1-Bromo-4-nitrobenzene

1-Bromo-4-nitrobenzene Basic information

Product Name:	1-Bromo-4-nitrobenzene
Synonyms:	1-BroMo-4-nitrobenzene, 99% 25GR;p-nitrobroMobenzene cation;The broMine nitrobenzene;p-Nitrobromobenzene;P-BROMONITROBENZENE;1-BROMO-4-NITROBENZENE;4-BROMONITROBENZENE;4-bromo-1-nitrobenzene
CAS:	586-78-7
MF:	C6H4BrNO2
MW:	202.01
EINECS:	209-583-8
Product Categories:	Nitro Compounds;Nitrogen Compounds;Organic Building Blocks
Mol File:	586-78-7.mol

1-Bromo-4-nitrobenzene Chemical Properties

Melting point	124-126 °C(lit.)
Boiling point	255-256 °C(lit.)
density	1,95 g/cm³
refractive index	1.6060 (estimate)
Fp	254-256°C
storage temp.	Store below +30°C.
solubility	soluble in Chloroform
form	Crystalline Powder
color	Light yellow
Water Solubility	insoluble
BRN	636964
InChIKey	ZDFBKZUDCQQKAC-UHFFFAOYSA-N
CAS DataBase Reference	586-78-7(CAS DataBase Reference)
NIST Chemistry Reference	Benzene, 1-bromo-4-nitro-(586-78-7)
EPA Substance Registry System	Benzene, 1-bromo-4-nitro- (586-78-7)

Safety Information

Hazard Codes	Xn,Xi
Risk Statements	22-36/37/38-20/21/22-62-51/53-46-45
Safety Statements	36/37/39-26-22-61-53-45
RIDADR	UN 3459 6.1/PG 3
WGK Germany	3
RTECS	CY9040550
TSCA	Yes
HazardClass	6.1
PackingGroup	III
HS Code	29049085

MSDS Information

Provider	Language
4-Bromo-1-nitrobenzene	English
SigmaAldrich	English
ACROS	English
ALFA	English

1-Bromo-4-nitrobenzene Usage And Synthesis

Chemical Properties	light yellow powder
Uses	It can be employed as a syntheses material intermediate. It is also used as a pharmaceutical intermediate.
Synthesis Reference(s)	Tetrahedron, 43, p. 4321, 1987 DOI: 10.1016/S0040-4020(01)90307-2
Purification Methods	Crystallise it twice from pet ether, using charcoal before the first crystallisation. [Beilstein 5 III 619, 5 IV 729.]

1-Bromo-4-nitrobenzene Preparation Products And Raw materials

Raw materials

Nitric acid-->Bromobenzene

Preparation Products

4-Nitrophenylboronic acid-->6-Bromoquinoline-->4-Bromophenoxybenzene-->NSC10978-->4-Nitroanisole-->4,4'-THIODIANILINE-->ethenylsulfanylethene-->4-bromo-2,6-dinitrophenol-->N,N-DIETHYL-4-NITROANILINE-->4-Nitrophenylboronic acid pinacol ester-->1-(4-Aminophenyl)-4-(4-hydroxyphenyl)piperazine-->2,7-Dibromophenazine-->4,4'-DINITROBIPHENYL-->Benzenamine, 4-(1-naphthalenyl)--->3-DIETHYLAMINO-1-NITROBENZENE-->1,2-Bis(4-bromophenyl)diazene

1-BROMO-2,4-DINITROBENZENE BROMONITROBENZENE 4-Nitrophenylacetic acid 2,3,4,5,6-PENTABROMONITROBENZENE 1-Bromo-4-nitrobenzene 2-Bromo-5-nitrobenzotrifluoride p-Nitrobenzoic acid 2-Bromo-5-nitroaniline 1-BROMO-2-NITROBENZENE,2-Bromo-1-nitrobenzene,1-BROMO-2-NITROBENZENE, 99+% ρ-Nitrobenzenesulphonic acid 2,5-Dibromonitrobenzene 3-Bromo-1-nitrobenzen Bromine Nitrobenzene 4-Nitrobenzaldehyde 2-BROMO-5-NITROANISOLE 3-Nitrochlorobenzene 4-BROMO-2,5-DIFLUORONITROBENZENE

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