| | Propyl sulfide Basic information |
| Product Name: | Propyl sulfide | | Synonyms: | 1,1'-THIOBIS(PROPANE);4-THIAHEPTANE;DIPROPYL SULPHIDE;DIPROPYL SULFIDE;DI-N-PROPYL SULPHIDE;DI-N-PROPYL SULFIDE;propane,1,1’-thiobis-;Propyl monosulfide | | CAS: | 111-47-7 | | MF: | C6H14S | | MW: | 118.24 | | EINECS: | 203-873-8 | | Product Categories: | sulfide Flavor | | Mol File: | 111-47-7.mol |  |
| | Propyl sulfide Chemical Properties |
| Melting point | −103 °C(lit.) | | Boiling point | 142-143 °C(lit.) | | density | 0.838 g/mL at 25 °C(lit.) | | refractive index | n20/D 1.4487(lit.) | | Fp | 83 °F | | storage temp. | Store below +30°C. | | form | liquid | | Specific Gravity | 0.838 | | color | Colorless to Almost colorless | | Odor | at 0.10 % in propylene glycol. garlic onion | | Odor Threshold | 0.00054ppm | | Odor Type | alliaceous | | explosive limit | 1-51%(V) | | Water Solubility | Soluble in water 351mg/L @ 25°C. | | Merck | 14,7868 | | BRN | 1719002 | | LogP | 3.015 (est) | | CAS DataBase Reference | 111-47-7(CAS DataBase Reference) | | NIST Chemistry Reference | Propane, 1,1'-thiobis-(111-47-7) | | EPA Substance Registry System | Dipropyl sulfide (111-47-7) |
| Hazard Codes | Xi,F | | Risk Statements | 10-36/37/38-36 | | Safety Statements | 26-36-39-16-7/9 | | RIDADR | UN 1993 3/PG 3 | | WGK Germany | 3 | | F | 13 | | Hazard Note | Harmful/Irritant | | TSCA | Yes | | HazardClass | 3 | | PackingGroup | III | | HS Code | 29309070 |
| | Propyl sulfide Usage And Synthesis |
| Chemical Properties | clear colorless liquid | | Uses | A garlic organosulfide | | Uses | Di-n-propyl sulfide is used in organic synthesis and used as a daily fragrance. | | Definition | ChEBI: Dipropyl sulfide is an aliphatic sulfide. | | Synthesis Reference(s) | Canadian Journal of Chemistry, 51, p. 1419, 1973 DOI: 10.1139/v73-213
Organic Syntheses, Coll. Vol. 2, p. 547, 1943
Tetrahedron Letters, 20, p. 3995, 1979 | | Purification Methods | Wash the sulfide with aqueous 5% NaOH, then water. Dry it with CaCl2 and distil it from Na [Dunstan & Griffiths J Chem Soc 1344 1962]. [Beilstein 1 IV 1452.] |
| | Propyl sulfide Preparation Products And Raw materials |
|
