CYCLOPENTADIENYLMANGANESE TRICARBONYL

CYCLOPENTADIENYLMANGANESE TRICARBONYL Basic information
Product Name:CYCLOPENTADIENYLMANGANESE TRICARBONYL
Synonyms:CYCLOPENTADIENYLMANGANESE TRICARBONYL;CYCLOPENTADIENYLTRICARBONYLMANGANESE;tricarbonyl(eta-cyclopentadienyl)manganese;Cyclopentadienyl marganese tricarbonyl;Cyclopentadienylmanganesetricarbonyl,98%;Manganese, tricarbonyl(.eta.5-2,4-cyclopentadien-1-yl)-;cyclopentadienylmanganese(i) tricarbonyl;(eta5-Cyclopentadienyl) manganese tricarbonyl
CAS:12079-65-1
MF:C8H5MnO35*
MW:204.06
EINECS:235-142-4
Product Categories:OIL ADDITIVE;OCTANE BOOSTER;metallocene;ManganeseVapor Deposition Precursors;Catalysis and Inorganic Chemistry;Chemical Synthesis;Manganese;Precursors by Metal
Mol File:12079-65-1.mol
CYCLOPENTADIENYLMANGANESE TRICARBONYL Structure
CYCLOPENTADIENYLMANGANESE TRICARBONYL Chemical Properties
Melting point 72-76 °C(lit.)
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
form crystal
color yellow
Water Solubility Soluble in water (70 ppm (25C)
Sensitive Air Sensitive
Exposure limitsACGIH: TWA 0.1 mg/m3 (Skin)
OSHA: Ceiling 5 mg/m3
NIOSH: IDLH 500 mg/m3; TWA 0.1 mg/m3; TWA 1 mg/m3; STEL 3 mg/m3
EPA Substance Registry SystemManganese cyclopentadienyl tricarbonyl (12079-65-1)
Safety Information
Hazard Codes T+
Risk Statements 28
Safety Statements 28-36/37-45
RIDADR UN 2811 6.1/PG 2
WGK Germany 3
RTECS OO9720000
TSCA Yes
HazardClass 6.1
PackingGroup II
HS Code 29310099
Hazardous Substances Data12079-65-1(Hazardous Substances Data)
Toxicitymouse,LD50,intravenous,710ug/kg (0.71mg/kg),U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. Vol. NX#11285,
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
ALFA English
CYCLOPENTADIENYLMANGANESE TRICARBONYL Usage And Synthesis
Chemical Propertiesyellow crystals or crystalline chunks
UsesOctane enhancer for gasoline
UsesAntiknock agent.
UsesCyclopentadienylmanganese tricarbonyl is an important raw material and intermediate used in organic synthesis, pharmaceutical intermediates.
General DescriptionBright yellow, crystalline solid with a camphor-like odor. Sublimes 75-77°C. Slightly soluble in water. Used as an octane enhancement additive for unleaded gasoline.
Reactivity ProfileMANGANESE CYCLOPENTAHIENYL TRICARBONYL is combustible. Heating causes evolution of carbon monoxide and other toxic or irritating gases. Heating in a confined space causes a rise in pressure with the risk of bursting. Incompatible with oxygen.
HazardToxic material absorbed by skin. Central nervous system impairment and skin irritant.
Health HazardManganese cyclopentadienyl tricarbonyl (MCT) causes convulsions and pulmonary edema in laboratory animals.
Safety ProfileA poison by ingestion, inhalation, intraperitoneal, and intravenous routes. A mild narcotic which can damage kidneys. When heated to decomposition it emits acrid smoke and irritating fumes. See also MANGANESE COMPOUNDS and CARBON MONOXIDE.
CYCLOPENTADIENYLMANGANESE TRICARBONYL Preparation Products And Raw materials
ETHYLCYCLOPENTADIENYLMANGANESE TRICARBONYL CYCLOPENTADIENYLMANGANESE TRICARBONYL HYDROXYISOPROPYLCYCLOPENTADIENYLMANGANESE TRICARBONYL Manganese ACETYLCYCLOPENTADIENYLMANGANESE(I) TRIC& Methylcyclopentadienyl manganese tricarbonyl

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