ChemicalBook Product Catalog Organic Chemistry Phosphines 2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL

2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL

2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL Basic information
Reaction
Product Name:2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL
Synonyms:2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL;2,2'-BIS(DIPHENYLPHOSPHINO)BIPHENYL;BIPHEP;2,2'-Bis(diphenylphosphino)-1,1'-biphenyl,98%BIPHEP;2,2'-Bis(diphenylphosphino)-1,1'-biphenyl, (BIPHEP);2,2’-Bis(diphenylphospino)-1,1’-biphenyl;PHOSPHINE, 1,1''-[[1,1''-BIPHENYL]-2,2''-DIYL]BIS[1,1-DIPHENYL-;2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL,98%
CAS:84783-64-2
MF:C36H28P2
MW:522.55
EINECS:
Product Categories:Achiral Phosphine;Aryl Phosphine;Phosphines;Biphenyl & Diphenyl ether;Phosphine Ligands;Synthetic Organic Chemistry
Mol File:84783-64-2.mol
2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL Structure
2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL Chemical Properties
Melting point 210-214 °C
Boiling point 635.5±48.0 °C(Predicted)
solubility soluble in Toluene
form crystal
color white
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38-36
Safety Statements 37/39-26
TSCA No
HS Code 29310099
MSDS Information
ProviderLanguage
ACROS English
2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL Usage And Synthesis
Reaction
  1. Supporting ligand in a chiral diamine-ruthenium system for the enantioselective hydrogenation of ketones.
  2. Useful ligand for palladium-catalyzed amination and Kumada cross-coupling reactions
  3. Useful ligand for palladium-catalyzed synthesis of butatrenes.
  4. Useful ligand for iridium-catalyzed C-C cross-coupling of allenes with primary alcohols via transfer hydrogenation.
  5. Useful ligand for iridium-catalyzed C-C cross-coupling of dienes with primary alcohols via transfer hydrogenation.
  6. Useful ligand for iridium-catalyzed C-C cross-coupling of allylic gem-dicarboxylates with aldehydes via transfer hydrogenation.
  7. Useful ligand for the palladium-catalyzed synthesis of chiral allenylsilanes.
  8. Ruthenium-catalyzed synthesis of indoles.
  9. Ruthenium-catalyzed oxidative cyclization.
  10. Rhodium-catalyzed boron arylation. 
Reactions of 84783-64-2_1
Reactions of 84783-64-2_2
Reactions of 84783-64-2_3

Chemical Propertieswhite crystalline powder or crystals
Uses2,2''-Bis(diphenylphosphino)-1,1’-biphenyl (CAS# 84783-64-2) is a chelating phosphine and has been used to study the effects of bite angles on the chemical and physical properties of transition metal complexes. 2,2''-Bis(diphenylphosphino)-1,1’-biphenyl appears as a catalytic ligand in Ni- and Pd-Catalyzed cross-electrophile coupling reactions to form highly substituted 1,3-dienes.
2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL Preparation Products And Raw materials
(aS)-5-Methoxy-4,6-dimethyl-4',6'-di(trifluoromethyl)-2,2'-bis(diphenylphosphino)-1,1'-biphenyl (R)-(+)-2,2'-BIS[BIS(3,5-DITRIFLUOROMETHYLPHENYL)PHOSPHINO]-1,1'-BINAPHTHYL (R)-H8-BINAP DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II) (aS)-4,4',6,6'-Tetrakis(trifluoromethyl)-2,2'-bis(diphenylphosphino)-1,1'-biphenyl DICHLORO[(R)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL][(R,R)-1,2-DIPHENYLETHANE DIAMINE]RUTHENIUM(II) DICHLORO[(R)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL][(R)-1,1-BIS(P-METHOXYPHENYL)-2-ISOPROPYLETHANE-1,2-DIAMINE]RUTHENIUM(II) DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL][(1S,2S)-(-)-1,2-DIPHENYLETHYLENEDIAMINE]RUTHENIUM (II) RARECHEM FH 1W 0053 DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL][(1R,2R)-(+)-1,2-DIPHENYLETHYLENEDIAMINE]RUTHENIUM (II) DICHLORO[(S)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL][(S)-1,1-BIS(P-METHOXYPHENYL)-2-ISOPROPYLETHANE-1,2-DIAMINE]RUTHENIUM(II) R(+)-2 2'-BIS-(DIPHENYLPHOSPHINO)-6 6'-& Chloro[(R)-(+)-5,5'-dichloro-6,6'-dimethoxy-2,2'-bis(diphenylphosphino)-1,1'-biphenyl](p-cymene)ruthenium(II)chlorideCH2Cl2adduct S-(-)-6,6'-Bis(diphenylphosphino)-1,1'-biphenyl-2,2'-diylbis(cyclohexylcarboxylate),99%(S)-CyclohexylSoniphos [(R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl]palladium(II) chloride (R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHALENECHLORO(P-CYMENE)RUTHENIUM CHLORIDE 2,2'-BIS[BIS(3,5-DITRIFLUOROMETHYLPHENYL)PHOSPHINO]-1,1'-BINAPHTHYL 3',6'-BIS(DIETHYLAMINO)-2-(4-NITROPHENYL)SPIRO[ISOINDOLE-1,9'-XANTHENE]-3-ONE
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