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Tris(triphenylphosphine)ruthenium(II) chloride

Tris(triphenylphosphine)ruthenium(II) chloride Basic information
Product Name:Tris(triphenylphosphine)ruthenium(II) chloride
Synonyms:RUTHENIUM(II)-TRIS(TRIPHENYLPHOSPHINE) DICHLORIDE;RUTHENIUM DICHLOROTRIS(TRIPHENYLPHOSPHINE);TRIS(TRIPHENYLPHOSPHINE)RUTHENIUM(2) DICHLORIDE;TRIS(TRIPHENYLPHOSPHINE)RUTHENIUM(II) CHLORIDE;TRIS(TRIPHENYLPHOSPHINE)RUTHENIUM(II) DICHLORIDE;Tris(triphenylphosphine)ruthenium(II) chloride≥ 99.5% (Assay);Tris(triphenylphosphine)ruthenium(II) chloride (10.5% Ru) for synthesis;DICHLOROTRIS(TRIPHENYLPHOSPHINE)RUTHENATE (II)
CAS:15529-49-4
MF:C54H45Cl2P3Ru
MW:958.83
EINECS:239-569-7
Product Categories:Ru;metal-phosphine complexes;Catalysts for Organic Synthesis;Classes of Metal Compounds;Environmentally-friendly Oxidation;Homogeneous Catalysts;Metal Compounds;Metal Complexes;Ru (Ruthenium) Compounds;Synthetic Organic Chemistry;Transition Metal Complexes (Environmentally-friendly Oxidation);Transition Metal Compounds;chemical reaction,pharm,electronic,materials
Mol File:15529-49-4.mol
Tris(triphenylphosphine)ruthenium(II) chloride Structure
Tris(triphenylphosphine)ruthenium(II) chloride Chemical Properties
Melting point 159 °C
storage temp. Inert atmosphere,Room Temperature
solubility Very slightly soluble (with dissociation) in acetone, alcohol, chloroform, ethyl acetate, and toluene
form Solution
color Clear
Water Solubility insoluble
Hydrolytic Sensitivity8: reacts rapidly with moisture, water, protic solvents
Sensitive Air & Moisture Sensitive
BRN 4935939
InChIInChI=1S/3C18H15P.2ClH.Ru/c3*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;/h3*1-15H;2*1H;/q;;;;;+2/p-2
InChIKeyQUVLSIIMVTXAPD-UHFFFAOYSA-M
SMILESP(C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1.P(C1=CC=CC=C1)(C1=CC=CC=C1)C1C=CC=CC=1.P(C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1.[Ru](Cl)Cl
CAS DataBase Reference15529-49-4(CAS DataBase Reference)
Safety Information
Hazard Codes Xn
Risk Statements 20/21/22-20/21
Safety Statements 36/37-22
RIDADR 2811
WGK Germany 3
TSCA No
HS Code 28439000
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
ALFA English
Tris(triphenylphosphine)ruthenium(II) chloride Usage And Synthesis
Chemical Propertiesblack crystals
Usessuzuki reaction
UsesDichlorotris(triphenylphosphine)ruthenium(II) serves as a precatalyst for the hydrogenation of alkenes, nitro compounds, ketones, carboxylic acids, synthesis of furans from allenyl sulfides and C-H Activation Catalyst in a Ruthenium/Lewis Acid System
Tris(triphenylphosphine)ruthenium(II) chloride Preparation Products And Raw materials
Raw materialsEthanol-->Tetrahydrofuran-->Dichloromethane-->Isopropyl alcohol-->Hydrazinium hydroxide solution-->Triphenylphosphine-->Lithium-->Ruthenium(III) chloride hydrate(1:x)
Tris(triphenylphosphine)rhodiu Triphenylphosphine Dimethylammoniumdichlorotri(mu-chloro)bis[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]diruthenate(II) Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) Dimethylammonium dichlorotri(μ-chloro)bis[(R)-(+)-5,5μ-bis[di(3,5-xylyl)phosphino]-4,4μ-bi-1,3-benzodioxole]diruthenate(II) TRIPHENYLPHOSPHINE DIBROMIDE Dimethylammoniumdichlorotri(mu-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]diruthenate(II) Tris(triphenylphosphine)ruthenium(II) chloride TRIPHENYLPHOSPHINE 2,2-Bis(hydroxymethyl)-2,2',2''-nitrilotriethanol Ruthenium(III) chloride Dimethylammonium dichlorotri(μ-chloro)bis[(S)-(-)-2,2μ-bis[di-(3,5-xylyl)phosphino]-1,1μ-binaphthyl]diruthenate(II) Ruthenium RUTHENIUM DICHLOROTRIS(TRIPHENYLPHOSPHINE) TRIS BUFFER SOLUTION PH 8.5, 1 L Tris(hydroxymethyl)aminomethane Dimethylammoniumdichlorotri(mu-chloro)bis[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]diruthenate(II) BUFFER SOLUTION PH = 6,00 (20 °C) (POTASSIUM DIHYDROGEN PHOSPHATE/SODIUM HYDROXIDE)
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