n-Tridecane

n-Tridecane Basic information
Product Name:n-Tridecane
Synonyms:N-TRIDECANE MIN. 99,9 % FOR GAS CHROMATO GRAPHY;N-Tridecane>99%;N-Tridecane~98%;standardmaterial;Tridecan;TRIDECANE,N-(SG);1-TRIDECANE;NAPHTHOCAINE
CAS:629-50-5
MF:C13H28
MW:184.36
EINECS:211-093-4
Product Categories:Chemical Class;Analytical Chemistry;n-Paraffins (GC Standard);Standard Materials for GC;Acyclic;Alkanes;Organic Building Blocks;Hydrocarbons;NeatsAlphabetic;TP - TZ;Alpha Sort;NeatsVolatiles/ Semivolatiles;T-ZAlphabetic
Mol File:629-50-5.mol
n-Tridecane Structure
n-Tridecane Chemical Properties
Melting point -6--4 °C (lit.)
Boiling point 110-112 °C/12 mmHg (lit.) 234 °C (lit.)
density 0.756 g/mL at 25 °C (lit.)
vapor density 6.4 (vs air)
vapor pressure 1 mm Hg ( 59.4 °C)
refractive index n20/D 1.425(lit.)
Fp 215 °F
storage temp. Store below +30°C.
form Liquid
color Clear colorless
explosive limit0.6-6.5%(V)
Water Solubility PRACTICALLY INSOLUBLE
BRN 1733089
Stability:Stable. Combustible. Incompatible with strong oxidizing agents.
InChIKeyIIYFAKIEWZDVMP-UHFFFAOYSA-N
LogP7.331 (est)
CAS DataBase Reference629-50-5(CAS DataBase Reference)
NIST Chemistry ReferenceTridecane(629-50-5)
EPA Substance Registry SystemTridecane (629-50-5)
Safety Information
Hazard Codes Xi,Xn
Risk Statements 36/37/38-66-65
Safety Statements 26-36-24/25-62
WGK Germany 3
RTECS YD3025000
Autoignition Temperature>204 °C
TSCA Yes
HS Code 29011090
Hazardous Substances Data629-50-5(Hazardous Substances Data)
ToxicityLD50 orally in Rabbit: > 5000 mg/kg LD50 dermal Rat > 2000 mg/kg
MSDS Information
ProviderLanguage
n-Tridecane English
ACROS English
SigmaAldrich English
ALFA English
n-Tridecane Usage And Synthesis
Chemical Propertiescolourless liquid
UsesOrganic synthesis, distillation chaser.
Usesn-Tridecane is used as a distillation chaser. It is a component of various fuels and solvents used in industry.
DefinitionChEBI: Tridecane is a straight chain alkane containing 13 carbon atoms. It forms a component of the essential oils isolated from plants such as Abelmoschus esculentus. It has a role as a plant metabolite and a volatile oil component.
Synthesis Reference(s)The Journal of Organic Chemistry, 46, p. 3909, 1981 DOI: 10.1021/jo00332a030
Tetrahedron, 48, p. 8253, 1992 DOI: 10.1016/S0040-4020(01)80493-2
General DescriptionAn oily straw yellow clear liquid with a hydrocarbon odor. Flash point 190-196°F. Specific gravity 0.76. Boiling point 456°F. Repeated or prolonged skin contact may irritate or redden skin, progressing to dermatitis. Exposure to high concentrations of vapor may result in headache and stupor.
Air & Water ReactionsInsoluble in water.
Reactivity ProfileSaturated aliphatic hydrocarbons, such as n-Tridecane, may be incompatible with strong oxidizing agents like nitric acid. Charring of the hydrocarbon may occur followed by ignition of unreacted hydrocarbon and other nearby combustibles. In other settings, aliphatic saturated hydrocarbons are mostly unreactive. They are not affected by aqueous solutions of acids, alkalis, most oxidizing agents, and most reducing agents. When heated sufficiently or when ignited in the presence of air, oxygen or strong oxidizing agents, they burn exothermically to produce carbon dioxide and water.
Health HazardMay be harmful by inhalation, ingestion or skin absorption. Vapor or mist is irritating to the eyes, mucous membrane and upper respiratory tract. Causes skin irritation.
Safety ProfileModerately toxic by intravenousroute. When heated to decomposition it emits acrid smokeand irritating fumes.
CarcinogenicityMice treated with tridecane developed tumors on their backs, after exposure to ultraviolet radiation at wavelengths longer than 350 nm, generally considered noncarcinogenic.
n-Tridecane Preparation Products And Raw materials
Raw materialsTetradecane-->METHYL MYRISTATE-->1-Tetradecanol
Preparation ProductsDibenzofuran, 1-nitro- -->N-NONANE-->1-BUTENE
PERFLUOROEICOSANE 1-Bromohexadecane 1-IODOHEXADECANE 1-Chlorotetradecane 1-BROMOPENTADECANE Chlorodimethyloctadecylsilane 1-Chlorooctadecane Myristoyl chloride 1-Bromotridecane PERHYDROFLUORENE CYCLOTRIDECANONE N-OCTADECYLTRICHLOROSILANE MARGAROYL CHLORIDE 2-BROMOTRIDECANE 1-Bromotetradecane 1-IODOOCTADECANE STEAROYL CHLORIDE Palmitoyl chloride Tridecane

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