ALLYLTRIPHENYLTIN

ALLYLTRIPHENYLTIN Basic information
Product Name:ALLYLTRIPHENYLTIN
Synonyms:2-propenyl-triphenylstannane;2-Propenyl-triphenylstannane, Allyltriphenyltin;3-(Triphenylstannyl)-1-propene;Triphenyl(2-propenyl)stannane;Triphenyl(allyl)stannane;Triphenylallyltin(IV);tri(phenyl)-prop-2-enylstannane;tri(phenyl)-prop-2-enyl-stannane
CAS:76-63-1
MF:C21H20Sn
MW:391.09
EINECS:200-975-4
Product Categories:Chemical Synthesis;Organometallic Reagents;Organotin;Organotins;Classes of Metal Compounds;Sn (Tin) Compounds;Typical Metal Compounds
Mol File:76-63-1.mol
ALLYLTRIPHENYLTIN Structure
ALLYLTRIPHENYLTIN Chemical Properties
Melting point 71-74 °C(lit.)
Boiling point 421.4±38.0 °C(Predicted)
density 1,07 g/cm3
Fp >100
Water Solubility Insoluble in water
form solid
color White to Almost white
Hydrolytic Sensitivity1: no significant reaction with aqueous systems
BRN 3612762
CAS DataBase Reference76-63-1(CAS DataBase Reference)
Safety Information
Hazard Codes T,N
Risk Statements 23/24/25-50/53
Safety Statements 26-27-28-45-60-61
RIDADR UN 3146 6.1/PG 3
WGK Germany 3
RTECS WH6705000
TSCA No
HS Code 2931.90.6000
HazardClass 6.1(b)
PackingGroup III
MSDS Information
ProviderLanguage
SigmaAldrich English
ALFA English
ALLYLTRIPHENYLTIN Usage And Synthesis
Chemical PropertiesNeedle-like crystals from alc.Sol in most org solvs.
UsesAllyltriphenyltin is an insect chemosterilants.
UsesAllyltriphenylstannane can be used:
  • As a reagent in the C-H phenylation of azoles catalyzed by palladium.
  • As an allylating reagent in the alkylidene Meldrum′s acids allylation catalyzed by Sc(OTf)3.
  • As a reagent in the total synthesis of an antifungal molecule (+)-ambruticin S.

General DescriptionAllyltriphenylstannane is an organotin compound, which is generally used as allylating and radical chain transfer reagent. It is also used as a source of allyl radicals.
HazardA poison.
ALLYLTRIPHENYLTIN Preparation Products And Raw materials
Allyltriphenylphosphonium bromide Allyl triphenylphosphonium chloride TRIMETHYL(PHENYL)TIN DIMETHYLDIPHENYLTIN ALLYLTRIPHENYLTIN Diphenyltin TRIPHENYLTIN HYDRIDE ETHYLTRIPHENYLTIN ALLYLTRIMETHYLTIN Ethyltrimethyltin(IV)

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