ChemicalBook Product Catalog Chemical Reagents Organic reagents Esters Other esters Benzyl 2-chloroacetate

Benzyl 2-chloroacetate

Benzyl 2-chloroacetate Basic information
Product Name:Benzyl 2-chloroacetate
Synonyms:AKOS B029322;CHLOROACETIC ACID BENZYL ESTER;BENZYL-(CHLORACETAT);BENZYL CHLOROACETATE;benzyl 2-chloroacetate;Acetic acid, chloro-, phenylmethyl ester;benzyl chloracetate;Phenylmethyl 2-chloroacetate
CAS:140-18-1
MF:C9H9ClO2
MW:184.62
EINECS:205-400-0
Product Categories:C8 to C9;Carbonyl Compounds;Esters
Mol File:140-18-1.mol
Benzyl 2-chloroacetate Structure
Benzyl 2-chloroacetate Chemical Properties
Boiling point 90 °C/1 mmHg (lit.)
density 1.215 g/mL at 25 °C (lit.)
refractive index n20/D 1.525(lit.)
Fp >230 °F
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
form clear liquid
Specific Gravity1.215
color Oil
Water Solubility insoluble
CAS DataBase Reference140-18-1(CAS DataBase Reference)
EPA Substance Registry SystemAcetic acid, chloro-, phenylmethyl ester (140-18-1)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36-37/39
WGK Germany 3
RTECS AF8750000
HS Code 29154000
ToxicityLDLo ipr-mus: 500 mg/kg CBCCT* 8,99,56
MSDS Information
ProviderLanguage
Benzyl 2-chloroacetate English
SigmaAldrich English
ACROS English
Benzyl 2-chloroacetate Usage And Synthesis
UsesBenzyl chloroacetate may be used:
  • in the synthesis of monoesters of phosphonoacetic acid
  • in the synthesis of N-benzoyl-glycyl- hydroxyl acetic acid, ester substrate for carboxypeptidase Y catalyzed peptide synthesis
  • as reagent in the total syntheses of the (±)-di-O-methyl ethers of the norlignans sequirin-A, agatharesinol, and hinokiresinol, and of (±)-tri-O-methyl sequirin-E
General DescriptionBenzyl chloroacetate is an ester.
Safety ProfileModerately toxic byintraperitoneal route. When heated todecomposition it emits toxic fumes of Cl- .
Benzyl 2-chloroacetate Preparation Products And Raw materials
Raw materialsDichloromethane-->Pyridine-->Chloroacetyl chloride-->Benzyl alcohol
Preparation ProductsDiethyl (benzyloxycarbonylmethyl)phosphonate, 98 %
Benzyl 2-chloro-2-[2-(3- BUTTPARK 60\40-55 1-phenylethyl 2-chloroacetoacetate AURORA KA-5058 AURORA KA-996 SALOR-INT L132187-1EA Chloroacetic acid Benzyl 2-chloro-2-[2-(3,4- Benzyl 2-chloroacetate Benzyl 2-[2-(4-bromophenyl)hydrazono]-2- Benzyl2-chloro-2-[2-(4-methylphenyl)hydrazono]acetate Benzyl 2-chloro-2-[2-(3,5- Benzyl 2-chloro-2-[2-(2,6- 3,4-DICHLORO-5-PHENYL-2(5H)-FURANONE Benzyl acetate AURORA KA-1002 Benzyl 2-chloro-2-[2-(4- BENZYL CHLOROFLUOROACETATE
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