6,7-Dihydro-5-methyl-5(H)-cyclopentapyrazine

6,7-Dihydro-5-methyl-5(H)-cyclopentapyrazine Basic information
Product Name:6,7-Dihydro-5-methyl-5(H)-cyclopentapyrazine
Synonyms:5-METHYL-6,7-DIHYDROC;5-METHYL-6,7-DIHYDROCYCLOPENTAPYRAZINE;6,7-DIHYDRO-5-METHYL-5H-CYCLOPENTAPYRAZINE;5H-5-METHYL-6,7-DIHYDROCYCLOPENTA[B]PYRAZINE;5H-5-METHYL-6,7-DIHYDROCYCLOPENTAPYRAZINE;5H-Cyclopentapyrazine, 6,7-dihydro-5-methyl-;5-methyl-(5H)-6,7-dihydrocyclo- pentapyrazine;5-Methyl-5H-cyclopenta[b]pyrazine
CAS:23747-48-0
MF:C8H10N2
MW:134.18
EINECS:245-864-1
Product Categories:Alphabetical Listings;Flavors and Fragrances;M-N
Mol File:23747-48-0.mol
6,7-Dihydro-5-methyl-5(H)-cyclopentapyrazine Structure
6,7-Dihydro-5-methyl-5(H)-cyclopentapyrazine Chemical Properties
Melting point 121-123 °C
Boiling point 96-99 °C20 mm Hg(lit.)
density 1.055 g/mL at 25 °C(lit.)
FEMA 3306 | 5H-5-METHYL-6,7-DIHYDROCYCLOPENTA(B)PYRAZINE
refractive index n20/D 1.527(lit.)
Fp 174 °F
storage temp. Inert atmosphere,Room Temperature
form clear liquid
pka1.85±0.40(Predicted)
color Colorless to Light yellow to Light orange
Odornutty, roasted odor
Odor Typeearthy
Water Solubility insoluble
JECFA Number781
InChIKeyYZEFQPIMXZVPKP-UHFFFAOYSA-N
LogP1.33
NIST Chemistry Reference5H-5-methyl-6,7-dihydrocyclopentapyrazine(23747-48-0)
EPA Substance Registry System5H-Cyclopentapyrazine, 6,7-dihydro-5-methyl- (23747-48-0)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36/37/39
WGK Germany 3
TSCA Yes
HS Code 29339900
MSDS Information
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5-Methyl-6,7-dihydro-5H-cyclopenta(b)pyrazine English
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6,7-Dihydro-5-methyl-5(H)-cyclopentapyrazine Usage And Synthesis
Description5H-5-Methyl-6,7-dihydrocyclopenta(-b)pyrazine has an earthy, baked potato, peanut, roasted odor. It may be prepared from condensation of 2-hydroxy-3-methyl-2-cyclopentene-l-one and ethylene diamine; by condensing a cyclopentenolone with alkylenediamines, or alternatively, an aliphatic α-diketone with 1,2-diamino cyclopentane; the resulting product is dehydrogenated in the presence of palladium over activated charcoal or copper chromite.
Chemical Properties5H-5-Methyl-6,7-dihydrocyclopenta(b)pyrazine has an earthy, peanut, roasted odor
Chemical Propertiesclear yellow to yellow-orange to brown liquid
OccurrenceReported found in peanuts, filberts, asparagus, potato wheat and rye bread, cooked beef, pork, pork liver, beer, cocoa, coffee, green tea, barley, filberts, almond, sesame seed, malt and wort
Uses5-Methyl-6,7-dihydrocyclopentapyrazine can be used for drug storage packaging and antibacterial composition.
DefinitionChEBI: 6,7-Dihydro-5-methyl-5H-cyclopenta[b]pyrazine is a member of pyrazines.
PreparationFrom condensation of 2-hydroxy-3-methyl-2-cyclopentene-1-one and ethylene diamine; by condensing a cyclopentenolone with alkylenediamines, or alternatively, and aliphatic α-diketone with 1,2-diamino cyclopentane; the resulting product is dehydrogenated in the presence of palladium over activated charcoal or copper chromite.
Aroma threshold valuesAroma characteristics at 1.0%: sweet, nutty, roasted, toasted, grainy, coffee and corn with savory, meaty nuances.
Taste threshold valuesTaste characteristics at 15 ppm: nut skin, brown, roasted, oily with a cocoa and coffee nuance, musty, nutty, and grainy
General Description5H-5-Methyl-6,7-dihydrocyclopenta[b]pyrazine is the major flavor compound of palm sugar. It is also found in coffee and cooked meat.
6,7-Dihydro-5-methyl-5(H)-cyclopentapyrazine Preparation Products And Raw materials
AKOS BBS-00000265 DIMETHYL DIHYDROCYCLOPENTAPYRAZINE AKOS BBS-00000235 AKOS BBS-00000234 AKOS BBS-00000178 6,7-Dihydro-5-methyl-5(H)-cyclopentapyrazine AKOS BBS-00001959 AKOS BBS-00002031 Tetramethylpyrazine Kresoxim-methyl AKOS BBS-00000177 AKOS BBS-00001901 Sulfachoropyrazine sodium Glipizide Methyl bromide METSULFURON METHYL AKOS BBS-00001904 AKOS BBS-00000179

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