867;2,3,5-TRIMETHACARB;2,3,5-TRIMETHYLPHENYL METHYL CARBAMATE
CAS:12407-86-2
MF:C11H15NO2
MW:193.24
EINECS:
Product Categories:
Mol File:12407-86-2.mol
2,3,5-TRIMETHACARB Structure
2,3,5-TRIMETHACARB Chemical Properties
Melting point 118-123°C
Boiling point 329.46°C (rough estimate)
density 1.0945 (rough estimate)
vapor pressure 6.8 x 10-3 Pa (25 °C)
refractive index 1.5080 (estimate)
storage temp. Refrigerator
solubility Chloroform (Slightly), Methanol (Slightly)
form Solid
Water Solubility >58 mg l-1 (23 °C)
color White to Off-White
EPA Substance Registry SystemTrimethacarb (12407-86-2)
Safety Information
RIDADR 2757
HazardClass 6.1(b)
PackingGroup III
Toxicityrabbit,LD50,skin,> 2500mg/kg (2500mg/kg),Shell Chemical Company. Vol. CODE,
MSDS Information
2,3,5-TRIMETHACARB Usage And Synthesis
UsesTrimethacarb is an insecticide with primarily stomach action. It is mainly used to control corn root worm larvae in maize but it also controls a wide range of insect and mollusc pests. Trimethacarb acts as a bird and mammal repellent.
Uses2,3,5-Trimethacarb is a major constituent in landrin insecticide.
DefinitionChEBI: 2,3,5-trimethylphenyl methylcarbamate is a carbamate ester that consists of 2,3,5-trimethylphenol carrying an O-(N-methylcarbamoyl) group. One of two constituents of trimethacarb. It has a role as an agrochemical and an insecticide. It is functionally related to a 2,3,5-trimethylphenol.
Metabolic pathwayThe metabolic pathways of trimethacarb in plants, mammals and insects involve mainly oxidation of N-methyl or ring-methyl substituents and conjugation. Some hydroxylation of the phenyl ring and ester hydrolysis occurs. The metabolism of trimethacarb was reviewed by Fukuto (1972), Kuhr and Dorough (1976) and by Schlagbauer and Schlagbauer (1972).
DegradationTrimethacarb is hydrolysed by strong acids and alkalis but aqueous solutions are stable to light (PM). Trimethacarb was applied to bean leaves and exposed to natural sunlight for 4 days. Both isomers were decomposed more rapidly when exposed to sunlight compared with normal light in the laboratory. The compounds were almost completely decomposed. Major photoproducts resulted from hydroxylation of methyl substituents of the phenyl ring (2 and 3) and of the N-methyl group (5 and 6) (see Schemes 1 and 2). There were few products of hydrolysis (Slade and Casida, 1970; Kuhr and Dorough, 1976).
2,3,5-TRIMETHACARB Preparation Products And Raw materials
Methyl carbamate 3,4,5-TRIMETHACARB,trimethacarb,(3,4,5)-componento 2,3,5-TRIMETHACARB STANDARD,2,3,5-TRIMETHACARB,trimethacarb,(2,3,5)-componento

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