TRIMETHYLTIN CHLORIDE

TRIMETHYLTIN CHLORIDE Basic information
Product Name:TRIMETHYLTIN CHLORIDE
Synonyms:TriMethyltin chloride solution 1.0 M in hexanes;TriMethyltin chloride solution 1.0 M in THF;TriMethyltin chloride, 1.0 M solution in Hexanes, SpcSeal;Trimethyltin chloride, 98+% (1M solution in hexanes);Trimethyltin chloride, 98+% (1M solution in methylene chloride);TriMethyltin chloride, 1.0 M solution in THF, SpcSeal;CHLOROTRIMETHYLSTANNANE;CHLOROTRIMETHYLTIN
CAS:1066-45-1
MF:C3H9ClSn
MW:199.27
EINECS:213-917-8
Product Categories:Alkyl Metals;Classes of Metal Compounds;Grignard Reagents & Alkyl Metals;Sn (Tin) Compounds;Synthetic Organic Chemistry;Typical Metal Compounds;Organometallic Reagents;Organotin;Organotin Halides;Alpha sort;Pesticides&Metabolites;Q-ZAlphabetic;TP - TZ;organotin compound;25mL Sure/Seal Reagents;Chemical Synthesis;Organometallic Reagents;Organotin Halides
Mol File:1066-45-1.mol
TRIMETHYLTIN CHLORIDE Structure
TRIMETHYLTIN CHLORIDE Chemical Properties
Melting point 37-39 °C (lit.)
Boiling point 148 °C
density 0.988 g/mL at 25 °C
Fp 207 °F
storage temp. Poison room
solubility Chloroform (Slightly)
form Liquid
Specific Gravity1.356
color White
OdorStrong unpleasant stench; no threshold data available
Water Solubility Soluble in water, chloroform and organic solvents.
Sensitive Moisture Sensitive
Hydrolytic Sensitivity4: no reaction with water under neutral conditions
BRN 3535111
Exposure limitsACGIH: TWA 0.1 mg/m3; STEL 0.2 mg/m3 (Skin)
NIOSH: IDLH 25 mg/m3; TWA 0.1 mg/m3
Stability:Moisture Sensitive
InChIKeyKWTSZCJMWHGPOS-UHFFFAOYSA-M
CAS DataBase Reference1066-45-1(CAS DataBase Reference)
EPA Substance Registry SystemTrimethyltin chloride (1066-45-1)
Safety Information
Hazard Codes T+,N,F
Risk Statements 26/27/28-50/53-51/53-36/37-19-11-34-40-65-62-48/23/25-36/37/38
Safety Statements 28-36/37-45-61-27-26-16-60-62
RIDADR UN 3146 6.1/PG 2
WGK Germany 3
RTECS WH6850000
10-21
TSCA Yes
HazardClass 6.1
PackingGroup II
HS Code 29319090
Hazardous Substances Data1066-45-1(Hazardous Substances Data)
ToxicityLD50 oral (rat) 12.6 mg/kg
PEL (OSHA) 0.1 mg tin/m3
The ACGIH has established the following uniform exposure limits for all organotin compounds based on the concentration of tin in air:
TLV-TWA (ACGIH) 0.1 mg tin/m3
STEL (ACGIH) 0.2 mg tin/m3



MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
ALFA English
TRIMETHYLTIN CHLORIDE Usage And Synthesis
Chemical PropertiesWHITE CRYSTALS
UsesTrimethyltin chloride is an organotin reagent widely used in transferring trimethylstannyl groups onto the substrates to synthesize various organostannanes. Trimethylstannyl compounds derived from this reagent, are extensively used in the palladium-catalyzed Stille coupling reactions.
General DescriptionSolid.
Reactivity ProfileTRIMETHYLTIN CHLORIDE is in the family of tin compounds widely used as stabilizers for plastics, additives to paint(as antifouling agents). Some have catalytic properties. Examples include butyl tin, dibutyl tin oxide. Their main hazard is associated with their high toxicity, in skin adsorption or inhalation.
HazardA deadly poison. A reproductive hazard.
Health Hazard(Non-Specific -- Tin Compounds, Organic) The material is an irritant to the skin and gastrointestinal tract. Contact may specifically damage the following target organs: central nervous system, eyes, liver, urinary tract, and skin.
Health HazardTrimethyltin chloride and other organotin compounds are highly toxic by ingestion, inhalation, or skin contact. Trimethyltin chloride can cause irritation and burns of the skin and eyes. Organotin compounds can affect the central nervous system. The degree of toxicity is greatest for compounds with three or four alkyl groups attached to tin. Diand monoalkyltin compounds are moderately toxic. The toxicity diminishes as the size of the alkyl groups increases. Thus, the oral LD50s in rats are as follows: dimethyltin dichloride, 74 to 237 mg/kg; tributyltin chloride, 122 to 349 mg/kg; dibutyltin oxide, 487 to 520 mg/kg; trioctyltin chloride, >4000 mg/kg.
Organotin compounds have been shown to cause reproductive effects in laboratory animals.
Fire HazardNot a significant fire hazard. Emits toxic fumes in fire.
Fire HazardWhen heated to decomposition, TRIMETHYLTIN CHLORIDE emits toxic fumes of chlorides. Avoid decomposing heat.
Flammability and ExplosibilityNot a significant fire hazard. Emits toxic fumes in fire.
Safety ProfileA deadly poison by intravenous route. Experimental reproductive effects. See also TIN COMPOUNDS. When heated to decomposition it emits toxic fumes of Cl-.
IncompatibilitiesTrimethyltin chloride and other organotin halides react with water to produce hydrogen halides. Organotin hydrides react with water to produce hydrogen gas, which is flammable and explosive.
Waste DisposalExcess trimethyltin chloride or other organotin compound and waste material containing this substance should be placed in an appropriate container, clearly labeled, and handled according to your institution's waste disposal guidelines.
TRI-P-TOLYLCHLOROTIN Tributyltin chloride TRIPHENYL-D15-TIN CHLORIDE ALLYLDIBUTYLTIN CHLORIDE TRICYCLOHEXYLTIN CHLORIDE TRIMETHYLTIN CHLORIDE TRIPENTYLTIN CHLORIDE N-BUTYLDIMETHYLCHLOROTIN TRIBENZYLTIN CHLORIDE Ethanaminium, N,N,N-triethyl-, (TB-5-12)-bromochlorotriphenylstannate( 1-) TRI-N-PROPYLTIN CHLORIDE TRI-I-PROPYLTIN CHLORIDE triisobutyltin chloride DI-N-BUTYL(3-HYDROXYBUTYL)TINCHLORIDE Chlorotriphenyltin Decafentin Trioctyltin chloride TRIBUTYLTIN CHLORIDE-D27

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