METHYL CHLORODIFLUOROACETATE

METHYL CHLORODIFLUOROACETATE Basic information

Product Name:	METHYL CHLORODIFLUOROACETATE
Synonyms:	Acetic acid, chlorodifluoro-, methyl ester;chlorodifluoro-aceticacimethylester;CHLORODIFLUOROACETIC ACID METHYL ESTER;METHYL DIFLUOROCHLOROACETIC ACID;METHYL CHLORODIFLUOROACETATE;Methyl chlorodifluoroacetate 99%;Methylchlorodifluoroacetate99%;2,2-Difluoro-2-chloroacetic acid methyl ester
CAS:	1514-87-0
MF:	C3H3ClF2O2
MW:	144.5
EINECS:	216-154-9
Product Categories:	Fluorinated Building Blocks;Fluorinating Reagents & Building Blocks for Fluorinated Biochemical Compounds;Synthetic Organic Chemistry;C2 to C5;Carbonyl Compounds;Esters
Mol File:	1514-87-0.mol

METHYL CHLORODIFLUOROACETATE Chemical Properties

Boiling point	79-81 °C(lit.)
density	1.37 g/mL at 25 °C(lit.)
refractive index	n20/D 1.349(lit.)
Fp	67 °F
storage temp.	Keep in dark place,Inert atmosphere,2-8°C
form	Liquid
color	Clear colorless
Specific Gravity	1.371
Sensitive	Moisture Sensitive
BRN	1756072
InChIKey	AWUPLMYXZJKHEG-UHFFFAOYSA-N
CAS DataBase Reference	1514-87-0(CAS DataBase Reference)
EPA Substance Registry System	Acetic acid, chlorodifluoro-, methyl ester (1514-87-0)

Safety Information

Hazard Codes	F,C
Risk Statements	11-34-37
Safety Statements	16-26-36/37/39-45
RIDADR	UN 2924 3/PG 2
WGK Germany	3
F	19
Hazard Note	Highly Flammable/Moisture Sensitive
TSCA	Yes
HazardClass	3
PackingGroup	II
HS Code	29159000

MSDS Information

Provider	Language
ACROS	English
SigmaAldrich	English
ALFA	English

METHYL CHLORODIFLUOROACETATE Usage And Synthesis

Chemical Properties	CLEAR COLOURLESS LIQUID
Uses	Methyl chlorodifluoroacetate was used in preparation of 2,2-difluoro-3-hydroxyesters and gem-difluorocyclopropane.
General Description	Methyl chlorodifluoroacetate is a trifluoromethylating agent.

METHYL CHLORODIFLUOROACETATE Preparation Products And Raw materials

Raw materials	Ethane, 1,2-dichloro-1,1,2-trifluoro-2-methoxy--->CHLORODIFLUOROACETYL CHLORIDE-->Sodium chlorodifluoroacetate-->CHLORODIFLUOROACETYL FLUORIDE-->Methyl dichlorofluoroacetate-->Methyl trichloroacetate-->Chlorodifluoroacetic acid-->Methanol
Preparation Products	2H-PERFLUORO-5-METHYL-3,6-DIOXANONANE-->Difluoroacetic acid-->4-Difluoromethoxy-3-hydroxybenzaldehyde-->Methyl 6-chloronicotinate-->4-DIFLUOROMETHOXY-3-METHOXY-BENZALDEHYDE-->Chloromethane

Methyl trifluoroacetate Ethyl bromodifluoroacetate Sodium chlorodifluoroacetate Potassium trifluoroacetate magnesium trifluoroacetate:trifluoroacetic acid (1:2) Diethyl chloromalonate METHYLBROMOCHLOROACETATE Methyl chloroacetate Chlorodifluoroacetic acid METHYL DIFLUOROACETATE Difluoroacetic acid CHLORO-DIFLUORO-ACETIC ACID ALLYL ESTER METHYL CHLORODIFLUOROACETATE T-BUTYL CHLORODIFLUOROACETATE Fluoroacetic acid Methyl fluoroacetate CHLORODIFLUOROACETIC ANHYDRIDE Chlorodifluoroacetic acid ethyl ester

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