ARAMITE

ARAMITE Basic information
Product Name:ARAMITE
Synonyms:ARAMITE, 1X5ML, 0.1MG/ML IN HEXANE;Aramite,0.1mg/mlinHexane;2-CHLOROETHYL-1-METHYL-2-(P-TERT-BUTYLPHENOXY)ETHYL SULFITE;2[P-TERT-BUTYLPHENOXY]ISO-PROPYL-2-CHLOROETHYL SULFITE;COMPOUND 88R;Butylphenoxyisopropylchloroethylsulfite;ARAMITE;ARAMITE(R)
CAS:140-57-8
MF:C15H23ClO4S
MW:334.86
EINECS:
Product Categories:A;Alphabetic;AR to AZ;8000 Series Solidwaste Methods;EPA;Method 8270
Mol File:140-57-8.mol
ARAMITE Structure
ARAMITE Chemical Properties
Melting point -31.7°
Boiling point bp0.1 175°; bp7.0 200-210°
density 1.195
refractive index nD20 1.5100 to 1.5118; nD27 1.5075
storage temp. 2-8°C
solubility Chloroform (Slightly), Methanol (Slightly)
form Oil
color Colourless to Pale Brown
Stability:Hygroscopic
IARC2B (Vol. 5, Sup 7) 1987
EPA Substance Registry SystemAramite (140-57-8)
Safety Information
Hazard Codes F,Xn
Risk Statements 11-36/37/38-48/20-62-40
Safety Statements 53-16-36/37/39-45-36/37-24/25-23
RIDADR UN 1208 3/PG 2
WGK Germany 2
HS Code 29252900
Hazardous Substances Data140-57-8(Hazardous Substances Data)
ToxicityLD50 orally in rats: 3.90±0.28 g/kg (Oser, Oser)
MSDS Information
ARAMITE Usage And Synthesis
DescriptionAramite is a synthetic chlorinated hydrocarbon with molecular weight of 334.87 and density of 1.143 at 20°C. It is a clear, light-colored oil with melting point of 37.3 C and boiling point of 175 °C at 0.1 mm Hg. The technical grade aramite is a dark amber liquid. Aramite is soluble at 0.000 1% (practically insoluble) in water but is miscible in many organic solvents. It was sold as mixture in organic solvents at different strengths for further dilution and use. Aramite was used as a pesticide (acaricide) to control mites in plants and animals. Aramite was initially introduced to market around 1950. It was mostly used between 1950 and 1954 in greenhouses in the United States. Its manufacture and use were voluntarily discontinued due to its carcinogenic potential according to a US Environmental Protection Agency (EPA) notice dated 12 April 1977. However, there are reports of bans of aramite use in a few European countries, in 1987 (Lithuania), 1996 (Poland), and 1999 (Estonia). There is no information on the production, import, registration, marketing, stockpiling, and use of aramite in Russia. Occupational exposure through dermal contact and inhalation was possible during its use.
Chemical PropertiesAramite is a heavy, dark-amber liquid.
UsesMiticide.
UsesAramite was formerly used in control of mites (miticide) in citrus fruits, vegetables, and animals. Active mite stage was most sensitive to aramite toxicity. The death in mites was due to paralysis and disorganized movements of appendages, leading to detachment from the plant. Insects and mites other than Tetracychidae are not as sensitive to aramite. Mites exposed in the field to up to 21 applications were not found to develop resistance in mites, unlike other organochlorines where insects develop resistance rapidly. Aramite is rendered inactive when mixed with lime and other alkaline materials. Aramite was used in combination of other pesticides to control a wide range of mite species.
DefinitionChEBI: Aramite is an alkylbenzene.
General DescriptionAramite is a carcinogenic acaricide, widely used against six spotted mite, European red mite and others affecting crops.
Safety ProfileConfirmed carcinogen with experimental carcinogenic, neoplastigenic, and tumorigenic data. Experimental poison by intraperitoneal route. Moderately toxic to humans by ingestion. Moderately toxic experimentally by ingestion. Experimental reproductive effects. A pesticide. When heated to decomposition it emits toxic fumes of Cland SOx. See also ESTERS and SULFUROUS ACID.
Potential ExposureAramite is an organochlorine miticide and antimicrobial agent. Aramite is regulated by EPA under the Federal Insecticide, Fungicide, and Rodenticide Act and the Resource Conservation and Recovery Act. The significant regulatory action was a voluntary cancellation of the active ingredient registration by the sole producer in 1975.
ShippingUN2902 Pesticides, liquid, toxic, n.o.s., Hazard Class: 6.1; Labels: 6.1-Poisonous materials, Technical Name Required.
Toxicity evaluationAramite can be released directly into the environment through its use as an acaricide (miticide); however, this use has been discontinued. If released to soil, aramite is expected to have no mobility. Volatilization from moist soil surfaces is not expected to be an important fate process based on an estimated Henry’s Law constant of 1.9×10-7 atm m3 mol-1. Biodegradation data for aramite are not available, and if released into water, aramite is expected to adsorb to suspended solids and sediments based upon the estimated Koc of 2.0×10+4. Volatilization from water surfaces is not expected to be an important fate process based on this compound’s estimated Henry’s Law constant. Aramite’s potential for bioconcentration in aquatic organisms is very high. Functional groups of aramite are susceptible to hydrolysis; however, insufficient data are available to predict the relative importance or occurrence of chemical or biological degradation processes in water or soil. Aramite is hydrolyzed by alkalies and may contribute to degradation in soil or water. If released into air, aramite is expected to be physically removed by wet and dry deposition processes.
IncompatibilitiesIncompatible with alkaline material, such as lime or Bordeaux mixture (slaked lime and copper sulfate solution).
Waste DisposalAcid or alkaline hydrolysis followed by flushing to sewer.
ARAMITE Preparation Products And Raw materials
1-TERT-BUTYL-4-PROPOXYBENZENE ARAMITE, 1X1ML, CH2CL2 2000UG/ML ARAMITE Diethyl sulfite 2-Chloroethanol Sulfurous Acid Dimethyl sulfite ARAMITE 1X1ML CH2CL2 2000UG/ML

Email:[email protected] [email protected]
Copyright © 2024 Mywellwork.com All rights reserved.